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z-Ch. 22 Carbonyl Alpha-Substitution RXN's
CHM2211 Dr. Elsheimer Fall 09
10
Organic Chemistry
Undergraduate 2
10/23/2009
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Term
LDA
 Definition
Lithiumdiisopropylamide Li+ -N(CH(CH3)2)2
Term
RC=OCH + X2 -CH3CO2H->
 Definition
RC=OCX
Term
HOC=OCH -1.Br2,PBr3/2.H2O->
 Definition
HOC=OCBr
Term
RC=OC(Br)CH -pyridine->
 Definition
RC=OC=C
Term
RCOCH3 -X2/NaOH->
 Definition
RCOO- + CH3X
Term
EtO2CCH2CO2Et -1.NaOEt/2.RX-> -H3O/Heat->
 Definition
First: EtO2CCH(R)CO2Et Then: RCH2COOH
Term
EtO2CCH2COCH3 -1.NaOEt/2.RX-> -H3O/Heat->
 Definition
First: EtO2CCH(R)COCH3 Then: RCH2COCH3
Term
RC=OCH -1.LDL,THF/2.R'X->
 Definition
RC=OCR'
Term
ROC=OCH -1.LDL,THF/2.R'X->
 Definition
ROC=OCR'
Term
HCCN -1.LDL,THF/2.RX->
 Definition
RCCN
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