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z-Ch. 20 Carboxylic Acids and Nitriles
CHM2211 Dr. Elsheimer Fall 09
14
Organic Chemistry
Undergraduate 2
10/06/2009
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Term
HCO2H
 Definition
Formic Acid
Term
CH3CO2H
 Definition
Acetic Acid
Term
HO2CCO2H
 Definition
Oxalic Acid
Term
HO2CCH2CO2H
 Definition
Malonic Acid
Term
HO2CCH2CH2CO2H
 Definition
Succinic Acid
Term
HO2CCH2CH2CH2CO2H
 Definition
Glutaric Acid
Term
HO2CCH2CH2CH2CH2CO2H
 Definition
Adipic Acid
Term
Structure and Properties of carboxylic acids
 Definition
Higher m.p., b.p., and H2O-solubility than many other functional classes of comparable size and MW
Term
Substituted Alkylbenzene -> Substituted benzoic acid
 Definition
KMnO4 or Na2Cr2O7
Term
Oxidative cleavage of an Alkene
 Definition
KMnO4 (there must be a vinylic H)
Term
Alkyl Hailide + NaCN
 Definition
C-X -> C-CN
Term
C-CN + NaOH
 Definition
C-(carboxylic acid)
Term
C=O-NH2 -SOCl2->
 Definition
CN
Term
CN + LiAlH4
 Definition
CNH2
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