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Test 2-Ch. 24 Nuclear Reactions
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26
Chemistry
Undergraduate 1
03/28/2011

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Term
Nuclear Reactions
Definition

-Reactions are accompanied by relatively large changes in energy and measurable changes in mass

-reaction rates depend only on number of nuclei and rarely based on the compound in which it occurs

Term
Isotopes
Definition

atoms with the characteristic number of protons of the element but different numbers of neutrons

-in nature, the isotopes of the element are present in specific proportions

Term
Intensity of Radiation
Definition
Directly proportional to the concentration of the element in the mineral, not to the nature of the mineral or compound, and is unaffected by temp, pressure or any other physical conditions
Term
Alpha Decay
Definition

Helium 2+ ion expelled

change in mass is -4

change in protons is -2

change in charge is -2
-Every element beyond Bi(z = 83) is radioactive and exhibits alpha decay

Term
Beta Decay
Definition

nucleus changes to a proton and a negative beta particle

change in mass = 0

change in protons = +1

change in charge = -1

Term
Positron Emission
Definition

a proton changes to a neutron and a positive beta particle

change in mass = 0

change in protons = -1

change in charge = +1

Term
Electron Capture
Definition

An electron and proton are changed into a neutron

change in mass = 0

change in proton = -1

change in charge = +1

 

 

Term
Gamma Emission
Definition
excited nucleus goes to a stable nucleus and emits a gamma photon
Term
Nuclear Stability- Odd or Even?
Definition

-elements with an even z usually have a larger number of stable nuclides than elements with and odd z.

-only four nuclides with odd N and odd z are stable: H(2/1), Li(6/3),B(10/5),N(14/7)

Term
Predicting Mode of Decay
Definition

-Neutron-rich nuclides= undergo beta decay

-Proton rich nuclides= undergo beta emission or electron capture

-Heavy nuclides(Z>83) undergo Alpha decay

Term
Decay Rate (A)
Definition
Decay rate(A) = -(delta nuclei)/(delta t)
Term
Unit of Radioactivity
Definition
1 curie(Ci) = 3.7*10^10 d/s (one disintegration per second)
Term
Decay Constant k
Definition

-larger the decay constant, the higher decay rate

A= (-delta nuclei)/(delta t) = k*nuclei

*ln(nuclei(t)/nuclei(0)) = -kt

*nuclei(t) = nuclei(0)*e^(-kt)

 

Term
Radioactive Decay Process
Definition

It is a first-order process

-in the case of nuclear decay the number of nuclei is considered rather than their concentrations

Term
Half-life
Definition

-the number of nuclei remaining is halved after each half-life

-t(1/2) = ln2/k

*dependent of number of nuclei

Term
Activity at Time = t
Definition

A(t) = A(0)*e^(-k*t)

 

Term
Radioactive Dating Equation
Definition
t = (1/k)*ln(A(0)/A(t))
Term
half-life of carbon 14
Definition
= 5730 yrs
Term
12C/14C after an organism dies
Definition
the ratio in a dead organism steadily increases because 14C decreases as it decays
Term
Einstein's Equation
Definition

E = mc^2

Delta(E) = Delta(m)*c^2

Term
Nuclear Binding Energy
Definition
The energy required to break 1 mol of atoms into neutrons and hydrogen atoms = the enegy to break 1 mol of nuclei into individual nucleons
Term
Electron Vold (eV)
Definition

The energy an electron acquires when it moves thru a delta(V) of 1 volt

 

1 eV = 1.602E-19J

 

Term
MeV or Mega eV
Definition
1 MeV = 10^6 eV = 1.602E-13 J
Term
1 amu to eVs
Definition
1 amu = 931.5E6 eV = 931.5 MeV
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