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REAGENTS-Alkene Rxns
alkenes
14
Chemistry
Undergraduate 2
10/14/2008
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Term
KOH
 Definition
Strong base- dehydrohalogenation of alkyl halides
Term
H3O+
 Definition
Dehydration of alcohols
Term
1)HX
2)ETHER
 Definition
Addition of HX
Term
1)X2(Cl2)
2)CH2Cl
 Definition
Addition of halogen
Term
1)X2(Cl2)
2)H2O
or (NBS/DMSO)
 Definition
Halohydrin formation
Term
1) Hg(oAc) H2O/THF
2)NaBH4
 Definition
Addition of H2O by oxymecuration
Term
1)BH3, THF
2)H2O2, OH-
 Definition
addition of H2O by Hydroboration/oxidation (N)
Term
H2+catalyst
 Definition
Hydrogenation
Term
1)OsO4
NaHSO4, H2O
 Definition
Hydroxylation
Term
CHCl3 + KOH
 Definition
Dichlorocarbene
Term
1)CH2I2
2)Zn(Cu)/ether
 Definition
Simmons-Smith
Term
1)O3
2)Zn/H3O+
 Definition
treatment with ozone
Term
KMnO4/H3O+
 Definition
Reaction with KMnO4 (acidic soln)
Term
1)HIO4
2)H2O
 Definition
Oxidative cleavage of 1,2-diols
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