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[image]
C=O next to the OH |
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| only reduces aldehydes and ketones |
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Reduces everything, strong reducer
reduces C=O to OH in aldehydes and ketones
Eliminates C=O and replaces with CH2 on everything else |
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| converts aldehyde into carboxylic acid! |
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| adds C=O onto carbon next to an OH |
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| converts an OH into a DASHED Br or Cl!! |
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| Reduction of an alkene into an expoxide |
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| KOTBu ( potassium tert butoxide ) |
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converts Br into an alkene
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[image]
DIBAL STOPS AT THE ALDEHYDE
ESTER TO ALDEHYDE |
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| TYPE 1 V TYPE 2 CARBONYLS |
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Type 1 : No LG
Type 2 : LG and Nucleophile ADDS TWICE |
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H2SO4 grabs a hydrogen from OH, beta hydrogen moves up and FORMS AN ALKENE
[image] |
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| how to kick off a leaving group and form an alkene! |
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BETA HYDROGEN ELECTRONS FALL DOWN AND CREATE AN ALKENE
[image] |
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ADD ONCE TO ACID CHLORIDES, ADD TO EPOXIDES
[image] |
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becomes H3O+ and HSO4- / makes an alkene into an OH [image]
MAKES AN OH ON THE MORE SUBSTITUTED INNER SIDE |
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Reduces C=O and adds an H
[image] |
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| Adds onto the OH to form SiClO(CH3CH2)3 |
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[image]
Turns carbonyl into alcohol and Ph (C6H5) |
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| ozonolysis of alkene using O3 and Me2S |
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[image]
produces FORMALDEHYDE (O=CH2) as a BYPRODUCT |
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| carboynl to alcohol to C---N addition ( enantiomeric ) |
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| Reverses the OH +CN additon back to the C=O |
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replaces Br with PPh3
The PPh3 replaces the BR
the substituent then can attach to the alkene
[image] |
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