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Organic Chemistry
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Organic Chemistry
Undergraduate 3
10/12/2011

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Term
Constitutional Isomers
Definition

Have the same molecular formual but a different connectivity of atoms in their molecules

 

Term
Stereoisomers
Definition

Have the same molecular formula and the same connectivity but different orientations of their atoms in space

Ex: Cis,trans isomers in cycloalkanes

Term
Configurational Isomers
Definition
Stereoisomerism in which the isomers have the same structure (same linkages between atoms) but different spatial arrangements of the atoms
Term
Enantiomers
Definition
Nonsuperposable mirror images (refers to the relationship between a pair of objects) -Must be chiral objects
Term
Chiral Center
Definition
a carbon atom with four different groups bonded to it and lacks the two key symmetry elements
Term
Stereocenter
Definition
an atom about which exchange of two groups produces a stereoisomer
Term
Diastereomers
Definition

Stereoisomers that are not mirror images of one another

-Can be chiral or achiral

Term
Conformational Isomerism
Definition
A form of stereoisomerism in which the isomers can be interconverted exclusively by rotations about formally single bonds
Term
Atropisomers
Definition
Isomers which lack a chiral center but do not interconvert because of hindered rotation
Term
Priority Rules
Definition

-Prioority is based on atomic number; higher number = higher priority

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