Shared Flashcard Set

Details

organic chemistry
review
33
Chemistry
Undergraduate 2
04/28/2009

Additional Chemistry Flashcards

 


 

Cards

Term
the condensation reaction between a carboxylic acid and an alcohol produces what two products?
Definition
ester and water
Term
adding water to split molecules
Definition
hydrolysis 
Term
physical properties of esters
Definition

- lower b.p/ melting point

- lower secondary forces than carboxylic acids

- weaker attractive forces

- lower polarity

- lower secondary attractive forces

- hydrogen bond well with water

- sweet fruity odor/ flavor

Term
nitrogenous bases in nucleic acids, the purines and pyrimidines, are classified as..
Definition
heterocyclic amines (contains and O2 or nitrogen atom in the ring)
Term
the water solubility of carboxylic acids and amines can be regulated by a solubility switch that can turn water solubility off and on for both types of molecules. the main determining factor of the switch is...
Definition

pH

 

 

NOT

- tempertature

- degree of mixing/ stirring

 

Term
nicotine is the active addictive amine found in tobacco, considered to be a mild CNS stimulant. the acute toxic dose of nicotine is surprisingly low, but smoking cigs reduces the amount of nicotine absorbed into the bloodstream. nicotine occurs in tobacco naturally as.....
Definition

a built-in insecticide, it protects the plant by killing bugs that might eat the leaves. 

 

NOT

- a built-in stimulant for the plants metabolism.

- a built-in depressant for the plant's metabolism.

 

Term
the principle molecule in the process by which cells use energy contains both ester and anhydride bonds made from phosphoric acid. this molecule is......
Definition
- ATP
Term
carboxylic acids are acids because......
Definition
- the carboxyl group donates a proton and becomes a carboxylate anion. 
Term
Highly reactive carboxylic acid derivative that consists of 2 carboxylic acid molecules that have a molecule of water removed is......
Definition
an Anhydride 
Term
alpha- hydroxy acids are commonly used in cosmetic products to treat dry flaky skin and to remove wrinkles. they work by eating away dead skin cells. what is an example of an alpha-hydroxy acid??
Definition

lactic acid

 

NOT 

- pyruvic acid

- propanoic acid

Term
a soap molecule....
Definition

- is a carboxylate salt

- is amphipathic

- has a nonpolar end and a polar end

Term
define enantiomers
Definition
- steroisomers that are nonsuperimposable mirror images of each other
Term
define diastereomers
Definition

stereoisomers that are not enantiomers= they aren't mirror images of each other

 

Term
monosaccharides/ function
Definition

- serve as building blocks

- synthesize larger saccharides

- can't be hydrolyzed into smaller saccharides

- taste sweet

- glucose, fructose, galactose

- can form H-bonds with themselves and H2O

Term
oligosaccharides functions
Definition

- larger than monosaccharides

- taste sweet

- sucrose/ lactose

Term
polysaccharide function
Definition

- hundreds to thousands of monosaccharides

- starch, cellulose, glycogen, chitin

Term
D-glucose
Definition

- most abundant monosaccharide in nature

- stored as glycogen in the liver

- blood sugar/dextrose

Term
D-fructose
Definition

- levulose, added to d-glucose to form dissaccharide sucrose

- in fruits and table sugar

Term
D- galactose
Definition
- bonded to D-glucose in the dissaccharide lactose (milk)
Term
aldose
Definition

- monosaccharides with an aldehyde group

- reducing sugar D/T the sugar being the reducing agent in the oxidation reaction

Term
ketose
Definition

- monosaccharide with a ketone

- reducing sugar D/T the sugar being the reducing agent in the oxidation reaction

Term
Maltose
Definition

- malt sugar, corn sugar

- hydrolysis of starch by amylase

- hydrolysis of maltose uses maltase (diglucose)

- reducing sugar

Term
cellobiose
Definition

- partial hydrolysis of cellulose from celluase

- reducing sugar

Term
lactose
Definition

-milk/ sugar in mammal milk

- energy source for the young

- D-galactose + D-glucose

- reducing sugar

- can inherit lactose intolerance

 

Term
sucrose
Definition

- most abundant in nature

- fruits/ veggies in diet

- table sugar

Term
digestion of maltose, lactose, and sucrose
Definition

- disaccharides can't be absorbed from the G.I tract

- must be digested to monosaccharides by maltase, lactase, and sucrase

Term
lipids
Definition

 -prodominant form of stored energy.

- come from animal fats/ plant walls

- exsess lipids that arent being used for energy= stored as fat

- soluble in non-polar/ low polarity solvents

- insoluble in WATER

Term

(lipid functions)

 

triacylglycerol

Definition
animal fat/ plant oil= stored energy not immediately used
Term

(lipid functions)

 

glycerophospholipids

Definition

cholesterol is primary structure that surrounds cells and organells.

-cell recognition

Term

(lipid functions)

 

steroid/ sex hormones

Definition
chemical messengers that alter activity in target cells
Term

(lipid functions)

 

lipid soluble vitamins

Definition
-A, D, E, K
Term

(lipid functions)

 

bile salts

Definition
needed for digestion of lipids in the G.I tract
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