Term
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Definition
Uses halogens with CH2Cl2
Creates Cyclic halonium ion and anti addition |
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Definition
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Term
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Definition
Uses mcpba???
Treatment of halohydrins and strong base
hydrolysis (acid catalyzed opening by H20) of epoxides to give 1,2-diols |
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Term
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Definition
Uses O3 first and (CH3)2S
Concerted syn addition with ozone
Cleavage of alkene double bond to give two carbonyl functional groups or compounds |
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Term
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Definition
Uses NaIO4, HO4I, or H5IO6
cyclic 1,2-diols must be cis to react
cleavage of 1,2-diol to give two carbonyl functional groups or compounds |
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Term
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Definition
Uses OsO4, HOOH, NMO
concerted syn addition of di-hydroxylation
creates 1,2-diols |
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Term
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Definition
Uses H2 with Pt or Pd
concentrated syn addition of H |
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Term
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Definition
uses first C4H12BO and H2O2, OH
H is added to most substituted carbon, boron adds to the less substituted carbon |
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Term
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Definition
Uses Hg(OAc)2, water, and NaBH4
creates a cyclic mercurinium ion
Markovnikov with OH to most substituted carbon
antiaddition |
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Term
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Definition
Uses two halogens and water
cyclic halonium ion
Markovnikov addition of OH to most substituted Carbon
anti addition |
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Term
| Hydration (acid catalyzed) |
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Definition
Uses a strong acid, such as H3O+ and water
OH on most substituted carbon, H on less substituted carbon |
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Term
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Definition
Uses H-halogen and water
Halogen on most substituted carbon, H on less substituted carbon |
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