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NEU GenChem 9/21-9/24 Toher
These cards cover most of the lecture notes for Northeastern University GenChem I from 9/21/09-9/24-09 with prof Toher
84
Chemistry
Undergraduate 1
09/27/2009

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Term
Define significant figures (aka sig figs)
Definition

Sig figs are used to determine which numbers in a measurement or calculation using measurement "count" or need to be reported for accuracy.

Term
How many rules for sig figs are there and what are they?
Definition

There are 5 rules regarding sig figs. They are: 1: All non-zero digits are sig. 2: Zeros between non-zeros are significant. 3: Zeros which preceed non-zero digits are not significant. 4: Zeros at the end of a number with a decimal place anywhere in the number are significant. 5: Zeros at the end of of a number not specifically mentioned in scientific notation are not significant.

Term
Are there any exceptions to the rules of sig figs and if so, what are they?
Definition

There is one exception which applies to rule #5. The base of the exception states that if there is a decimal place (such as 10.0) then both zeros are significant since the 0 typically would denote a rounded number.

Term
What are the rules for addition/subtraction of significant figures?
Definition
Sum/difference is reported to the number of decimal places as the measurement with the fewest decimal places. In the case of 15.8 - 14.73 3 sig figs would be used.
Term
What is the rule for reporting sig figs in regards to multiplication/division?
Definition

Like the addition/subtraction rule you simply take the least number of decimal places reported. Again, with a number of 3 sig figs and another of 4 the reported answer would have 3 sig figs.

Term
Define accuracy
Definition

Accuracy is defined as how close to the actual value a measurement is.

Term
Define precision
Definition

Precision is defined as how close together a set of measurements is.

Term
Define an atomic bond
Definition

An atomic bond is defined as the "glue" which is the attraction force which holds atoms together.

Term
Define a covalent bond
Definition

A covalent bond is defined as a bond in which electrons are shared between atoms (always a non-metal to another non-metal).

Term
Define an ionic bond
Definition
An ionic bond is defined as oppositely charged particles Coulombically attracted which is always between a metal and a non-metal (that is, always between a cation and an anion).
Term
What are columns of the periodic table called?
Definition

They're called groups or families.

Term
What do metals tend to form?
Definition
Metals tend to form cations by electron loss (oxidation).
Term
What to non-metals typically form?
Definition
Non-metals tend to form anions by electron gain (reduction).
Term
In nomenclature, what does the prefix "per" denote?
Definition
It means that the highest amount of oxygen possible is present.
Term
What does the prefix "hypo-" denote?
Definition
It indicates that the lowest amount of oxygen possible is present.
Term
What is so special about CrAsPS?
Definition

There is no per-ates and not hypo-ites. For example, PO4-3 becomes simply phosphate and PO3-3 becomes phosphite.

Term
If a compound ends in "-ide", what will its acidic name become?
Definition
It will become hydro-ic acid (ex: hydrochloric acid).
Term
Hydrogen
Definition
H+
Term
Lithium
Definition
Li+
Term
Sodium
Definition
Na+
Term
Potassium
Definition
K+
Term
Ammonium
Definition
NH4+
Term
Silver
Definition
Ag+
Term
Copper(I)
Definition
Cu+
Term
Mercury(I)
Definition
Hg2+2
Term
Magnesium
Definition
Mg+2
Term
Calcium
Definition
Ca+2
Term
Strontium
Definition
Sr+2
Term
Barium
Definition
Ba+2
Term
Zinc
Definition
Zn+2
Term
Cadmium
Definition
Cd+2
Term
Copper(II)
Definition
Cu+2
Term
Mercury(II)
Definition
Hg+2
Term
Chromium(II)
Definition
Cr+2
Term
Manganese(II)
Definition
Mn+2
Term
Iron(II)
Definition
Fe+2
Term
Cobalt(II)
Definition
Co+2
Term
Nickel(II)
Definition
Ni+2
Term
Tin(II)
Definition
Sn+2
Term
Lead
Definition
Pb+2
Term
Aluminum
Definition
Al+3
Term
Chromium
Definition
Cr+3
Term
Manganese
Definition
Mn+3
Term
Iron(III)
Definition
Fe+3
Term
Cobalt(III)
Definition
Co+3
Term
Nickel(III)
Definition
Ni+3
Term
Tin(IV)
Definition
Sn+4
Term
Lead(IV)
Definition
Pb+4
Term
Peroxide
Definition
O2-2
Term
Hydride
Definition
H-
Term
Fluoride
Definition
F-
Term
Chloride
Definition
Cl-
Term
Bromide
Definition
Br-
Term
Iodide
Definition
I-
Term
Hydroxide
Definition
OH-
Term
Hydrogen carbonate
Definition
HCO3-
Term
Hydrogen sulfate
Definition
HSO4-
Term
Hydrogen sulfite
Definition
HSO3-
Term
Thiocyanate
Definition
SCN-
Term
Cyanide
Definition
CN-
Term
Acetate
Definition
CH3COO- or C2H3O2-
Term
Nitrate
Definition
NO3-
Term
Nitrite
Definition
NO2-
Term
Permanganate
Definition
MnO4-
Term
Perchlorate
Definition
ClO4-
Term
Chlorate
Definition
ClO3-
Term
Chlorite
Definition
ClO2-
Term
Hypochlorite
Definition
ClO-
Term
Oxide
Definition
O-2
Term
Sulfide
Definition
S-2
Term
Selenide
Definition
Se-2
Term
Telluride
Definition
Te-2
Term
Carbonate
Definition
CO3-2
Term
Sulfate
Definition
SO4-2
Term
Thiosulfate
Definition
S2O3-2
Term
Oxalate
Definition
C2O4-2
Term
Chromate
Definition
CrO4-2
Term
Dichromate
Definition
Cr2O7-2
Term
Nitride
Definition
N-3
Term
Phosphide
Definition
P-3
Term
Arsenide
Definition
As-3
Term
Carbide
Definition
C-4
Term
Phosphate
Definition
PO4-3
Term
Phosphite
Definition
PO3-3
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