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Life 102
Macromolecules and Carbohydrates
38
Biology
Undergraduate 1
02/10/2009

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Term
Cells join smaller organic molecules together to form larger molecules called...
Definition
Macromolecules
Term
There are FOUR major classes of macromolecules:
Definition
1. Carbohydrates
2. Lipids
3. Proteins
4. Nucleic Acids
Term
Macromolecules form long, chainlike molecules called....
Definition
Polymers
Term
Polymers consist of many similar or identical builiding blocks (units) linked together by...
Definition
Covalent Bonds
Term
The repeated units are called...
Definition
Monomers
Term
Monomers are connected by covalent bonds via...
Definition
Condensation reaction or a dehydration reaction
Term
What forms water?
Definition
One monomer provides a hydroxyl group and the other provides a hydrogen...this process requires energy and is aided by ENZYMES.
Term
The COVALENT BONDS connecting monomers in a polymer are dissembled by...
Definition
Hydrolysis
Term
Hydrolysis...
Definition
As the covalent bond is broken, a HYDROGEN atom and HYDROXYL group from a split water molecule attaches where the covalent bond used to be.
Term
Sugars, the smallest carbohydrates, serve as what?
Definition
Serve as fuel and carbon sources
Term
What are the polymers of sugars?
Definition
Polysaccharides which have storage and structural roles
Term
What are the simplest carbohydrates?
Definition
Monosaccharides or simple sugars
Term
Carbohydrates include....
Definition
Monosaccharides, Dissacharides, and Polysaccharides
Term
Dissacharides are...
Definition
Double sugars, and consist of two monosaccharides joined by a condensation reaction
Term
Polysaccharides
Definition
Polymers of monosaccharides
Term
Monosaccharides have what two groups?
Definition
Carbonyl and multiple hydroxyl groups
Term
What happens in if the carbonyl group is at the end of a monosaccharide?
Definition
The sugar is an aldose and if not, then it is a ketose...

(most names for sugars end in -ose)
Term
What are some structural isomers?
Definition
Glucose (and aldose) and Fructose (a ketose)
Term
How else are monosaccharides classified?
Definition
By the number of carbons in the backbone

(5 carbon backbones are pentoses and 3 carbon sugars are trioses)
Term
Glucose and other sugars exist in what kind of form?
Definition
They exist in a RING structure
Term
When 2 monosaccharides are joined with a glycosidic linkage, it forms what?
Definition
It forms a dissaccharide via dehydration

(maltose, malt sugar, is formed by joining 2 glucose molecules)
Term
How is sucrose formed?
Definition
By the joining of glucose and fructose through a 1-2 glyosidic linkage
Term
Polysaccharides are...
Definition
polymers of hundreds to thousands of monosaccharides joined by glyosidic linkages
Term
What is one function of polysaccharides?
Definition
Energy storage macromolecule that is hydrolyzed as needed

(others serve as building materials for the cell or whole organism)
Term
What is starch?
Definition
Storage polysaccharide composed entirely of glucose monomers

(most monomers are joined by 1-4 linkages between the glucose molecules)
Term
One unbranched form of starch forms what?
Definition
A HELIX
Term
What is an example of a branched form of starch?
Definition
Amylopectin, which is more complex than an unbranched form
Term
Where do plants store starch?
Definition
Within plastids and chloroplasts
Term
Plants can store a surplus of.....in starch
Definition
GLUCOSE and withdraw it when needed for energy or for carbon source

(animals that feed on plants, can also use this starch to support their own metabolism)
Term
Animals store glucose polymers in the form of what?
Definition
Glycogen which is highly branched like Amyopectin

(humans and other vertebrates store glycogen in the liver and muscle tissues)
Term
What is the primary monomer used in polysaccharides?
Definition
GLUCOSE
Term
What is one KEY DIFFERENCE among polysaccharides that develops from 2 possible ring structures of glucose?
Definition
These 2 ring forms differ in whether the hydroxyl group attached to the number 1 carbon is fixed above (beta glucose) or below (alpha glucose) the ring plane
Term
Starch is a polysaccharide of what?
Definition
ALPHA GLUCOSE MONOMERS
Term
What is a major component of the tough cell wall of plant cells?
Definition
CELLULOSE

(it is also a polymer of glucose monomers, but using beta rings)
Term
Polymers built with ALPHA glucose form helical structures, polymers built with BETA glucose form what?
Definition
STRAIGHT STRUCTURES

(this allows H atoms on one strand to form hydrogen bonds with OH groups on other strands)
Term
When enzymes digest starch, they cannot what?
Definition
hydrolyze the beta linkages in cellulose
Term
How do some microbes digest cellulose to its glucose monomers?
Definition
Through the use of cellulase enzymes
Term
What kind of relationships with cellulolytic microbes do many eukaryotic herbivores (like cows) have?
Definition
SYMBIOTIC RELATIONSHIPS

(this allows them access to this rich source of energy from cellulose)
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