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Environmental Science - 1
Environmental Science - Weeks 1 - 5 (test 1)
170
Science
Post-Graduate
03/14/2014

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Term
Energy
Definition
The driving force bringing about a change or result in a system that would not have otherwise changed

The ability to work (the ability to transfer energy)
Term
First Law of Thermodynamics
Definition
Energy cannot be created or destroyed
Total energy remains the same, after work has been done (or a chemical reaction has taken place)
No energy is lost; only transformed
Term
Second Law of Thermodynamics
Definition
In energy transformation, some energy is always dispersed and degraded to a less usable form
No energy transformation can be 100% efficient
Energy cannot ever be reused at the same level
Energy transfer - hotter objects give up heat to cooler objects spontaneously
Term
Entropy
Definition
the degree of dispersion or disorder in a system
entropy will always increase in the universe as a whole - you can reduce entropy and maintain order somewhere, but somewhere else it will be increased
Term
Temperature of a planet depends on...
Definition
Luminosity of the sun
Distance from the sun (zone of habitability)
Albedo
Presence of an atmosphere
Composition of atmosphere
Objects between the plant & sun
Orbital features
Term
Distance of Earth from Sun
Definition
152 000 000 km - 147 000 000 km average 149 600 000 km
Term
Obliquity of Earth
Definition
23.5 degrees
Term
Speed of Earth
Definition
29.8km/s
Term
Diameter of Earth
Definition
12,756km
Term
Temperature of Earth
Definition
-70 degrees C to +55 degrees C
Average of 16 degrees C on the surface
Term
Age of the planet / life on the planet
Definition
4600 million years / 3500 million years
Term
Composition of the earth by mass
Definition
Iron 34.6%
Oxygen 29.5%
Silicon 15.2%
Magnesium12.7%
Nickel 2.4%
Sulphur 1.9%
Titanium 0.05%
Term
Energy is measured in ...
Power is measured in ...
Electrical energy is measured in...
Definition
Joules
Watts (Joules per second)
kWh (kilowatt hours - 3.6 000 000 joules)
Term
Exergy
Definition
Available or usable energy
Term
Radiation
Definition
Giving off energy
Term
Energy transfer
Definition
Energy tends to move spontaneously from areas of greater energy to areas of less energy unless there is a barrier
Hotter objects give up heat to cooler ones.
(Second law of thermodynamics)
Term
Ionising radiation
Definition
Short wavelength UV, X and gamma rays create ions; a charged atom/molecule through gain/loss of electrons
Damaging to biological molecules
Term
Absorption/reflection of EM radiation depends on....
Definition
Albedo
Angle of EM radiation
Shape of object
Term
EM radiation interacts with objects by being....
Definition
Absorbed
Transmitted
Reflected
but it cannot change an object
Term
EM waves are most effective when...
Definition
They hit an object at 90 degrees
Term
Insolation
Definition
Total energy arriving from the sun
Term
Insolation varies with...
Definition
Time of day - greatest at midday
Latitude - greatest at equator
Season - greatest in summer
Term
Location of the tropics
Definition
23.5 degrees N
23.5 degrees S
..of the equator
Term
Climactic zones are caused by...
Definition
uneven receipt of solar radiation
Term
Climactic zones are...
Definition
Polar
Tropical
Temmperate
Term
Seasons are caused by...
Definition
Tilt of the earth

Eccentricity of orbit makes southern hemisphere seasons more extreme
Term
Perihelion
Definition
Closest point in the earth's orbit to the sun
Term
Aphelion
Definition
Furthest point in the earth's orbit to the sun
Term
Solstices are...
Definition
The longest day of the year (in summer)
The shortest day of the year (in winter)

(Applies outside the tropics)
Term
Equinoxes are...
Definition
When hours in the day = hours in the night

The Earth's told is neither inclined away nor towards the Sun
Term
System
Definition
Something to be studied, around which there is a boundary
Consists of subsystems/components
Term
Closed system
Definition
No components to the system cross the boundary
Term
Open system
Definition
Things can go in and out of the system; crossing its boundaries
Term
Earth - closed or open system?
Definition
Open system in terms of energy
Closed in terms of matter
Term
Feedback
Definition
Communication in a system to maintain stability/homeostasis/constant internal condition
Term
Feedback regulation process
Definition
Detector detects variance from equilibrium
Signals to Effector
Effector brings about change
System indicates detector
Term
Positive feedback
Definition
The enhancing or amplification of an effect by its own influence on the process which gives rise to it
Term
Negative feedback
Definition
Diminution of an effect by a system's own influence on the process giving rise to it
Where the result of a certain action may inhibit further performance of that action - to try and maintain equilibrium
Term
Climate change as negative feedback
Definition
Increase in average temperature through increase in CO2
Ice melts
Reduction of albedo
Increase in average temperature
Term
Atmosphere
Definition
Collection of gases around a planet
Term
5 advantages of our atmosphere
Definition
Oxygen
Pressure
Radiation protection
Temperature regulation
Shield against meteors
Term
Composition of the atmosphere
Definition
Nitrogen 78%
Oxygen 21%
Argon 0.09%
Carbon Dioxide 0.037%
Term
Gravity
Definition
The attractive force between two bodies in the universe with mass.
Directly proportional to the product of their masses and inversely proportional to the square of the distance between them
Term
Mass
Definition
Total amount of matter of on object
Term
Weight
Definition
Measure of mass on the surface of the Earth; mass with Earth's gravity acting upon it
Term
Atmospheric pressure
Definition
Pressure exerted by the weight of the atmosphere
Term
Boiling point
Definition
The point at which the vapour pressure of the liquid equals the pressure surrounding it
Boiling occurs when vapour pressure of the liquid becomes sufficient to overcome atmospheric pressure and allow bubbles of vapour to form inside the bulk of the liquid
Term
Evaporation
Definition
Molecules located near the liquid's edge, not contained by enough liquid pressure on that side, escape into the surroundings as vapor.
Term
Sublimation
Definition
A substance goes from a solid to a gaseous state without first becoming a liquid
Term
EMR: relationship between wavelength and energy
Definition
Wavelength is inversely proportional to energy
Short wavelengths = higher energy
Hot objects emit shorter wavelengths
Term
Wavelength of visible light
Definition
400 - 700 nanometres 10^-9
Term
Temperature on the surface of the moon
Definition
~120 degrees celsius in the sun
~ -140 degrees celsius in the shade
Term
Why is the temperature on the surface of the moon so extreme?
Definition
Lack of an atmosphere to regulate temperature
Lack of oceans to regulate temperature
13-14 days of continuous day/night
Term
Albedo
Definition
A measure of an objects reflectivity of EM radiation

1 = perfect reflector
0 = perfect black body absorber
Term
Earth's albedo
Definition
~ 0.33
Term
Why is Earth's temperature 16 degrees rather than -18 as expected?
Definition
Atmosphere presence and composition
Regulating temperature
Natural greenhouse effect
Oceans regulating temperature
Term
Greenhouse gases
Definition
1. Greenhouse gases are gases in the atmosphere that allow short wavelength radiation from the sun to pass through and heat the Earth's surface

2. The gases absorb longer wavelength radiation - thermal infrared - emitted from the Earth

3. This heat is then re-radiated by the gases in all directions, heating up the lower atmosphere and the Earth's surface


Examples: H2O, CFCs, Methane and CO2
Term
The greenhouse effect
Definition
1. Solar radiation largely at frequencies of visible light pass through the atmosphere and heat the Earth

2. Earth radiates at the lower frequencies of infrared thermal radiation

3. Infrared radiation is absorbed by greenhouse gases, which in turn re-radiate much of the energy to the surface and lower atmosphere
Term
Life
Definition
Life is a process that distinguishes living things from dead and inanimate things.
The process occurs in living things manifested by the requirement of energy from the external environment, the capacity for growth, reproduction, functional activity, expulsion of waste products, and continual change preceding death
Term
Characteristics of life (12)
Definition

Metabolism (continuous, heat generating chemical processes)
Continuous expenditure of energy
Information storage and retrieval (nucleic acids)
Organised exchange of materials with the external environment
Propagation/spread/replication/reproduction
Adaptation (evolution)/ Responsiveness to the environment
Death 

Alteration of external conditions to make more favourable Carbon-based macro-molecules

Internal organisation (compartmentalisation) which requries continuous energy to be maintained

Term
4 types of matter
Definition
Living organisms
Dead organisms
Products of biogenic origin
Inanimate objects
Term
Schrodinger, life & second law of thermodynamics
Definition
Living matter avoids the decay into equilibrium; they postpone the trend toward increasing entropy (the spread out of energy increases)
Death is submission of the body to the entropy of the universe
Living things resist entropy through the process of taking in energy for activities and expelling waste byproducts
Term
Carbon-based life
Definition
Life as we know it is based on carbon.
Complex molecules are made up of carbon, bonded with other elements, especially oxygen, hydrogen and nitrogen,
Term
Functional groups
Definition
Clusters of atoms in a molecule with characteristic functions/structure
Term
Polymers
Definition
Large compounds of identical or nearly identical repeating subunits (monomers)
Term
Condensation
Definition
Process of making polymers by eliminating a water molecule
(Hydroxyl from one monomer, hydrogen from another)

Dehydration synthesis
Term
Hydrolysis
Definition
A reaction breaking apart polymers by introducing a water molecule
Term
Chemical composition of carbohydrates
Definition
C H O
Term
Chemical composition of proteins
Definition
C H O N S
Term
Lipids
Definition
C H (a little oxygen)
Term
Nucleic Acids
Definition
C H O N P
Term
Combustion
Definition
ignition source + carbon-based fuel + oxygen e.g. fire
Term
Respiration
Definition
Process where organisms obtain energy from organic compounds
Term
Aerobic respiration
Definition
Carbon containing fuel (usually glucose) + oxygen -> carbon dioxide and energy
(an exergonic reaction - releases energy)
All living things perform respiration all the time
Term
Exergonic reaction
Definition
Releases energy
Term
Endergonic reaction
Definition
Requires energy
Term
Oxidation
Definition
Process of combining molecules with oxygen usually exergonic (releases energy)
Oxygen breaks the C-H bonds to make CO2 and H2O
e.g. respiration and combustion
Term
Photosynthesis
Definition
A biochemical process performed by the green parts of plants
Happens at the same time as respiration
Only happens when there is light
Plants obtain glucose from the process
Term
Carbohydrates
Definition

Saccharides. Molecular compounds containing carbon, hydrogen and oxygen

 Components of other molecules e.g. DNA, RNA, glycolipids

Term
Saccharides
Definition
Carbohydrates
Term
Disaccharides
Definition
Simple sugars; small carbohydrate molecules
formed in a condensation reaction between two monosaccarides (releasing water)
Most sugars in nature are disaccharides
e.g. sucrose, lactose, maltose
Term
Monosaccharides
Definition
Simple sugars; small carbohydrates
(CH2O)n (n=3-7)
e.g. glucose
Term
Polysaccharides
Definition
Large carbohydrate molecules
Characterised by length, extent of branching, folding, straightness or coiling
e.g. glycogen, starch and cellulose
Term
Glucose
Definition
C6H12O6
Hexose (six carbons) monosaccharide
Most important fuel to human cells
Soluble
Energy is released in respiration/metabolisation of glucose
C6H12O6 + 6xO2 -> 6CO2 + H2O + energy
Term
Alpha glucose
Definition
Hydrogen is 'up', hydroxyl is 'down' on carbon atom #1
Term
Beta glucose
Definition
Hydroxyl is 'up', hydrogen is 'down' on carbon atom #1
Term
Triose
Definition
Carbon monosaccharide containing 3 carbons
Term
Pentose
Definition
Carbon monosaccharide containing 5 carbons
Term
Hexose
Definition
Carbon monosaccharide containing 6 carbons
Term
Aerobic respiration/ metabolism of glucose
Definition
C6H12O6 + 6xO2 -> 6CO2 + H2O + energy
Term
Numbering of carbon atoms in carbohydrates
Definition
Starts on the right, going clockwise
Term
Polymer of alpha glucose
Definition
Starch
Glycogen
Term
Polymer of beta glucose
Definition
Cellulose
Term
Glucose structure
Definition
[image]
Term
Formation of proteins from amino acids
Definition
[image]
Term
How do enzymes work?
Definition
[image]
Term
Protein folding
Definition
[image]
Term
Starch is a polymer of ....
Definition
Alpha glucose
Term
Starch is produced in/from...
Definition
Plants
Term
Starch is used as ...
Definition
A compact storage of glucose
Term
Starch bonds are formed....
Definition
Between carbon atom 1 and carbon atom 4 of alpha glucose monomers, by an oxygen atom
Hydrogen from one end plus hydroxyl from the other, form water as a by-product
Term
By-product of condensation reaction
Definition
Water
Term
Types of bonds in starch
Definition
1-4 bonds (amylose) some 1-6 bonds (amylopectin; starch with branches)
Term
Two forms of starch
Definition
Amylose (all 1-4 bonds) and amylopectin (some 1-6 bonds)

Amylopectin is insoluble, amylose is partially soluble
Term
Is starch soluble in water?
Definition
Amylose is partially soluble
Amylopectin is insoluble (has branches; 1-6 bonds)
Term
Glycogen is a polymer of ...
Definition
alpha glucose
Term
Glycogen structure ...
Definition
has 1,4 and 1-6 bonds (oxygen between the carbons)
has many side branches
Term
Glycogen is used...
Definition
as the storage carbohydrate of animals
Term
Difference between glycogen and starch
Definition
Glycogen is amylopectin (has side branches), as is one form of starch, however, glycogen side branches are much closer together
Starch is found in plants
Glycogen is found in animals
Term
Cellulose
Definition
Beta glucose polymer
Most common organic molecule
Term
Cellulose purpose..
Definition
Structural
Term
Cellulose is found in...
Definition
Cell walls
Plant fibre and wood (50% of wood; other material is lignin)
Term
Wood is made of...
Definition
Cellulose and lignin
Term
Characteristics of cellulose
Definition
Strength - due straight bondings between monomers and hydrogen bonding between chains
Not hydrolysed easily
Insoluble and indigestible to humans
Term
Digestibility of cellulose
Definition
Indigestible to humans and most animals
Herbivores require an enzyme called cellulase and microbes in the stomach to digest it
Term
Mutualism
Definition
Symbiosis - two organisms of different species in a mutually beneficial relationship
Term
Dietary fibre is...
Definition
Cellulose
Term
Fructose
Definition
C6H12O6
A monosaccharide and an isomer of glucose
Term
Isomer
Definition
Same chemical formula, different structure/arrangement of atoms
Term
Sucrose
Definition
C12H22O11
alpha glucose + alpha fructose
isomer of lactose
disaccharide
Term
Lactose
Definition
C12H22O11
alpha glucose + beta galactose
isomer of sucrose
disaccharide
Term
Protein
Definition
Polymers of amino acids containing C H O N S
Term
Amino acids
Definition
a simple organic compound containing both a carboxyl (-COOH) and an amino (-NH2) group.
Term
Carboxyl group
Definition
e.g. Carboxylic acid on the end of an amino acid molecule
COOH molecule
Term
Amino group
Definition
NH2
on one end of an amino acid molecule
Term
R group
Definition
Variable group
On an amino acid, there can be 20 group combinations which give each amino acid different characteristics, contains sulphur
Can be charged or repelling
Term
Peptide bond
Definition
Bond between two amino acids
Formed by a condensation reaction (water is removed)
Carboxylic acid joins with an amino group with by product of water
Term
Dipeptide
Definition
two amino acid molecules joined together by a peptide bond
Term
Tripeptide
Definition
three amino acid molecules joined together by a peptide bond
Term
Polypeptides
Definition
polymers of amino acids joined together by peptide bonds
Term
Amino acid structure
Definition
Amino group (NH2) positive charge
Carboxyl group (COOH) negative charge
Central carbon atom
R group (variable; containing sulphur)
Term
Protein chain folding
Definition
Due to charged nature of the molecules
If two groups contain sulphur, they can form a sulphide bridge/link
Ionic bonds can form due (+ve charge attracts a -ve)
Term
Purpose of protein (5)
Definition
1. Structural (connective tissues, cell membranes, keratin)
2. Enzymes (biological catalysts)
3. Transport (haemoglobin to carry oxygen)
4. Movement (actin and myosin in muscle)
5. Immune system (antibodies; immunoglobulins, are proteins)
Term
Enzymes
Definition

Large globular proteins that act as biological catalysts

Lock and key 'fit' of enzymes with substrates
A specific enzyme is designed to fit only the substrates in the reaction that the enzyme is meant to control 

 

Term
Catalyst
Definition
Substances that accelerate chemical reactions (reducing the energy barrier) but which remain unchanged or unused in the process
Term
How do enzymes work?
Definition
An enzyme has a specific shape to 'hold onto' the specific substrate it is working on and convert it into a product
Term
Substrate
Definition
The molecule an enzyme is 'working on'
Term
Product
Definition
The end molecule(s) that result from an enzyme working on the substrates
Term
Binding/active site
Definition
The active part of the enzyme where the reactions take place
Term
Denature
Definition
Polypeptides/proteins can be denatured by pH and temperature; changing its shape When proteins are denatured, they lose their normal shape/configuration and cannot perform their normal function
Term
Lipids
Definition
Fats/oils, fatlike substances and some vitamins and steroids
Term
Lipid use/purpose
Definition
Primarily energy sources and structural compounds
Term
Characteristics of lipids (2)
Definition
1 Hydrophobic/ insoluble
2 Large number of bonded hydrogens (more energy stored because more hydrogen - carbon bonds)
Term
Major lipids
Definition
Triglycerides (fats and oils)
Term
Triglycerides
Definition
Fat and oils - three fatty acids joined to a glycerol molecule
Fatty acids:
- saturated
- unsaturated
Term
Fatty acids
Definition
long hydrocarbon chains with terminal carboxyl group (COOH)
Saturated fatty acids - no double bonds between carbons
Unsaturated fatty acids - double bonds between carbons
Term
Saturated fatty acids
Definition
no double bonds between carbons of a long hydrocarbon chain with terminal carboxyl group (COOH)
Term
Unsaturated fatty acids
Definition
double bonds between carbon atoms in the carbon chain (fatty acids are long hydrocarbon chains with a carboxyl group at the end COOH)
Term
Glycerol
Definition
Three carbon molecule
Term
Fats
Definition
Triglycerides containing saturated fatty acids (e.g. butter = solid at room temperature)
Term
Oils
Definition
Triglycerides containing unsaturated fatty acids (e.g. oil = liquid at room temperature)
Term
Phospholipids
Definition
Another group of major lipids
Two fatty acids attached to a phosphate group
Phosphate heads are hydrophilic (water soluble)
Phosphate tais are hydrophobic (water insoluble)
Therefore they spontaneously form a lipid bi-layer
These form biological membranes
Term
Nucleic Acids
Definition
Polymers of nucleotides
Term
Nucleotide make up
Definition
Made up of:
1. Phosphate group PO4
2. 5 carbon sugar called ribose (or deoxyribose)
3. Nitrogenous base (ring structure containing C & N)
Term
Nucleotide functions
Definition
Metabolic functions in cells:
1. Coenzymes are molecules that facilitate enzymatic reactions
2. ATP (adenosine triphosphate) - universal energy carrying molecule
3. Nucleic acid monomers
Term
Examples of nucleic acids
Definition
DNA (deoxyribonucleaic acid)
RNA (ribonucleic acid)
Term
DNA
Definition
deoxyribonucleic acid - the molecule which stores the genetic information passed on from parent to offspring
Term
RNA
Definition
ribonucleic acid - serves as the translator of the genetic information contained in DNA
Term
Specificity
Definition
Lock and key 'fit' of enzymes with substrates
A specific enzyme is designed to fit only the substrates in the reaction that the enzyme is meant to control
Term
Active site
Definition
The region of the enzyme that interacts with the substrate
Term

Carbon

 

Definition
Carbon has an ability to form four chemical bonds with other elements at the same time.
It has 4 valence electrons - 4 electrons in the outer shell that enables this bonding

Term
Valency
Definition

The number of electrons in the outer shell enabling bonds to form with other atoms 

Carbon has 4, oxygen has 2

Term
Hydrocarbons
Definition
Long chains of carbon atoms, also bonding with hydrogen around the outside
Term
Subsolar point
Definition
Where the sun is perceived to be directly overhead (in zenith)
Where the sun's rays are hitting the planet exactly perpendicular to the surface.
Term
Tropic of Capricorn
Definition
Southernmost latitude where the sun can be directly overhead
23degrees 26' south of the equator
Term
Tropic of Cancer
Definition
Northernmost latitude where the sun can be directly overhead
23 degrees 26' north
Term
Subsolar point max/min latitudes
Definition
Tropic of Capricorn (south) and Cancer (north)
Term
June solstice
Definition
When the sub solar point is on the Tropic of Cancer
Term
March and September equinoxes
Definition
When the sub solar point is on the equator
Term
December solstice
Definition
When the sub solar point is on the Tropic of Capricorn
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