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internal corrosion #1
Interanal Corrosion Test 1
22
Other
Professional
09/25/2013

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Cards

Term
*Controlled by the formation of iron carbonate on the metal surface *Can cause pitting if the protective scale is damaged *Forms carbonic acid *Corrosion rate is affected by temp., velocity, pressure, pH *aka "sweet corrosion"
Definition
CO2 Corrosion
Term
*Can produce iron sulfide as a by-product
*Damages metal by causing embrittlement to hard alloys & blistering to softer alloys

*Unaffected by velocity
*aka "sour corrosion"
Definition
H2S
Term
*Exist when fertilizers contact metal surfaces
*inhibited using water
*in the form of SCC
*Can be reduced by stress relieving storage tanks before exposure to this corrosive substance
Definition
Ammonia Corrosion
Term
*includes chemicals (acetic acid, propionic acid, formic acid)

*weak compared to hydrochloric and sulfuric acid
Definition
Organic Acid corrosion
Term
*very localized attack
*formation of biofilm
*controlled in pipelines by regular pigging

*controlled using biocide chemicals
*if found it water, may not indicate there is a problem on the surface of the steel
Definition
MIC
Term
*result from stresses related to welding processes

*accelerated by stress concentrations, material properties, fabrication, and weld size and quality

*remedies-use of proper weld procedures, correct cooling procedures, proper technique
Definition
Weldment Corrosion
Term
*requires tensile stress, specific environmental conditions, and a specific set of metallurgical factors

*increased levels of zinc in carbon steel alloys reduce this corrosion

*well bonded coating will prevent this form of corrosion externally

*low, near neutral or high pH electrolytes are susceptible to this corrosion
Definition
SCC
Term
*dependent mainly on the temp. and chemical concentration of the corrodent

*slightly corrosive at low temps and low flow velocities

*under concentrations above 70% it can be handled w/ ordinary carbon steel

*below 70%, chemical lead is commonly utilized
Definition
Sulfuric Acid Corrosion
Term
*similar to wet chlorine corrosion
*encountered in bleaching, sanitizing, deodorizing, and waste treatment applications

*sodium version = liquid bleach
*calcium version = bleaching powder
*lower temp. will greatly reduce the corrosion rate of this corrodent
Definition
Hypochlorite Corrosion
Term
*encountered when it made form ammonia
*colorless, corrosive, toxic liquid
*important industrial raw material that even attacks copper and high carbon 304 stainless steel
Definition
Nitric Acid Corrosion
Term
*involves the gas that is considered the most corrosive

*can be removed mechanically or chemically

*found in surface equipment
*use of plastic materials or internally plastic coating is common practice when this corrosion is expected

*cement lining is also effective
Definition
Oxygen Corrosion
Term
*caused by a greenish yellow gas or liquid

*utilized in water purification, bleaches, and mustard gas

*used in swimming pools
*attack iron, steel, aluminum, nickel, stainless steel, copper, and titanium

*attack is minimized if the corrodent is kept dry except in the case of titanium corrosion where the corrodent should be kept wet
Definition
Chlorine Corrosion
Term
*one of the few that attacks glass
*corrodent can only be stored in plastic or Teflon containers

*corrodent is utilized to purify aluminum and uranium
Definition
Hydrogen Fluoride Corrosion
Term
Sulfuric
Definition
H2SO4
Term
AMMONIA
Definition
NH3
Term
CARBONIC
Definition
H2CO3
Term
NITRIC
Definition
HNO3
Term
HYDROCHLORIC
Definition
HCL
Term
HYDROFLUORIC
Definition
HF
Term
ACETIC
Definition
CH3COOH
Term
FORMIC
Definition
HCOOH
Term
PROPIONIC
Definition
CH3CH2COOH
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