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Inorganic Final Review
Review of inorganic chemistry for final exam- CHEM 317 University of Richmond
21
Chemistry
Undergraduate 2
04/26/2010

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Cards

Term
How to balance a redox reaction
Definition
  1. Separate into ox and red half-reactions
  2. Mass balance
  3. Add oxygen by adding H2O
  4. Balance oxygen with H+
  5. Add electrons to balance charges on both sides
  6. Multiply both sides by opposite number of electrons
  7. Add half-reactions together
  8. IF IN BASIC SOLUTION- add OH- to neutralize H+ on both sides (so H2O will be on one side, OH- on the other)
Term
E0 cell=
Definition
E0redn -E0oxidn
Term
Bond Order (molecular orbital theory)
Definition

# electrons in bonding orb's - # electrons in antibonding

2

Term
6 strong acids
Definition
HI, HBr, HCl, H2SO4, HNO3, HClO4
Term
What makes a strong acid a strong acid?
Definition
Completely dissociates in aqueous solution
Term
Difference between strong acid/weak acid rxns and strong base/weak base rxns
Definition
Use a --> for strong acids/ bases because they dissociate/associate completely.  Use <==> for weak acids and bases since they have an equilibrium
Term
Dissociation of HOAc in water
Definition
H+ + OAc-
Term
Spectator ions: cations and anions
Definition

Cations: Group I and IIA

Anions: Bases of strong acids

Term
strong bases (yield weak acids when you add a proton)
Definition
NH2-, O-2, S-2
Term
Acid strength: bond polarity
Definition

In H-X bonds, the more polar the bond is (more electronegative X is) then the stronger the acid

(F>O>N)

Term
Strength of acids: bond strength
Definition

Weaker bond --> better acid

as size increases, bond strength decreases, acid strength increases

Term
Strength of oxyacids
Definition
More oxygens (higher oxidation state of Y in HO-Y), then stronger acid
Term
Acid strength: metal ions
Definition

Smaller the metal with the same charge, stronger acid

Co+3 is smaller than Fe+3, so stronger acid

Term
Acid strength: substituents
Definition
Electron withdrawing (electronegative (CF3)) are stronger acids
Term
Base strength: sterics
Definition

If there are too many big ligands on a base, then it will become less basic

This can compensate for base strengthening effects, such as addition of methyl groups (which donate electrons)


Term
Hard acids (14)
Definition

Small with large positive charge ( mostly +3 or larger)

H+, Li+, Na+, K+, Be+2, Mg+2, Ba+2, Al+3, Me3Al, AlCl3, Cr+3, Mn+2, Fe+3, Co+3

Term
Soft bases (9)
Definition

More electrons and larger size

I-, H2S, HS-, S-2, SCN-, CN-, CO, PR3, R3As

Term
Soft acids (7)
Definition
BH3, Cu+, Ag+, Au+, Pd+2, Pt+2, Pd+4 
Term
Hard bases (10)
Definition
F-, Cl-, H2O, OH-, O-2, NO3-, ClO4-, NH3, RHN2, N2H4
Term

Bigger oxidation state:

Bigger size:

Definition

Bigger oxidation state: hard

Bigger size: soft

Term
Molecular Orbital Diagram
Definition
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