Shared Flashcard Set

Details

Infared Spectroscopy
Wade Organic Chapter 12
18
Organic Chemistry
Undergraduate 2
09/22/2014

Additional Organic Chemistry Flashcards

 


 

Cards

Term

C-H BOND

STRETCHING FREQUENCY

Definition
~3000 cm-1
Term

C-D

STRETCHING FREQUENCY

Definition
2100 cm-1
Term
C-C
Definition
~1200 cm-1
Term

C=C

STRETCHING FREQUENCY

Definition
1660 cm-1
Term
C≡C
Definition
2200 cm-1
Term
C-N
Definition
~1200 cm-1
Term
C=N
STRETCHING FREQUENCY
Definition
~1650 cm-1
Term

C≡N

STRETCHING FREQUENCY

Definition
2200 cm-1
Term

C-O

STRETCHING FREQUENCY

Definition
1100 cm-1
Term

C=O

STRETCHING FREQUENCY

Definition
1700 cm-1
Term

sp3 hybridized, one-fourth s character

STRETCHING FREQUENCY

Definition
~2800-3000 cm-1
Term

sp2 hybridized, one-third s character

STRETCHING FREQUENCY

Definition
~3000-3100 cm-1
Term

sp hybridized, one-half s character

STRETCHING FREQUENCY

Definition
3300 cm-1 (sharp)
Term

Alcohol O-H 

STRETCHING FREQUENCY

Definition

3300 cm-1, very broad

also shows a C-O stretching peak at ~1050 cm-1

Term

Carboxylic acid O-H

STRETCHING FREQUENCY

Definition
3000 cm-1, broad
Term

amine N-H

STRETCHING FREQUENCY

Definition

3300 cm-1, broad with spikes 

will not show C-O peak 

2 spikes for primary amine

1 spike for secondary amine

0 spike for tertiary amine

Term

Aldehyde 

STRETCHING FREQUENCY

Definition

2 C-H peaks at ~2700-2800 cm-1

C=O (~1710 cm-1)

Term
Peak at around ~1599-1600 cm-1
Definition
C=C bonds, indicating an aromatic ring is attached
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