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General Chemistry
Fundamentals of Chemistry - Ch 1-6 Whitten, Davis, Peck 6th Ed
179
Chemistry
Undergraduate 1
08/18/2008

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Term
matter
Definition
anything that has mass and occupies space
Term
energy
Definition
the capacity to do work or to transfer heat
Term
kinetic energy
Definition
the energy of motion
Term
potential energy
Definition
energy an object possesses because of its position, condition, or composition
Term
exothermic process
Definition
a process that releases energy (heat) into the environment
Term
endothermic process
Definition
a process that absorbs energy (heat) from the environment
Term
Law of Conservation of Matter
Definition
there is no observable change in the quantity of matter during a chemical reaction or during a physical change
Term
scientific (natural) law
Definition
a general statement based on the observed behavior of matter to which no exceptions are known
Term
Law of Conservation of Energy
Definition
energy cannot be created or destroyed in a chemical reaction or in a physical change. It can only be converted from one form to another.
Term
Law of Conservation of Energy and Matter
Definition
the combined amount of matter and energy in the universe is fixed (related to Newton's 2nd Law E=mc^2)
Term
solid
Definition
a state of matter in which substances are rigid and have definite shapes; very difficult to compress
Term
liquid
Definition
a state of mater in which substances flow and assume the shape of containers up to the volume of the liquid; difficult to compress
Term
gas
Definition
a state of matter in which substances occupy all parts of containers; easily compressed and expanded
Term
chemical properties
Definition
characteristics of matter as it undergoes chemical changes; e.g., the rxn that occurs when metallic magnesium combines with gaseous oxygen
Term
physical properties
Definition
characteristics of matter with no changes in chemical composition; e.g., color, hardness, density, melting point, etc.
Term
extensive properties
Definition
properties that depend on the amount of material present in the sample; e.g., volume and mass
Term
intensive properties
Definition
properties that are independent of the amount of material present in the sample; all chemical properties are intensive
Term
chemical change
Definition
a reaction in which 1) one or more substances are used up (at least partially), 2) one or new substances are formed, and 3) energy is absorbed or released
Term
physical change
Definition
a change in which a substance changes from one physical state to another, but no substances with different compositions are formed; energy is absorbed or released
Term
mixture
Definition
a combination of two or more pure substances in which each substance retains its own composition and properties
Term
heterogeneous mixture
Definition
a mixture that does not have uniform composition and properties throughout
Term
homogeneous mixture/solution
Definition
a mixture that has uniform composition and properties throughout
Term
Classification of Matter
Definition
[image]
Term
characteristics of any mixture
Definition
1) the composition can be varied and 2) each component of the mixture retains its own properties
Term
substance
Definition
any kind of matter, all specimens of which have the same chemical composition and physical properties
Term
compound
Definition
a substance that can be decomposed by chemical means into simpler substances, always in the same ratio by mass
Term
element
Definition
a substance that cannot be decomposed into simpler substances by chemical changes
Term
Law of Definite Proportions (aka Law of Constant Composition)
Definition
different samples of any pure compound contain the same elements in the same proportions by mass; this corresponds to atoms of these elements in fixed numerical ratios
Term
mass
Definition
the measure of the quantity of matter a body contains
Term
weight
Definition
a measure of the gravitational attraction of a body to Earth (or other such object)
Term
primary SI units of measurement: mass, length, volume
Definition
kilogram, meter, cubic meter
Term
accuracy
Definition
how closely a measured value agrees with the correct value
Term
precision
Definition
how closely individual measurements agree with one another
Term
dimensional analysis
Definition
calculation based problem solving
Term
unit factor method
Definition
a technique used to perform unit conversions
Term
density
Definition
mass per unit volume; D = m/V
Term
specific gravity
Definition
the ratio of the density of a substance to the density of water, both at the same temperature
Term
density of water
Definition
1.000 g/mL at 3.98˚C
Term
temperature
Definition
measures the intensity of heat of a body
Term
heat
Definition
a form of energy; always flows spontaneously from a hotter body to a colder body (never reverse)
Term
Kelvin (K)
Definition
the basic unit of temperature in the SI system
Term
joule (J)
Definition
the SI unit of energy and work; defined as 1 kg·m2/s2
Term
calorie
Definition
a unit of heat energy defined as 4.184J; originally defined as the amount of heat required to raise the temperature of one gram of water from 14.5˚C to 15.5˚C
Term
specific heat
Definition
the amount of heat required to raise the temperature of one gram of a substance by one degree Celsius (or kelvin) with no change in phase
Term
heat capacity
Definition
the amount of heat required to raise the temperature of a body 1˚C.
Term
temperature scale conversions
Definition
˚F = 1.8˚C+32˚; ˚C = (˚F - 32˚)/1.8; K = ˚C+273
Term
allotropic modifications (allotropes)
Definition
different forms of the same element in the same physical state
Term
anhydrous
Definition
without water
Term
anion
Definition
an ion with a negative charge
Term
atom
Definition
the smallest particle of an element that maintains its chemical identity through all chemical and physical changes
Term
atomic mass unit (amu)
Definition
one twelfth of the mass of an atom of the carbon-12 isotope; a unit used for stating atomic formula weights
Term
atomic number
Definition
the number of protons in the nucleus of an atom
Term
atomic weight
Definition
weighted average of the masses of the constituent isotopes of an element; the relative mass of atoms of different elements
Term
Avogadro's number
Definition
6.022 x 1023 units of a specified item
Term
Cation
Definition
ion with a positive charge
Term
chemical formula
Definition
combination of symbols that indicates the chemical composition of a substance
Term
composition stoichiometery
Definition
describes the quantitative (mass) relationships among elements in compounds
Term
empirical formula/simplest formula
Definition
the smallest whole-number ratio of atoms present in a compound
Term
formula unit
Definition
the smallest repeating unit of a substance - for non-ionic substances, the molecule
Term
formula weight
Definition
the mass, in atomic mass units, of one formula unit of a substance. Numerically equal to the mass, in grams, of one mole of the substance. This number is obtained by adding the atomic weights of the atoms specified in the formula
Term
hydrate
Definition
a crystalline sample that contains water and another compound in a fixed mole ratio. Examples include: CuSO4 * 5H2O and (COOH)2 * 2H2O
Term
ion
Definition
an atom or group of atoms that carries an electric charge (cations and anions)
Term
ionic compound
Definition
a compoun that is composed of cations and anions; example: sodium cloride, NaCl
Term
Law of Multiple Proportions
Definition
when two elements, A and B, form more than one compound, the ratio of the masses of element B that combine with a given mass of element A in each of the compounds can be expressed by small whole numbers
Term
molar mass
Definition
the mass of a substance in one mole of the substance; numerically equally to the formula weight of the substance
Term
mole
Definition
6.022 x 1023 (Avogadro's number of) formula units (or molecules, for a molecular substance) of the substance under discussion; the mass of one mole, in grams, is numerically equal to the formula (molecular) weight of the substance
Term
molecular fomula
Definition
a formula that indicates the actual number of atoms present in a molecule of a molecular substance
Term
molecular weight
Definition
the mass, in atomic mass units, of one molecule of a nonionic (molecular) substance. Numerically equal to the mass, in grams, of one mole of such a substance; this number is obtained by adding the atomic weights of the atoms specified in the formula
Term
molecule
Definition
the smallest particle of an element or a compound that can have a stable independent existence
Term
percent composition
Definition
the mass percentage of each element in a compound
Term
percent purity
Definition
the mass percentage of each element in a compound
Term
polyatomic
Definition
consisting of more than one atom; element examples: Cl2, P4, and S8; ion examples: ammonium ion, NH4+, and sulfate ion, SO42-
Term
stoichiometry
Definition
description of the quantitative relationships among elements in compounds (composition stoichiometry) and among substances as they undergo chemical changes (reaction stoichiometry)
Term
structural formula
Definition
a representation that shows how atoms are connected in a compound
Term
actual yield
Definition
the amount of a specified pure product actually obtained from a given reaction
Term
chemical equation
Definition
description of a chemical reaction by placing the formulas of reactants on the left and the formulas of products on the right of an arrow; it must be balanced - that is, it must have the same number of each kind of atom on both sides
Term
concentration
Definition
the amount of solute per unit volume or mass of solvent or of solution
Term
dilution
Definition
the process of reducing the concentration of a solute in a solution, usually simply by adding more solvent
Term
limiting reactant
Definition
a substance that stoichiometrically limits the amount of product(s) that can be formed
Term
molarity (M)
Definition
the number of moles of solute per liter of solution
Term
percent by mass
Definition
100% multiplied by the mass of a solute divided by the mass of the solution in which it is contained
Term
percent yield
Definition
100% times actual yield divided by theoretical yield
Term
products
Definition
substances produced in a chemical reaction
Term
reactants
Definition
substances consumed by a chemical reaction
Term
reaction ratio
Definition
the relative amounts of reactants and products involved in a reaction; may be the ratio of moles, or masses
Term
reaction stoichiometry
Definition
description of the quantitative relationships among substances as they participate in chemical reacions
Term
sequential reaction
Definition
a chemical process in which several reaction steps are required to convert starting materials into products
Term
solute
Definition
the dispersed (dissolved) phase of a solution
Term
solvent
Definition
the dispersing medium of a solution
Term
theoretical yield
Definition
the maximum amount of a specified product that could be obtained from specified amounts of reactants, assuming complete consumption of the limiting reactant according to only one reaction complete recovery of the product
Term
acid
Definition
a substance that produces H+ (aq) ions in aqueous solution; strong acids ionize completely or almost completely in dilute aqueous solution; weak acids ionize only slightly
Term
acid-base reaction/neutralization reaction
Definition
the reaction of an acid with a base to form a salt; often, the reaction of hydrogen ions with hydroxide ions to form water molecules
Term
active metal
Definition
a metal that readily loses electrons to form cations
Term
activity series
Definition
a listing of metals (and hydrogen) in order of decreasing activity
Term
alkali
Definition
elements of Group IA in the periodic table, except hydrogen
Term
alkaline earth metals
Definition
Group IIA elements in the periodic table
Term
base
Definition
a substance that produces OH- (aq) ions in aqueous solution; strong bases are soluble in water and are completely dissociated; weak bases ionize only slightly
Term
binary acid
Definition
a binary compound in which H is bonded to a nonmetal in Group VIIA or a nonmetal other than oxygen in Group VIA
Term
binary compound
Definition
a compound consisting of two elements; may be ionic or molecular
Term
chemical periodicity
Definition
the variation in properties of elements with their positions in the periodic table
Term
combination reaction
Definition
reaction in which two substances (elements or compounds) combine to form one compound
Term
decomposition reaction
Definition
reaction in which a compound decomposes to form two or more products (elements, compounds, or some combination of these)
Term
displacement reaction
Definition
a reaction in which one element displaces another from a compound
Term
disproportionation reaction
Definition
a redox reaction in which the oxidizing agent and the reducing agent are the same element
Term
dissociation
Definition
in aqueous solution, the process in which a solid ionic compound separates into its ions
Term
electrolyte
Definition
a substance whose aqueous solutions conduct electricity
Term
formula unit equation
Definition
an equation for a chemical reaction in which all formulas are written as complete formulas
Term
gas-formation reaction
Definition
a metathesis reaction in which an insoluble or slightly soluble gas is formed as a product
Term
group (family)
Definition
the elements in a vertical column of the periodic table
Term
halogens
Definition
Group VIIA elements in the periodic table
Term
ionization
Definition
in aqueous solution, the process in which a molecular compound separates to form ions
Term
metal
Definition
an element below and to the left of the stepwise division (metalloids) of the periodic table; about 80% of the known elements
Term
metalloids
Definition
elements with properties intermediate between metals and nonmetals: B, Si, Ge, As, Sb, Te, Po, and At
Term
metathesis reaction
Definition
a reaction in which the positive and negative ions in two compounds "change partners," with no change in oxidation numbers, to form two new compounds
Term
net ionic equation
Definition
an equation that results from cancelling spectator ions from a total ionic equation
Term
noble (rare) gases
Definition
elements of Group VIIIA in the periodic table
Term
nonelectrolyte
Definition
a substance whose aqueous solutions do not conduct electricity
Term
nonmetals
Definition
elements above and to the right of the metalloids in the periodic table
Term
oxidation
Definition
an increase in oxidation number; corresponds to a loss of electrons
Term
oxidation-reduction reaction/redox reaction
Definition
a reaction in which oxidation and reduction occur
Term
oxidation numbers/oxidation states
Definition
arbitrary numbers that can be used as mechanical aids in writing formulas and balancing equations; for single-atom ions they correspond to the charge on the ion; less metallic atoms are assigned negative oxidation numbers in compounds and polyatomic ions
Term
oxidizing agent
Definition
the substance that oxidizes another substance and is reduced
Term
period
Definition
the elements in a horizontal row of the periodic table
Term
periodic law
Definition
the properties of the elements are periodic functions of their atomic numbers
Term
periodic table
Definition
an arrangement of elements in order of increasing atomic number that also emphasizes periodicity
Term
precipitate
Definition
an insoluble solid that forms and separates from a solution
Term
precipitation reaction
Definition
a reaction in which a solid (precipitate) forms
Term
pseudobinary ionic compound
Definition
a compound that contains more than two elements but is named like a binary compound
Term
reducing agent
Definition
the substance that reduces another substance and is oxidized
Term
reduction
Definition
a decrease in oxidation number; corresponds to a gain in electrons
Term
reversible reaction
Definition
a reaction that occurs in both directions; described with double arrows
Term
salt
Definition
a compound that contains a cation other that H+ and an anion other than OH- or O2-
Term
semiconductor
Definition
a substance that does not conduct electricity at low temperatures but does so at higher temperatures
Term
spectator ions
Definition
ions in solution that do not participate in a chemical reaction; they do not appear in net ionic equations
Term
strong acid
Definition
an acid that ionizes (separates into ions) completely, or very nearly completely, in dilute aqueous solution
Term
strong electrolyte
Definition
a substance that conducts electricity well in dilute aqueous solution
Term
strong base
Definition
metal hydroxide that is soluble in water and dissociates completely in dilute aqueous solution
Term
ternary acid
Definition
a ternary compound containing H, O, and another element, usually a nonmetal
Term
ternary compound
Definition
a compound consisting of three elements; may be ionic or molecular
Term
total ionic equation
Definition
an equation for a chemical reaction written to show the predominant form of all species in aqueous solution or in contact with water
Term
weak acid
Definition
an acid that ionizes only slightly in dilute aqueous solution
Term
weak base
Definition
a molecular substance that ionizes only slightly in water to produce an alkaline (base) solution
Term
weak electrolyte
Definition
a substance that conducts electricity poorly in dilute aqueous solution
Term
absorption spectrum
Definition
the spectrum associated with the absorption of electromagnetic radiation by atoms (or other species) resulting from transitions from lower to higher energy states
Term
alpha (a) particle
Definition
a helium ion with a 2+ charge; an assembly of two protons and two neutrons
Term
angular momentum quantum number (l)
Definition
the quantum mechanical solution to a wave equation that designates the subshell, or set of orbitals (s, p, d, f), within a given main shell in which an electron resides
Term
anode
Definition
in a cathode-ray tube, the positive electrode
Term
atomic orbital
Definition
the integral number of protons in the nucleus; defines the identity of an element
Term
Aufbau ("building up") Principle
Definition
a guide for predicting the order in which electrons fill subshells and shells in atoms
Term
Balmer-Rydberg equation
Definition
an empirical equation that relates wavelengths in the hydrogen emission spectrum to integers
Term
canal ray
Definition
a stream of positively charged particles (cations) that moves toward the negative electrode in a cathode-ray tube; observed to pass through canals in the negative electrode
Term
cathode
Definition
in a cathode-ray tube, the negative electrode
Term
cathode ray
Definition
the beam of electrons going from the negative electrode toward the positive electrode in a cathode-ray tube
Term
cathode-ray tube
Definition
a closed glass tube containing a gas under low pressure, with electrodes near the ends and a luminescent screen at the end near the positive electrode; produces cathode rays when high voltage is applied
Term
continuous spectrum
Definition
the spectrum that contains all wavelengths in a specified region of the electromagnetic spectrum
Term
d orbitals
Definition
beginning in the third shell, a set of five degenerate orbitals per shell, higher in energy than s and p orbitals in the same shell
Term
degenerate orbitals
Definition
two or more orbitals that have the same energy
Term
diamagnetism
Definition
weak repulsion by a magnetic field; associated with all electrons being paired
Term
electromagnetic radiation
Definition
energy that is propagated by means of electric and magnetic fields that oscillate in directions perpendicular to the direction of travel of the energy
Term
electron
Definition
a subatomic particle having a mass of 0.00054858 amu and a charge of 1-
Term
electron configuration
Definition
the specific distribution of electrons in the atomic orbitals of atoms and ions
Term
electron transition
Definition
the transfer of an electron from one energy level to another
Term
emission spectrum
Definition
the spectrum associated with emission of electromagnetic radiation by atoms (or other species) resulting from electron transitions from higher to lower energy states
Term
excited state
Definition
any energy state other than the ground state of an atom, ion, or molecule
Term
f orbitals
Definition
beginning in the fourth shell, a set of seven degenerate orbitals per shell, higher in energy than s, p, and d orbitals in the same shell
Term
ferromagnetism
Definition
the property that allows a substance to become permanently magnetized when placed in a magnetic field; exhibited by iron, colbalt, and nickel
Term
frequency (v)
Definition
the number of crests of a wave that pass a given point per unit time
Term
fundamental particles
Definition
subatomic particles of which all matter is composed; protons, electrons, and neutrons are fundamental particles
Term
ground state
Definition
the lowest energy state or most stable state of an atom, molecule, or ion
Term
Heisenberg Uncertainty Principle
Definition
it is impossible to determine accurately both the momentum and position of an electron simultaneously
Term
Hund's Rule
Definition
each orbital of a given subshell is occupied by a single electron before pairing begins
Term
isotopes
Definition
two or more forms of atoms of the same element with different masses; that is, atoms containing the same number of protons but different number of neutrons
Term
line spectrum
Definition
an atomic emission or absorption
Term
magnetic quantum number (ml)
Definition
quantum mechanical solution to a wave equation that designates the particular orbital within a given subshell (s, p, d, f) in which an electron resides
Term
mass spectrometer
Definition
an instrument that measures the charge-to-mass ratios of charged particles
Term
natural radioactivity
Definition
spontaneous decomposition of an atom
Term
neutron
Definition
a subatomic nuclear particle having a mass of 1.0087 amu and no charge
Term
nucleus
Definition
the very small, very dense, positively charged center of an atom containing protons and neutrons, except for 11H
Term
nuclide symbol
Definition
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