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Term
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Definition
lithium: attain 2 valence electrons
beryllium: attain 4 valence electrons
boron: bonds to attain 6 valence electrons
elements in period 3 and below: expand valence shell to include more than 8 electrons by incorporating d subshell orbitals |
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one or more electrons from an atom with lower ionization energy are transferred to an atom with greater electron affinity and the electrostatic force of attraction between opposite charges holds the resulting ions together
difference in electronegativities must be greater than 1.7
usually occurs between Group 1 or Group 2 and Group 7
very high melting and boiling points: because of the strength of electrostatic forces between ionic constituents of the compound
dissolve readily in polar solvents (aqueous); in molten or aqueous state = good conductors
solid state: form a crytallin lattice in which attractive forces between opposite charges are maximized and repulsive forces between ions of like chargers are minimized |
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an electron pair is shared betwen 2 atoms which have relatively similar values of electronegativity
binding force between the atoms is the attraction that each electron in the shared pair has for the 2 positive nuclei of the bonded atoms
lower melting and boiling points: because weak intermolecular interactions
poor conductors of electricity: because they don't break down into constituent ions |
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| Bond Length vs. Bond Strength |
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single bond: longest and weakest
triple bond: shortest and strongest |
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| when atoms that have identical or nearly identical electronegativities share electron pairs with equal distribution of the electrons |
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atoms of elements that differ moderately in their electronegativities will share their electrons unevenly
difference in electronegativities: between 0.4 - 1.7 |
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| Polar Covalent bond: dipole moment (μ) |
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Definition
vector quantity defined as the product of the charge magnitude and the distance between the 2 partial charges
μ = qr |
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