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Gen. Chem. Ch. 17.5 - 17.7
Complex ion equilibria
8
Chemistry
Undergraduate 1
03/17/2008

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Term

Complex ion (539)

Definition
An ion formed from a metal ion with a Lewis base attached to it by a coordinate covalent bond.
Term
Ligand (539)
Definition
A Lewis base that bonds to a metal ion to form a complex ion.
Term

Formation Constant/ Stability Constant

(Kf) 

Definition
The equilibrium constant for the formation of the complex ion from the aqueous metal ion and the ligands.
Term

Formation Constant (Kf) example:

What is the Kf of Ag(NH3)2+?

Definition
Kf = [Ag(NH3)2+] / [Ag+][NH3]2
Term
What does a large Kf mean?
Definition

The complex ion is quite stable.

Term
Dissociation Constant (Kd) (539)
Definition
The reciprocal, or inverse, value of Kf.
Term

The equation for the dissociation of Ag(NH3)2+

is?


The dissociation equilibrium Constant?
Definition

Ag(NH3)2+(aq)  --><-- Ag+(aq) + 2NH3(aq)


Kd = 1 / Kf = [Ag+][NH3]2 / [Ag(NH3)2+]

Term

Amphoteric Hydroxides (pg. 540)

 

Definition
Metal hydroxide that reacts with both bases and acids. Zinc is and example.
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