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Gen Chem 2 Elements and Groups
Chapter 21 & 22
89
Chemistry
Undergraduate 1
04/28/2011

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Cards

Term
What element has the isotope tritium?
Definition
Hydrogen
Term
What are three ways hydrogen is prepared in a lab?
Definition
Metal + Acid, Metal + Water, Metal Hydride + Water
Term
How is hydrogen produced industrially
Definition
Sythesis Gas (C + H20 -> H2 + CO

Catalytic Steam Reforming (CH4+H2O -> H2 + CO
Term
What are the three types of hydrides?
Definition
Ionic metal hydrides, Covalent hydrides and Interstitial Hydrides
Term
How does reactivity change in groups 1 and 2 on the periodic table?
Definition
Reactivity increases with atomic weight, or reactivity increases as you move down the group.
Term
What two ways are Alkali Metals prepared? Briefly describe the processes.
Definition
Downs Cell Electrolysis
eg. 2NaCl -> 2 Na + Cl2

Redox
eg. Na(g) + KCl (l) -> K(g) + NaCl
Term
In general, how do boiling point and melting point change in a group of the periodic table?
Definition
As atomic weight increases, boiling point and melting point both generally decrease. Or as you move down the periodic table boiling point and melting point generally decrease.
Term
How does density change in a group of the periodic table?
Definition
Generally as atomic weight increases density increases, or as you move down the group density increases.
Term
What element is used in batteries, depression meds and greases?
Definition
Lithium
Term
What element is used in soap, salt, baking soda and nerve impulses?
Definition
Sodium
Term
What are the three primary nutrients?
Definition
Nitrogen, Phosphorus and Potassium
Term
Which two of the Alkali metals are most common in the crust?
Definition
Potassium and Sodium
Term
Which two of the Alkaline Earth Metals are most common in the crust?
Definition
Magnesium and Calcium
Term
What is used to produce Magnesium? Briefly describe the process.
Definition
Magnesium chloride is filtered out from seawater and is heated in the presence of lime to produce magnesium hydroxide, an insoluble solid. This solid is converted back to Magnesium chloride through a reaction with HCl. Finally magnesium chloride is converted to magnesium through electrolysis.
Term
Which group is more soluble: Group 1 or Group 2?
Definition
Group 1
Term
Do the elements of groups 1 and 2 produce acidic, basic or neutral oxides?
Definition
Basic
Term
True or False, the elements of group 2 can be found in their elemental state in nature.
Definition
False, they are always found combined and must be converted to their elemental state.
Term
How does ionic radii change in the periodic table?
Definition
Ionic radii decreases as you move right across a period and increases as you move down a group.
Term
Which element is used in x-ray tubes and atomic weapons?
Definition
Beryllium
Term
Which element is used in lightweight alloys, chlorophyll, and organic synthesis?
Definition
Magnesium
Term
Which poisonous element is used in x-ray imaging?
Definition
Barium
Term
Which element causes old watches to glow?
Definition
Radium
Term
What is the chemical formula for limestone?
Definition
CaCO3
Term
What is the chemical formula for lime?
Definition
CaO
Term
What element is related to muscle contraction and blood clotting?
Definition
Calcium
Term
Which group 13 element is one of the most common in the crust?
Definition
Alluminum
Term
How is aluminum produced? Briefly describe the process.
Definition
Hall-Heroult process
Bauxite(Al2O3)and Cryolite (Na3AlF6) undergo electrolysis at high temperature to separate Al from oxygen. Molten Al produced. Oxygen is produced at the carbon anode producing CO2 and eventually destroys the electrode.
Term
Which element is found in gemstones, implicated in Alzheimers and used in rocket fuel?
Definition
Aluminum
Term
Which group 13 element is known for being a good reducing agent?
Definition
Aluminum
Term
Which element is used in flame retardants, insecticides, and cosmetics?
Definition
Boron
Term
Which group 14 element is one of the ten most common in the crust?
Definition
Silicon
Term
Which element is found in sand, asbestos and quartz?
Definition
Silicon
Term
How is silicon produced? Briefly describe the process.
Definition
Silicon Dioxide reacts with Carbon to form liquid silicon and carbon monoxide. The liquid silicon then reacts with chlorine gas because it is not pure enough. SiCl4 then reacts with magnesium to produce Magnesium chloride and solid silicon.
Term
Which element is used in integrated circuits, glass and antifoaming agents?
Definition
Silicon
Term
What is the name of group 15?
Definition
Pnictogens
Term
Which group 15 elements produce acidic oxides and which produce basic oxides?
Definition
Acidic: N, P
Basic: Bi
Term
Which group 15 element has oxidation states from +5 to -3?
Definition
Nitrogen
Term
Which Pnictogen is known for its 3 allotropes? Describe the allotropes.
Definition
Phosphorus
White/Yellow - Toxic, waxy solid that burns in air
Red - Polymerized P4
Black - Most stable, complex polymeric structure
Term
Which element is used in detergents, fertilizer, metal finishing and cheese?
Definition
Phosphorus
Term
Which element is needed for plant growth and is found in amino acids?
Definition
Nitrogen
Term
Which element is used in blood buffering, DNA, RNA, ATP and bone?
Definition
Phosphorus
Term
What are the biological effects of Arsenic?
Definition
Trace amounts needed to inhibit enzymes.
Term
What is the most common element in the crust?
Definition
Oxygen
Term
What three things is oxygen found most present in?
Definition
Air, Water and Minerals
Term
What process is used to isolate sulfur? briefly describe the process.
Definition
Frasch Process
Superheated H2O and air react with sulfur deposits.
Term
Which element is used to perm or relax hair?
Definition
Sulfur - specifically breaking and remaking disulfide bonds
Term
What is the name of the group 16 elements?
Definition
Chalcogens
Term
Which element is needed to prevent muscular problems but in excess causes "blind staggers" in animals?
Definition
Selenium
Term
What are two types of medicine that sulfur is used in?
Definition
Penicillin and Sulfa Drugs
Term
Which two Calcogens are found in amino acids?
Definition
Oxygen and Sulfur
Term
Which two Chalcogens are found in amino acids?
Definition
Oxygen and Sulfur
Term
How does reactivity change in group 17 of the periodic table?
Definition
Reactivity decreases as you move down the group (or as atomic weight increases.)
Term
Which element was first discovered in sponges?
Definition
Iodine
Term
What is the most reactive element?
Definition
Fluorine
Term
How are halogens prepared?
Definition
The oxidation of halides
eg. NaCl -> NaOH + Cl2
Term
At STP in what state are each of the halides naturally found?
Definition
Gas: F, Cl
Liquid: Br
Solid: I
Term
Which halide has oxidation states from -1 to +7 and is found in PVC and fireworks?
Definition
Chlorine
Term
What is the main biological use of fluorine?
Definition
Tooth hardening
Term
Which halogen is used in saline solution?
Definition
Chlorine
Term
Which halogen is used in hydroperoxidase enzymes?
Definition
Bromine
Term
Which element is concentrated in the thyroid?
Definition
Iodine
Term
True or False, The Noble gases are found in high abundance.
Definition
False.
eg. Argon makes up roughly 1% of air by volume.
Term
Which noble gas forms a few compounds despite having a filled valence shell?
Definition
Xenon
Term
How was helium first discovered?
Definition
First discovered on the sun through the use of a spectroscope.
Term
Which element is known for its orange-red light?
Definition
Neon
Term
Which element is used in welding, light bulbs and metal production?
Definition
Argon
Term
Match the noble gas with the meaning of its name.

1. He
2. Ne
3. Ar
4. Xe

A. Stranger
B. Light
C. Inactive
D. New
Definition
1. B.
2. D.
3. C.
4. A.
Term
How is Radon formed?
Definition
Through radioactive decay.
Term
Which groups make up the early transition metals? What are two characteristics of most early transition metals?
Definition
4-6

Oxophilic (found as oxides) and less stable (air sensitive)
Term
Which groups make up the late transition metals and what are two characteristics of most late transition metals?
Definition
8-10

Thiophilic (found as sulfides)and More stable
Term
What are the two common oxidation states of transition metals and what are some examples of elements in these states?
Definition
+2 and +3

Element (Charge)
Mn(2+), Fe (3+), Ni (2+)
Term
What are two examples of transition metals with oxidation states +6 or higher?
Definition
Oxidation State - Element (Charge)
+6 - CrO4(2-)
+7 - MnO4 (-)
Term
What are the three main steps of metal production?
Definition
1. Reduce metal to elemental form
2. Remove impurities
3. Alloy formation
Term
Which elements are ferromagnetic?
Definition
Iron, Nickel and Cobalt
Term
What is the difference between paramagnetism, diamagnetism and ferromagnetism?
Definition
Paramagnetism - unparied electrons cause it to become magnetic in the presence of a magnetic field.
Ferromagnetic - Permanent magnet
Diamagnetic - No unpaired electrons, not magnetic.
Term
Under what condition do d-orbitals have different energy levels?
Definition
In the presence of a ligand. Distribution of energy depends on the shape.
Term
What transition metal is used in pigments, lubricants, catalysts, corrosion inhibitors and fertilizer?
Definition
Molybdenum
Term
What biological effect does Cromium have?
Definition
Cr(6+) is carcinogenic, but Cr(3+) is necessary for glucose regulation.
Term
What element is found in hemoglobin, myoglobin, and cytochromes?
Definition
Iron
Term
Which element is found in ferritins and ferredoxins?
Definition
Iron
Term
Which element is found in plant and animal enzymes?
Definition
Manganese
Term
Which element is found in vitamin B12?
Definition
Cobalt
Term
Which transition metal is used as a bactericide?
Definition
Silver
Term
Which element is found in proteins, used in iron regulation and used to carry oxygen?
Definition
Copper
Term
In coordinate bonding, which component functions as a Lewis acid?
Definition
The metal cation functions as a Lewis acid. The ligand, with its electron pair, functions as a Lewis base.
Term
If a coordination of a copper ion and ammonia involves 6 ammonia molecules, what is the coordination number?
Definition
The coordination is 6 because there are 6 ammonia ligands bonded (via coordinate covalent bond) to the Cu ion.
Term
What is the process for creating ammonia called? Briefly describe the process.
Definition
Haber Process
Nitrogen gas reacts with Hydrogen gas to form ammonia.
Term
What two acids combine to make aqua regina? What does aqua regina do?
Definition
Nitric acid and hydrochloric acid
Aqua regina makes noble water which dissolves the noble metals including silver and gold.
Term
What are the 10 most abundant elements in the Crust (starting with most abundant)
Definition
1. Oxygen
2. Silicon
3. Aluminum
4. Iron
5. Calcium
6. Sodium
7. Magnesium
8. Potassium
9. Titanium
10. Hydrogen
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