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Fire Behavior & Chemistry of Fire
Chapter 2 (FDNY Proby Manual)
15
Other
Professional
02/23/2016

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Term
Fire is...
Definition
...the result of a rapid combustion reaction.
Term
Combustion is...
Definition
...the self-sustaining process of rapid oxidation of a fuel, which produces heat and light.
Term
flammable or explosive limits
Definition
The % of a substance (vapor) in air that will burn once it is ignited. Most substances have an upper (too rich) and a lower (too lean) flammable limit.
Term
flash point
Definition
The minimum temperature at which a liquid fuel gives off sufficient vapors to form an ignitable mixture with the air near the surface. At this temperature, the ignited vapors will flash but will not continue to burn.
Term
ignition temperature
Definition
the minimum temperature to which a fuel in air must be heated to start self-sustained combustion without a separate ignition source
Term
Heat can travel throughout a burning building by one or more of 3 methods:
Definition
1. conduction
2. convection
3. radiation
Term
conduction
Definition
Direct contact. Example: A basement fire that heats pipes enough to ignite the wood inside walls several rooms away. Aluminum, copper, and iron are good conductors. Fibrous materials like felt, cloth, and paper are poor conductors. Liquids, gas and air are poor conductors of heat.
Term
convection
Definition
The transfer of heat by the movement of air or liquid. Heated air in a building will expand and rise, so fire spread by convection is mostly in an upward direction. Direct flame contact is a form of convective heat transfer.
Term
radiation
Definition
Heat travel where matter does not exist. Radiation of heat waves. Example: us being warmed by the Sun. Heat waves are longer than light waves.
Term
Fire Tetrahedron
Definition
1. oxygen (oxidizing agent) (~16% required. Normal air contains 21%)
2. fuel (solid, liquid, or gas [only gases burn])
3. heat
4. self-sustaining chemical reaction
Term
3 phases of fire
Definition
1. incipient
2. steady-state
3. hot smoldering
Term
Class A Fuels
Definition
ordinary combustible materials (wood, cloth, paper, rubber, many plastics)
Term
Class B Fuels
Definition
Flammable and combustible liquids and gases like gasoline, oil, lacquers, paints, mineral spirits, and alcohol (liquids, greases, gases).
Term
Class C Fuels
Definition
Live electrical equipment like household appliances, computers, transformers, and overhead transmission lines.
Term
Class D Fuels
Definition
Combustible Metals (aluminum, magnesium, titanium, zirconium, sodium, potassium, lithium, calcium, zinc)
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