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exam 2 reagents
n/a
33
Chemistry
Undergraduate 3
03/26/2013
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Term
SN1
 Definition
weak Nu (solvent)
Term
SN2
 Definition
strong base/Nu
Term
E1
 Definition
weak base
Term
E2
 Definition
strong base/bulky base
Term
Reduction of Aldehyde
 Definition
NaBH4/MeOH or LAH/H3O+
Term
Reduction of Ketone
 Definition
NaBH4/MeOH or LAH/H3O+
Term
Reduction of Carboxylic acids and derivatives
 Definition
LAH/ H3O+
Term
oxidation of 1. alcohol ending in aldehyde
 Definition
PCC
Term
oxidation of 2. alcohol ends in ketone
 Definition
PCC or CrO3
Term
oxidation of 1. alcohol ends in carboxylic acid
 Definition
CrO3 or KMnO4
Term
t-butyl ether synthesis
 Definition
isobutylene gas and acid catalyst
Term
E1/dehydration
 Definition
H2SO4 or H3PO4
Term
ether clevage of ether
 Definition
HBr or HI (conc)
Term
ether clevage of t-butyl ether
 Definition
CF3CO2H
Term
synthesis of alkyl bromides
 Definition
PBr3
Term
synthesis of alkyl chlorides
 Definition
SOCl2
Term
Synthesis of tosylates
 Definition
tosylates
Term
hemiacetals/acetals formation
 Definition
alcohol, H+
Term
imine formation
 Definition
primary amine, H+
Term
synthesis of amines
 Definition
H2 and Pd/C or NaBH4
Term
Alcohol synthesis via grignard
 Definition
a.R-Mg-Br
b. H3O+
Term
formation of acid chloride
 Definition
SOCl2
Term
formation of anhydride
 Definition
carboxylate anion
Term
esterification
 Definition
acid catalyst
Term
formation of amide
 Definition
hydrolysis
Term
hydrolysis of ester
 Definition
H20
Term
synthesis of alchohols (ester end)
 Definition
Alcohol
Term
synthesis of alchohols (amide end)
 Definition
Amine
Term
Hydrolysis of amide
 Definition
acid or base
Term
reduction of amide
 Definition
LAH/H3O+
Term
SN2 of nitriles
 Definition
NaCN
Term
Hydrolysis of nitriles
 Definition
acid or base
Term
reduction of nitriles
 Definition
LAH, H3O+
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