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exam 2
chapter 11
22
Chemistry
Undergraduate 4
03/26/2012

Additional Chemistry Flashcards

 


 

Cards

Term

Ion-Ion

Definition

intermolecular force between two Ionic molecules

ex. Na+Cl-

Term
Ion-Dipole
Definition
ontermolecular force between ion & polar molecule
Term
Dipole-Dipole
Definition
intermolecular forces between polar molecule & polar molecule
Term

Dipole induced Dipole

 

Definition
intermolecular forces between polar molecule & non-polar molecule
Term
London Forces
Definition

Exist for all species (polar or non-polar) but only become significant only when all other forces do not exist

 

The strength of london force depends upon the size (or molecular weight) of the species.

 

Bigger/Heavy=Stronger Force

Term
Bond strength order from strongest to weakest.
Definition

1) H group bonds

2)dipole-dipole

3)London Forces

4) molercular weight

Term
Vaporization of a liquid is dependant on what?
Definition

TEMPERATURE!

↑ liquid temp= ↑ vaporization rate

 

↑ surface area=↑ vaporization rate

 

↓ strength of intermolecular forces=↑ vaporization rate

 

ΔHvap in kJ/mole

 

 

Term
Suppose for H2O @ 25°c is 44kJ/mole. how much heat is needed to vaporise 36mL of H2O?
Definition

 * What is being vaporised?

*mL→g

*g→mole

*mole→kJ

 

(36mLH2O)(1gH2O/1mLH2O)(1moleH2O/18gH2O)(44kJ/1mole)=88kJ

Term
Hydrogen Bonds
Definition

sort of super dipole-dipole force. 

Hydrogen bonds strongly with F, O, and, N

Term
Vapor pressure and dynamic equilibrium
Definition

when a system in dynamic equilibrium is disturbed, the system responds so as to minimize the disturbance and return to a state of equilibrium!

 

Dynamic equilibrium: Rate of evaporation=Rate of condensation

Term
Simple cubic
Definition

[image]

 

8 corners

Term
Faced center cubic
Definition

[image]

8 corners+ 6 faces

Term
Body centered cubic
Definition

[image]

8 corners+ 1 body

Term
What makes a good electrical conductor?
Definition

A) you must have charge... think ions

 

B) Ions must be free to move

Term
WHy are metals good conductors?
Definition
they do not hold onto there electrons very strongly allowing them to move freely
Term
ΔHsub
Definition
=ΔHfus+ΔHvap
Term
molecular solid
Definition
ice
Term
network covalent solid
Definition
diamond
Term
t1/2
Definition
half life- the time required for the concentration of a reactant to fall to one half of its initial value.
Term
enzyme
Definition
are biological catalysts thats increase the rates of biological reactions
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