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Electronic Structure of Atoms
chapter 6
37
Chemistry
12th Grade
01/02/2013

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Term
electronic structure
Definition
the arrangement of electrons in an atom or molecule
Term
electromagnetic radiation
Definition
a form of energy that has awave characteristics and that propagates through a vacuum at the characteristic speed of 3.00*10^8 m/s
Term
wavelength
Definition
the distance between identical points on successive waves
Term
frequency
Definition
the number of times per second that one complete wavelength passes a given point
Term
quatum
Definition
the smallest increment of radiant energy that may be absorbed or emitted the magnitude of radiant energy is hv
Term
Planck's constant
Definition
the constant that relates the energy and frequency of a photon E = hv; equals 6.626*10^-34 J-s
Term
photoelectric effect
Definition
the emissions of electrons from a metal surface induced by light
Term
spectrum
Definition
the distribution among various wavelengths of the radiant energy emitted or absorbed by an object
Term
continuous spectrum
Definition
a spectrum that contains radiation distributed over all wavelengths
Term
line spectrum
Definition
a spectrum that contains radiation at only certain specific wavelengths
Term
ground state
Definition
the lowest energy, or most stable, state
Term
excited states
Definition
a higher energy state than the ground state
Term
matter waves
Definition
the term used to describe the wave characteristics of a moving particle
Term
momentum
Definition
the product of the mass and velocity of an object
Term
uncertainty principle
Definition
a principle stating there is an inherent uncertainty in the precision with which we can simultaneously specify the position and momentum of a particle this uncertainty is significant only for particles of extremely small mass, such as electrons
Term
wave functions
Definition
a mathematical description of an allowed energy state (an orbital)
Term
probability density
Definition
a value the represents the probability that an electron will be found at a given point in space
Term
electron density
Definition
the probability of finding tan electron at any particular point in an atom; this probability is equal to the square of the wave function
Term
orbitals
Definition
an allowed energy state of an electron in the quantum mechanical model of the atom; the term orbital is also used to describe the spatial distribution of the electron; an orbital is defind the the values of three quantum numbers: n, l, and ml
Term
electron shell
Definition
a collection of orbitals that have the same value of n
Term
subshell
Definition
one or more orbitals with the same set of quantum numbers n and l
Term
radial probability function
Definition
the probability that the electron will be found at a certain distance from the nucleus
Term
nodes
Definition
points in an atom at which the electron density is zero; for example the node in a 2s orbital is spherical surface
Term
degenerate
Definition
a situation in which two or more orbitals have the same energy
Term
electron spin
Definition
a property of the electron that makes it behave as though it were a tiny magnet; the electron behaves as if it were spinning on its axis; electron spin is quantized
Term
spin magnetic quantum number
Definition
a quantum number associated with the electron spin
Term
Pauli exclusion principle
Definition
a rule stating that no two electrons in an atom may have the same four quantum numbers; as a reflection of this principle, there can be no more than two electrons in any one atomic orbital
Term
electron configuration
Definition
the arrangement of electrons in the orbitals of an atom or molecule
Term
Hund's rule
Definition
a rule stating that electrons occupy degenerate orbitals in such a way as to maximize the number of electrons with the same spin; in other words, each orbital has one electron placed in it before pairing of electrons in orbitals occurs
Term
valence electrons
Definition
the outermost electrons of an atom; those that occupy orbitals not occupied in the nearest noble-gas element of lower atomic number; the valence electrons are the ones the atom uses in bonding
Term
core electrons
Definition
the electrons that are not in the outermost shell of an atom
Term
representative elements
Definition
an element from within the s and p blocks of the periodic table
Term
main-group elements
Definition
elements in the s and p blocks of the periodic table
Term
transition elements
Definition
elements in which the d orbitals are partially occupied
Term
lanthanide (rare earth) elements
Definition
element in which the 4f subshell is only partially occupied
Term
actinide elements
Definition
element in which the 5f orbitals are only partially occupied
Term
f-block metals
Definition
lanthanide and actinide elements in which the 4f and 5f orbitals are partially occupied
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