Shared Flashcard Set

Details

Descriptive
Group 13 elements
14
Chemistry
Undergraduate 3
05/16/2013

Additional Chemistry Flashcards

 


 

Cards

Term
Boron: Where do we get it from?
Definition
Borax, Kernite
Term
Boron: How is it extracted?
Definition
Borax --> B(OH)3 + heat --> B2O3 + Mg(l) --> MgO(s) + B(s)
Term
Aluminum: Where do we get it from?
Definition
Bauxite
Term
Aluminum: How is it extracted?
Definition

Bayer Process: Bauxite dissolved in NaOH (Al & Si dissolved) --> Al(OH)3 + NaB4O5(OH)4 +H2SO4 --> 4B(OH)3 + Na2SO4

 

Hall-Heroult Process: Al(OH)3 dissolved in molten cryolite (Na3AlF6) --> Al2O3 + 3C --> 4Al + 3CO2

Term
Aluminum: Uses?
Definition

- Most widely used metal after Fe

- Airplanes, Cars, Trains, etc...

- Packaging, cooking utensils

- Power lines

- Corrosive resistant due to Al2O3

- Recycling Al: 5% of energy to make from ore

- All oxides: catalyst supports, chromotography, abrasives

Term
Gallium: Where do we get it from?
Definition

- Impurity of Bauxite (GaO)

- Byproduct of Al production

 

Term
Gallium: Uses?
Definition

Semiconductors (98% of use)

GaAs - Blue LEDs, solar cells, integrated circuits, IR light emitting

GaN- Bright light emitting diodes, Blue-Ray disc lasers

Term
Indium: Where do we get it from?
Definition

-Byproduct of Zn and Pb production

- Leached from dust and slag

- Purified by electrolysis

Term
Indium: Uses?
Definition

-LCD and touch screens

- Uses In2O3 and ITO(In tin oxide) to make transparent and conductive coatings

-LEDs

 

Term
Thallium: Where do we get it from?
Definition

Byproduct of smelting Cu, Zn, Pb by collecting flue powder

- leached w/ sulfuric acid and electrolysis

Term
Thallium: Uses?
Definition

Tl2SO4 --> rat poison

-60 to 70% used in electronics

- Tl2Se used in IR detector

-Tl semiconductor dopant

-Glass industry: IR optics

-Pharmaceuticals: 201Tl radioactive and used in heart imaging, salts treat ringworm and other skin infections

 

 

Term
Boron: Uses?
Definition

35% used for borosilicate glass (pyrex)

- 12 to 15% B2O3, 80% SiO2, 2% Al2O3

-Expands half as much as soda glass

20% used as cleaning agents 

-Perchlorate Bleach (NaBO3 x nH2O): made from Borax, dissolves water to make H2O2, teeth whitener, antiseptic, less agressive than NaClO bleach

- High strength lightweight B fibers

-Semi-conductor dopant

- B4C and BN alternative to diamonds: bullet proof vests

- Nuclear power plant shielding

Term
Boron: Uses (Borax)?
Definition
Borax (Na2B4O5(OH)4 x nH2O): biochem buffers(TBE,BBS,DNA electrophoresis buffers, insecticide, antifungal, food preservative, fire retardant, enamal glazes
Term
Boron neutron capture theory
Definition

-BNCT: Boron neutron capture theory

10B + 10n --> 11B --> alpha + 7Li + 2.31 MeV

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