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Conformations
NA
11
Organic Chemistry
Undergraduate 2
09/14/2011

Additional Organic Chemistry Flashcards

 


 

Cards

Term
ANTI STAGGERED
Definition
[image]
Term
ECLIPSED
Definition
[image]
Term
GAUCHE STAGGERED
Definition
[image]
Term
SYN ECLIPSED
Definition
[image]
Term
How many different conformations are there?
Definition

Anti

Gauche

Syn

Eclipsed

Term
Which conformation is the most relatively unstable?
Definition
Syn eclipsed
Term
Which conformation is the most relatively stable?
Definition
Anti staggered
Term
What causes torsional strain?
Definition
When, shown in a Newman Projection, the bonds are eclipsed. The hydrogen bonds are on the same plane and too close together. This causes torsional strain between the hydrogens.
Term
What casues angle strain?
Definition
When angles are larger or smaller than 109-110 degrees
Term
What does a molecule do to relieve strain?
Definition

It will pucker or twist. This makes the bond angles closer to the ideal 109 degrees or moves them away from each other if they are on the same place. However, when this relieves angle strain, it can increase torsional strain and vice versa.

 

Exception: cyclohexane

Term
What is the only alkane that has no tortional or angle strain AND is abundant in a natural occuring state?
Definition
Cyclohexane
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