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Chemistry 3a
Chemistry GCSE
24
Science
11th Grade
01/01/2017

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Term
Who was John newlands?
Definition

A man who tried to organise elements in 1864. He noticed that every 8th element (atomic mass order) had similar properties. These sets of 8 were called Newlands' Octaves however his pattern didn't work after the 3rd row. His work was criticised because:

1.His groups contained elements that didn't have similar properties

2.He mixed up metals and non-metals

3.He didn't leave any gaps for un-discovered elements

Term
Who was Dmitri Mendeleev?
Definition

A man who tried to organise the elements - 1869. He put the elements in order of atomic mass but he left gaps in order to keep elements with similar properties in the same column.The gaps predicted the properties of un-discovered elements. His work was accepted because:

1.Elements in the same column had similar properties

2.He left gaps for the un-discovered elements

3.When the elements were found they fit in the pattern

 

Term
Describe the Modern Periodic Table.
Definition

1. The elements are arranged by their electronic structure

 2.Apart from the transition metals, elements in the same group have the same number of electrons in their outer shells

3. The group number is equal to the number of electrons in their outer shell.


Term
Why do Group 1 metals get more reactive as you go down the group?
Definition
The positive charge of the nucleus attracts electrons and holds them in place. The further from the nucleus the electron is, the less the attraction. The attraction of the nucleus is even less when there are a lot of inner electrons. This effect is known as shielding. The combination of increased shielding and distance means that an electron in a higher energy level is more easily lost.
Term
Why do Group 7 metals get less reactive as you go down the group?
Definition
Increased distance and shielding also means that a higher energy level is less likely to gain an electron - there's less attraction from the nucleus pulling electrons into the atom.
Term
What are the trends of Group 1 (The Alkali Metals)?
Definition

As you go down the metals.....

1.....become more reactive

....because the outer electron is more easily lost

....because of distance (it is further away from nucleus)

2.....have lower melting and boiling points

3....they have low density

Term
What are the first 3 Group 1 Elements?
Definition

Lithium (Li)

Sodium (Na)

Potassium (K)

Term
Why do The Alkali Metals form Ionic Compounds with Non- metals?
Definition
They need to lose their one outer electron to form a 1+ ion so they always form ionic bonds - they produce white compounds that dissolve in water to form colourless solutions.
Term
What happens when Lithium (Li), Sodium (Na) and Potassium (K) react with water?
Definition

Li reacts vigorously with water H20 (likewise Na, K). They fizz furiously and produce Hydrogen (H2). K gets hot enough to ignite it. A lighted splint will indicate H2 by producing a pop. They form Hydroxides that dissolve in water to give alkaline solutions.

 

2Li(s) + 2H20 ➙ 2LiOH(aq) + H2(g)

2Na(s) + 2H20 ➙ 2NaOH(aq) + H2(g)

2K(s) + 2H20 ➙ 2KOH(aq) + H2(g)

Term

What are the trends of Group 7 (The Halogens)?

 

Definition

As you go down the halogens.....

1.....become less reactive

....because it's harder to gain an electron

....because of distance (it is further away from nucleus)

2.....have a higher melting point

3....they have a higher boiling point

 

Term
What are the first 3 Group 7 Elements?
Definition

Flurine (F)

Chlorine (Cl)

Bromine (Br)

 

Term

Why do The Halogens form Ionic Compounds with Metals?

 

Definition
The halogens form 1- ions called halides (F-, Cl-, Br-) when they bond with metals. For example Na+Cl-.
Term
Why will more reactive halogens displace less reactive ones?
Definition

A more reactive halogen can displace (kick out) a less reactive halogen from an aqueous solution of it's salt. For example Chlorine (Cl) can displace Iodine (I) from an aqueous solution of its salt (Potassium Iodide KI)

 

Cl2(g) + 2KI(aq) ➙ I2 + 2KCl(aq)

Term
What are the trends of The Transition Elements?
Definition

1. They are good conductors of heat and electricity

2. They are very dense, strong and shiny

3.They are much less reactive than group 1 metals

4.They don't react as vigorously with water or oxygen

5.They're much denser, stronger & harder than group 1

Term
Name some Transition Metal (Compounds) which are good catalysts.
Definition

Iron - used in the Haber process for making ammonia

Maganese(IV)Oxide - used in the decomposition of hydrogen peroxide

Nickel - used to turn oil into fat for magarine

Term
What is Hard Water?
Definition
Water containing dissolved Calcium ions (Ca2+) or Magnesium ions (Mg2+) which are present due to a reaction between acidic rain and Calcium (Ca) or Magnesium (Mg) compounds in rocks.
Term
Where does Hard Water come from?
Definition

1. Carbon Dioxide (CO2) dissolves in rain water making it slightly acidic

2. Rainwater falls into rivers and streams which flow over rocks containing Calicium (Ca)

3. Ca compounds (eg. CaCO3) react with the solution

4. This makes Calcium Hydrogen Carbonate (Ca(HCO3)2 ) which is soluble in water, so releases Ca2+ ions

5. This water flows into reservoirs and into our domestic water supply

Term
What happens when you use soap with Hard Water?
Definition
It makes scum and scale and the soap doesn't lather.
Term
What happens when you heat Hard Water?
Definition
When heated, hard water forms scale (Calcium carbonate) on the insides of pipes, boilers and kettles which reduce the efficiency of the heating system. This may need to be replaced - which all costs money.
Term
Name some advantages of Hard Water.
Definition

1. Ca2+ ions are good for healthy teeth and bones

2.Studies have found that people who live in hard water areas are at a less risk of developing heart disease than people who live in soft water areas.

Term
What is Temporary Hard Water?
Definition

Temporary hardness can be removed by boiling. When heated the Calcium Hydrocarbonate decomposes to form Calcium Carbonate which is insoluble.

 

Calcium Hydrocarbonate ➙ Calcium Carbonate + Water + Carbon Dioxide

Ca(HCO3)2(aq) ➙ CaCO3(s) + H2O(l) + CO2(g)

Term
What is Permanent Hard Water?
Definition
Permanent hardness cannot be removed by boiling.
Term
How can hardness be removed in both types of Hard Water?
Definition
Both types of hardness can be softened by adding washing soda (Sodium Carbonate - Na2CO3). The added Carbonate ions react with the Ca2+ and Mg2+ ions to make an insoluble precipitate of Calcium Carbonate and Magnesium Carbonate.
Term
How can you use Titration to compare the hardness of water samples?
Definition

1. Fill a burette with 50cm3 of soap solution

2. Add 50cmof sample a into a flask

3. Use the burette to add 1cm3 of soap solution into flask

4.Put a bung in the flask and shake for 10 seconds

5. Repeat steps 3 & 4 until a long lasting lather is formed

6. Record how much soap was needed to create a long lasting lather

7. Repeat steps 1-6 with sample b

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