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Chemistry 1306
Exam II
105
Chemistry
Undergraduate 4
02/26/2014

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Term
Know how we get electricity (what process happens and where does fossil fuel get used in this process)
Definition
Coal is used to create electricity in a power plant.
1.) combustion
2.) Boil water in a closed, high pressure system
3.) Turn turbine to create electricity
*every other fuel source is cleaner
Term
When naming a compound composed of two non-metals, the number of _____ of each element is indicated by a Greek numerical prefix.
Definition
Atoms
Term
The first element in the name is numbered only when ___ or more atom(s)of that element are present.
Definition
1
Term
Gas molecules are in constant random motion and are extremely ______ under normal circumstances.
Definition
Close together.
Term
If the gas molecules in a sample of air were condensed their actual volume would be very _____.
Definition
Large
Term
Catalyst
Definition
Substance that increases the rate of a reaction without being consumed.
Term
Chemical reaction where reactants are transformed into products.
Definition
Combustion
Term
Express the quantity 0.000000000085 in scientific notation.
Definition
8.5x10-11
Term
TRUE or FALSE.
After the completion of a reaction, the number of substances may change but the total mass remains the same.
Definition
TRUE. Matter is neither created nor destroyed.
Term
The prefix ____ represents 10 atoms of the same element
Definition
deca
Term
The prefix hexa- is used to indicate ___ atoms of an element.
Definition
6
Term
Percent means parts per ____.
Definition
hundred
Term
A molecule that always contains carbon and may contain hydrogen, nitrogen, or oxygen is ______.
Definition
Organic
Term
Which pollutant is present in air as particulate matter?
Definition
Soot
Term
What two factors are considered when determining the risk assessment for air pollutants?
Definition
Exposure and Toxicity.
Term
Which pollutant can not be detected by their odor?
Definition
Carbon Monoxide
Term
The layer of our atmosphere that contains the highest concentration of ozone is the ____?
Definition
Stratosphere
Term
Green Chemistry
Definition
the design of products and processes that reduce hazardous substances
Term
Which of the following is a pure substance?
Lemonade, Concrete, Gasoline, Silver Wire
Definition
Silver wire
Term
Which color in the rainbow has the shortest wavelength?
Definition
Violet
Term
What distinguishes the atoms of one element from another?
Definition
the # of protons
Term
The atomic number is the same as the ____.
Definition
number of protons in a nucleus
Term
What is the second law of thermodynamics?
Definition
The entropy of the universe is constantly increasing. Energy conversions cannot be 100% efficient.
Term
Hydrocarbons with only single bonds between carbons
Definition
Alkanes
Term
Isomers
Definition
Have the same formula, but vary structurally
Term
Activation Energy
Definition
Increasing temperature allows more particles to have sufficient energy to overcome the activation barrier. Lower activation energy generally results in faster reactions
Term
First law of dynamics
Definition
Energy cannot be created nor destroyed
Term
What is the most modern unit of energy?
Definition
Joules (J)
Term
During an energy conversion, what happens to the energy that is lost?
Definition
It becomes kinetic energy of random motion of the surrounding molecules.
Term
Net efficiency=
Definition
electrical energy produced/ x100
heat from fuel
Term
What are common sources of energy in the US?
Definition
Petroleum, Natural gas, and Coal
Term
Proposed "clean coal" technologies use what kind of techniques?
Definition
Capture and store carbon emissions.
Wash to remove impurities.
Chemically removing SO2 before releasing combustion products.
Term
Example of Waste-to-energy Conversion
Definition
Garbage can be burned without additional fuel used to generate electricity
Term
What are the benefits of a catalyst in green chemistry?
Definition
They are not consumed in the reaction, so only small amounts are needed, and they allow for lower reaction temperatures.
Term
What is the chemical formula for Pentane?
Definition
C5H12
Term
What is the chemical formula for Ethane?
Definition
C2H6
Term
What is chemical formula for methane?
Definition
CH4
Term
What is the chemical formula for Heptane?
Definition
C7H16
Term
What are common products of combustion?
Definition
CO2 and H20
Term
In the octane-rating system, iso-octane is assigned a rating of ____.
Definition
100
Term
In the octane-rating system, heptane is assigned a rating of ____.
Definition
0
Term
What are environmental and ethical impacts of increased corn ethanol production?
Definition
Fertilizers have insecticides used in corn growing that have been increasingly introduced to the soil and water. Farmland is being diverted from food to produce ethanol, driving worldwide food prices up. The demand for additional farmland has increased the danger of deforestation.
Term
Petroleum
Definition
It is made from partially decomposed organic matter. It is a mixture of many different compounds.
Term
What type of hydrocarbon molecule burns most smoothly in an internal combustion engine?
Definition
Highly branched hydrocarbons
Term
What are some disadvantages of using coal as a fuel source?
Definition
Coal mining can cause environmental harm. Burning coal can release sulfur and mercury.
Term
How is the octane-rating of fuel assigned?
Definition
Octane rating is the percentage of iso-octane that, mixed with heptane, burns with the same characteristic as fuel.
Term
What are the main social and economic disadvantages of using corn ethanol as fuel?
Definition
Ethanol production consumes significant fossil fuels to provide energy to plant corn and distill the alcohol. Ethanol is more expensive per volume than crude oil.
Term
What was the result of the energy balance study on the production and use cycle of bio diesel?
Definition
Bio diesel generates 300% more energy than is required to produce it.
Term
What is the main component of petroleum?
Definition
Hydrocarbon(s)
Term
Biogas
Definition
Fuel mixture produced by using bacteria to decompose sewage and manure.
Term
What are advantages of using oxygenated fuels?
Definition
They enhance the octane rating of the gasoline, and they produce less CO than traditional gasoline.
Term
What do proteins and nylons have in common?
Definition
Both polymers are formed through condensation polymerization. The monomers of both polymers are linked through amide linkages.Both polymers are copolymers.
Term
Describe the recycling of plastics.
Definition
Codes on plastic containers help to separate different types of polymers.Once sorted, plastics are melted.
Term
Relationship between molecular shape and the strength of dispersion forces.
Definition
Molecules with a larger surface area have more points of contact and therefore experience stronger dispersion forces.
Term
Dispersion forces
Definition
Attraction between molecules due to a distortion in the electron cloud, which causes an uneven distribution of negative charge
Term
Recycling that involves a closed loop in which plastics are recycled and converted into other products.
Definition
True Recycling
Term
Polymers that are formed by a combination of functional groups that eliminate a small molecule.
Definition
Condensation polymers
Term
Describe a catalyst used in an addition polymerization
Definition
The catalyst is a free radical, and highly reactive
Term
Eco-friendly polymers
Definition
Made from materials such as wood, cotton, starch, and sugar. Waste decomposes easily. Have been used in automobile parts.
Term
What is the first step in addition polymerization?
Definition
Reaction of the catalyst with the monomer
Term
HDPE
Definition
High Density so strong and rigid.
Term
Describe plastic in landfills.
Definition
Not readily biodegradable.
Term
Describe source reduction and its advantages.
Definition
Involves using less material and helps to reduce pollution.
Term
Energy
Definition
Capacity to do work
Term
Work
Definition
Movement against a force
(w=fxd)
Term
Heat
Definition
Energy that flows from a hotter to colder object
Term
Calorie
Definition
Amount of heat required to raise the temperature of 1 gallon of water by 1 degree c
Term
When naming organic molecules, 1 Carbon would be represented by what prefix?
Definition
Meth-
Term
When naming organic molecules, 2 Carbon would be represented by what prefix?
Definition
Eth-
Term
When naming organic molecules, 3 Carbons would be represented by what prefix?
Definition
Prop-
Term
When naming organic molecules, 4 Carbons would be represented by what prefix?
Definition
But-
Term
When naming organic molecules, 5 Carbon would be represented by what prefix?
Definition
Pent-
Term
When naming organic molecules, 6 Carbons would be represented by what prefix?
Definition
Hex-
Term
Saturated Hydrocarbon
Definition
All single bonds, each carbon is bound to only other carbons and hydrogens.
Term
Unsaturated Hydrocarbon
Definition
Carbon is bound to the maximum amount of atoms. Each of the 4 bonds that carbon make are NOT to separate atoms. Multiple bonds greatly influence the shape of a molecule.
Term
Functional Groups
Definition
Molecules that behave as a unit. Allow us to categorize types of organic molecules that have similar properties
Term
Heteroatoms
Definition
organic compounds that are not carbon or hydrogen. functional groups contain 1 or more heteratom.
Term
Alcohol
Definition
OH group molecule. Allows short molecules to fully dissolve in water.
Term
What happens when you make the alcohol longer?
Definition
Becomes less soluble.
Term
Methanol
Definition
one of the most produced chemicals in the US. Used to make formaldehyde and acetic acid which are used in plastic production.
Term
Ethers
Definition
Much like alcohols except the oxygen is bound to two carbons instead of a carbon and a hydrogen. NOT polar.
Term
Amines
Definition
compounds where a N bound to 1,2,3 saturated carbons.Very strong odors. Ex: Potrescine. Less polar than alcohol, but more polar than ethers.
Term
Carbonyl
Definition
NOT its own functional group. Makes Ketones and Aldehydes.
Term
Mer
Definition
Name given to a small # unit
Term
Plastic
Definition
Man-made polymer
Term
Biopolymer
Definition
Plant cell walls made from proteins, DNA, complex carbohydrates
Term
Synthetic Polymer
Definition
Made from one or two reactions: addition and condensation.
Term
Addition Polymerization
Definition
From joining together 2 or more monomers. Requires the pressence of a double bond. No atoms are gained or lost. only electrons are shared between the bonds.
Term
HDPE
Definition
High Density Polyethylene. strong/rigid.
Term
LDPE
Definition
Low Density Polyethylene. EX: twigs.
Term
Condensation Polymerization
Definition
formed by the gaining of 2 or more monomers that form from the loss of a single molecule. Requires the use of a functional group. Many different polymers are formed from 2 separate compounds.
Term
Copolymer
Definition
Forming of a polymer from 2 separate compounds.
Term
Biomolecules
Definition
Mostly polymers. Take on multiple shapes. Molecules produced and used within a cell.
Term
Animal Cell (difference from plant)
Definition
Mitochondria
Term
Plant Cell (difference from animal)
Definition
Cell wall and Chloroplast
Term
Plasma Membrane
Definition
the boundary of the cell. Regulates the movement of particles in and out of the cell.
Term
Cytoplasm
Definition
Where all the other components of the cell are found (organelles).
Term
Organelle
Definition
Produce, store, and transport biomolecules. Each organelle has a specific function that it must carry out.
Term
Carbohydrates
Definition
Molecules composed of carbon, hydrogen, and oxygen. Plants produce carbs during photosynthesis by combining carbon dioxide with water via sunlight.
Term
Saccharide
Definition
Simple sugar. Can be mono-, di-, poly-
Term
Sucrose
Definition
Disaccharide made from glucose and fructose.
Term
Polysaccharide
Definition
Long chains of monosaccharides much like polymers are long chains of monomers
Term
Starch
Definition
Plants produce glucose during the process of photosynthesis. Glucose is the fuel of the plant cell. So excess glucose must be store-plants store glucose as starch. Two types: Amylose and Amypectin.
Term
Amylose
Definition
Straight chain of glucose that coils around itself. Only two ends open for release of glucose.
Term
Amylopectin
Definition
Branched form of plant starch. Coiled but branched, making it bulky and having more free ends open to release glucose.
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