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| does not appear in reactant or product |
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k = m/s
conc. vs. time
positive slope |
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k = 1/sec
ln[A] vs time
negative slope |
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k = sec/M
1/[A] vs t
positive slope |
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| Factors affecting rxn rate |
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| conc., temp., medium, catalysts |
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| increase collision freq, change orientation, donate e- density, reduce intermolecular bonding |
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| products over reatants raised to coefficients |
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| pure solids and liquids... |
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| dont appear in equilibrium constant expression |
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| An increase in pressure will shift to |
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| lnk2/k1=(Ea/R)(1/T1-1/T2) |
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