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Chem 4 Chapter 7
Chem 4 Chapter 7
28
Chemistry
Undergraduate 2
03/26/2014

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Term
Temperature
Definition
the average kinetic energy of its particles
Term
Heat
Definition
amount of KE that flows from a hot object to a cold object as a result of their difference in temperature.
Term
Internal energy (E)
Definition
the sum of energy of all of the individual particles
Term
State function
Definition
depends only on an object's current state; we only care about final - initial
Term
State function examples
Definition
pressure, temperature, volume, and chemical composition
Term
Equation: Heat and temperature
Definition
Q = (C)*∆T = (m*s)*∆T
Heat = heat capacity * temp
Heat = specific heat * mass * temp
Term
Heat capacity (C)
Definition
J/(°C)
amount of energy needed to raise the temperature of an object by 1°C
Term
Specific heat (s)
Definition
J/(g°C)
the amount of heat required to raise the temperature of 1 gram of a substance by 1°C
Term
Positive Q
Definition
Heat is gained
Term
Negative Q
Definition
heat is lost
Term
Exothermic
Definition
Produces heat; products have less PE (and more KE) than reactants. Weak bonds form strong bonds, which hold less PE because they're smaller
Term
Endothermic
Definition
Absorbs heat; products have more PE (and less KE) than reactants
Term
Heat of reaction
Definition
The amount of heat absorbed or released in a reaction; determined by measuring ∆T
Term
Negative ∆E
Definition
System loses energy
Term
Positive ∆E
Definition
System gains energy
Term
Equation: Internal energy change
Definition
∆E = w + Q
The change in internal energy is equal to the work and heat that goes into the system
Term
Positive ∆H
Definition
endothermic
Term
Negative ∆H
Definition
exothermic
Term
∆H at constant pressure
Definition
∆H = Q when ∆P = 0
The change in enthalpy is equal to the change of KE (heat) at constant pressure
Term
Difference between ∆E and ∆H
Definition
large in gasses, insignificantly small in gas/ solid
Term
Standard state
Definition
1M, 298K, 1 atm
Term
Standard Heat of Reaction (∆H°)
Definition
the value of ∆H for a reaction in reactants and products in their standard conditions; involves the actual numbers of moles specified by the coefficients of the equation
Term
Equation: Change in enthalpy at standard pressure
Definition
∆H = ∆E + P∆V = Qp
change in enthalpy is the change in energy minus the work done by the system.
At standard pressure, change in enthalpy is the change in heat
Term
Standard Enthalpy of Formation (∆H°f)
Definition
the change in enthalpy for a reaction that forms one mole of the compound from its elements, with all substances in their standard states.
Term
The standard enthalpy of formation (∆H°f) of the most stable form of any element:
Definition
zero; no formation reaction needed when the element is already in its standard state
Term
(∆H) vs (∆H°) vs (∆H°f)
Definition
change in heat energy (∆H), reaction-induced change in heat energy when reactants and products in their standard conditions (∆H°), forms 1 mole of compound from its elements with everything in most stable state (∆H°f)
Term
Heats of Reaction (q)
Definition
The change in chemical potential energy in a reaction
Term
(Pressure-Volume) Work
Definition
w = -P∆V
Work is the pressure times the change in volume
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