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Chem 101 Chapter 5
What dat says^
23
Chemistry
Undergraduate 1
10/04/2011

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Term

Covalent Bond

Definition
A bond that results from the sharing of electrons between atoms
Term

Molecule

 

Definition
THe unit of matter held together by covalent bonds
Term
bond length
Definition

-optimum distance between nuclei forming a bond.

-where net attractive forces are maximized and molecule is most stable

-

Term
structural formula
Definition

-shows specific bonds between atoms

-gives much more info than a chemical formula

-uses lines between atoms to represent covalent bonds

 

Term
chemical formula
Definition
lists the symbols of the compound's constituent elements and uses subscripts to indicate the number of atoms of each element
Term
bond dissociation energy (D)
Definition
the amount of energy that must be supplied to break a chemical bond in an isolated molecule in the gaseous state, and thus the amount of energy released when the bond forms
Term

range of strength of bonds commonly encountered in naturally occuring molecules 

Ex. (C-H , C-C , C-O)

Definition
350-400kJ/mol
Term
Lattice Energy (U)
Definition
The amount of energy that must be supplied to break an ionic solid into its individual gaseous ions and is thus a measurement of the strength of the crystal's ionic bonds
Term
polar covalent bonds
Definition

the large majority of bonds in which bonding electrons are shared unequally between two atoms but are not completely transferred 

Represented by delta (δ)

-  (δ+) for atom w/ smaller share

-  (δ-) for atom w/ larger share

Term
electrostatic potential map
Definition

-uses cols to portray the calculated electron distribution in an isolated, gas-phase molecule

 -blue represents electron shortage (partial positive) and red represents electron surplus (partial negative)

Term
nonpolar covalent bond
Definition

-the bond between the two atoms is equal

-occurs with diatomic molecules that contain a covalent bond between two identical atoms

Term
Electronegativity (EN)
Definition

-The ability of an atom in a molecule to attract shared electrons in a covalent bond

-fluorine has the highest

-metallic elements have weakest

-highest top right decreases to lowest bottom left

Term
what is bond polarity caused by
Definition
differences in electronegativity
Term
electron affinity
Definition
the energy change that occurs when an electron is added to an isolated gaseous atom
Term
ionization energy
Definition
the amount of energy needed to remove the highest-energy electron from an isolated neutral atom in the gaseous state
Term

Lewis Structes

(Electron-Dot Structures)

Definition
represents an atom's valence electrons by dots and indicates by the placement of the dots how the valence electrons are distributed in a molecule 
Term
octet rule
Definition
states that main-group elements tend to undergo reactions that give them a noble-gas electron configuration with filled s and p sublevels in their valence electron shells
Term
lone pairs
Definition
pairs of nonbonding electrons on each atom in a covalent bond
Term
bonding pairs
Definition
the shared electrons between two atoms in a covalent bond
Term
bond order
Definition

number of pairs  of electrons shared in a covalent bond 

Delineated by lines

- is 1

= is 2

i dont have a button with three lines but you get the idea

Term
Coordinate Covalent Bonds
Definition

Bond formed whenone atom donates both electrons (a lone pair) to another atom that has a vacant valence orbital.

Ex.

ammonium ion (NH4+) forms when two lone pair electrons from the nitrgen atom of ammonia (NH3) bond to (H+)

N,O,P, and S form these regularly

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