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Chapter 8 - Chemical Bonding
Vocabulary
29
Chemistry
Undergraduate 1
05/05/2010

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Term
Chemical Bonds
Definition
the attractive forces between atoms in molecules result in their formation
Term
Covalent Bond
Definition
formed when two atoms share a pair of electrons
Term
Ionic Bond
Definition
results from the electrostatic attraction of a cation for an anion
Term
Metallic Bond
Definition
consists of the nuclei of metal atoms surrounded by a "sea" of shared electrons
Term
Octet
Definition
a set of eight electrons in the outermost (valence) shell of an atom
Term
Octet Rule
Definition
states that atoms of main group elements make bonds by gaining, losing, or sharing electrons to achieve an outer shell containing eight electrons or four electron pairs
Term
Duet
Definition
the maximum of two electrons that the outermost shell of a hydrogen atom can contain
Term
Lewis Structure
Definition
a two-dimensional representation of a molecule that provides a view of the connections between its atoms' valence electrons are depicted as dots around the atomic symbol
Term
Lewis Symbol
Definition
the chemical symbol for an atom surrounded by one or more dots representing the valence electrons
Term
Single Bond
Definition
results when two atoms share one pair of electrons
Term
Lone Pair
Definition
a pair of electrons that is not shared
Term
Bonding Pair
Definition
a pair of electrons shared between two atoms
Term
Double Bond
Definition
results when two atoms share two pairs of electrons
Term
Triple Bond
Definition
results when two atoms share three pairs of electrons
Term
Bond Length
Definition
the distance between the nuclear centers of two atoms joined together in a bond
Term
Polar Molecule
Definition
contains bonds that have an uneven distribution of charge because electrons in the bonds re not shared equally by the two atoms
Term
Nonpolar Molecule
Definition
contains bonds that have an even distribution of charge; electrons in the bonds are shared equally by the two atoms; pure covalent bonds give rise to nonpolar diatomic molecules
Term
Polar Covalent Bond
Definition
results from unequal sharing of bonding pairs of electrons between atoms
Term
Electronegativity
Definition
a relative of the ability of an atom to attract electrons to itself
Term
Bond Polarity
Definition
a measure of the extent to which bonding electrons are shared between two atoms in a covalent bond; the less equally they are shared, the more uneven the distribution, the more polar the bond
Term
Allotropes
Definition
different forms of the same element, such as oxygen and ozone
Term
Resonance
Definition
occurs when two or more equivalent Lew structures can be drawn for one compound
Term
Resonance Structure
Definition
one of two or more Lewis structures with the same arrangement of atoms but different arrangements of electrons for a molecule
Term
Formal Charge
Definition
equals the number of valence electrons on the free atom in the Lewis structure minus the sum of the number of electrons in its lone pairs plus half the number of electrons in its bonding pairs
Term
Bonding Capacity
Definition
reflects the number of covalent bonds an element forms when it has a formal charge of zero
Term
Electron-Deficient Compounds
Definition
substances who central atoms in Lewis structures have fewer than four electron pairs (less than an octet of electrons)
Term
Free Radicals
Definition
molecules having an odd umber of valence electrons and hence unpaired electrons in their Lewis structures
Term
Bond Order
Definition
the number of bonds between atoms
Term
Bond Energy
Definition
the energy needs to break one mole of a covalent bond in the gas phase
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