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Chapter 7 - Electrons in Atom and the Periodic Table
Vocabulary
52
Chemistry
Undergraduate 1
05/05/2010

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Term
Electromagnetic Spectrum
Definition
a continuous rane of radiant energy that includes radio waves, infrared radiation, visible light, ultraviolet radiation, X-rays, and gamma rays
Term
Electromagnetic Radiation
Definition
any form of radiant energy in the electromagnetic spectrum
Term
Wavelength
Definition
the distance from crest to crest or trough to trough on a wave
Term
Frequency
Definition
expresses the number of times a wave passes a given point in some unit of time (typically one second)
Term
Hertz
Definition
the SI unit of frequency expresses in the units s-1
Term
Frequency
Definition
expresses the number of times a wave passes a given point in some unit of time (typically one second)
Term
Amplitude
Definition
the height of the crest or the depth of the trough with respect to the center line of the wave; the intensity of a wave is related to this
Term
Refraction
Definition
the bending of light as it passes from one medium to another with different densities
Term
Diffraction
Definition
the bending of electromagnetic radiation as it passes around the edge of an object or through narrow openings
Term
Interference
Definition
the interaction of waves that results in either reinforcing or canceling the amplitudes
Term
Frannofer Lines
Definition
set of dark lines in the otherwise continuous solar spectrum
Term
Atomic Emission Spectra
Definition
consist of bright lines on a dark background; appear at specific wavelengths; also called bright-line spectra
Term
Atomic Absorption Spectra
Definition
consist of dark lines produced when free, gaseous atoms are illuminated by external sources of radiation; also called dark-line spectra
Term
Quantum
Definition
the smallest discrete quantity of a particular form of energy
Term
Quantum Theory
Definition
based on the idea that energy is absorbed and emitted in discrete quanta
Term
Quantized
Definition
has values that are restricted to whole-number multiples of a specific base value; the base unit of energy is the quantum
Term
Planck's Constant
Definition
the proportionality constant between the energy and frequency of electromagnetic radiation
Term
Photoelectric Effect
Definition
occurs when light strikes a metal surface and an electric current (a flow of electrons) is produced
Term
Threshold Frequency
Definition
the minimum frequency of light that is required to produce the photoelectric effect
Term
Photon
Definition
quantum of electromagnetic radiation
Term
Work Function
Definition
the amount of energy needed to dislodge an electron from the surface of a metal
Term
Energy Level
Definition
an allowed state that an electron can occupy in an atom
Term
Electron Transitions
Definition
movement of electrons between energy levels
Term
Ground State
Definition
the lowest energy level available to an electron in an atom
Term
Excited State
Definition
any energy state above the ground state
Term
Matter Wave
Definition
the wave associated with any particle
Term
Standing Wave
Definition
confined to a given space and has a wavelength that is related to L of the space
Term
Node
Definition
a location in a standing wave that experiences no displacement
Term
Wave Mechanics
Definition
the description of the wavelike behavior of particles on the atomic level
Term
Schrodinger Wave Equation
Definition
describes the electron in hydrogen as a matter wave and indicates how it varies with location and time around the nucleus solutions to the wave equation are the energy levels of the hydrogen atom
Term
Wave Function
Definition
a solution to the Schrodinger equation
Term
Orbitals
Definition
defined by the square of the wave function; are regions around the nucleus where the probability of finding an electron is high
Term
Quantum Numbers
Definition
unique combination of three integers that define each orbital
Term
Principal Quantum Numbers
Definition
a positive integer that describes the relative size and energy of an atomic orbital or group of orbitals in an atom
Term
Angular Momentum Quantum Number
Definition
an integer that may have any value from 0 to n-1; defines the shape of an orbital
Term
Magnetic Quantum Number
Definition
an integers that may have any value from -l to +l; defines the orientation of an orbital in space
Term
Spin Magnetic Quantum Number
Definition
either +1/2 or -1/2, indicating that the electron spin orientation is either up or down
Term
Pauli Exclusion Principle
Definition
states that no two electrons in an atom each have the same set of quantum numbers
Term
Valence Electrons
Definition
the electrons in the outermost shell of an atom and have the most influence on the atoms chemical behavior
Term
Core Electrons
Definition
electrons in the files, inner-shell in an atom and are not involves in chemical reactions
Term
Degenerate
Definition
orbitals that have the exact same energy level
Term
Hund's Rule
Definition
states that lowest energy electron configuration of an atom is the configuration with the maximum of unpaired electrons in degenerate orbitals, all having the same spin
Term
Electron Configuration
Definition
describes the distribution of electrons among the orbitals of an atom or ion
Term
Aufbau Principle
Definition
the method of building electron configurations one electron at a time; one elctron is added to the lowest-energy orbitals of a ground-state atom; the electron configurations of atoms are built in sequence as atomic number increases in order across the rows of the periodic table
Term
Orbital Diagrams
Definition
one way of showing the arrangement of electrons in an atom or ion using boxes to represent orbitals
Term
Isoelectronic
Definition
atoms and ions that have identical numbers and configurations of electrons as each other
Term
Orbital Penetration
Definition
occur when an electron in an outer orbital has some probability of being as close to the nucleus as an electron in an inner shell
Term
Screening
Definition
the effect when inner-shell electrons protect outer-shell electrons from experiencing the total nuclear charge; also called shielding
Term
Effective Nuclear Charge
Definition
the attractive force toward the nucleus experienced by an electron in an atom; its value is the positive charge on the nucleus reduced by the extent to which other electrons in the atom shield it from the nucleus
Term
Ionization Energy
Definition
the amount of energy needs to remove one mole of electrons from a mole of ground-state atoms or ions in the gas phase
Term
Effective Nuclear Charge
Definition
the attractive force toward the nucleus experienced by an electron in an atom; its value is the positive charge on the nucleus reduced by the extent to which other electrons in the atom shield it from the nucleus
Term
Ionization Energy
Definition
the amount of energy needs to remove one mole of electrons from a mole of ground-state atoms or ions in the gas phase
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