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Ch3 Water/Fitness of Environment
BIO181 BIO 181 Obermiller
63
Biology
Undergraduate 2
06/07/2012

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Cards

Term
The number of molecules in a mole
Definition
Avagadro number
Term
The negative log of the concentration of hydrogen ions in a solution
Definition
pH
Term
The affinity a water molecule has for other water molecules (the result of hydrogen bonding)
Definition
Cohesion
Term
The amount of energy required to raise the temperature of 1 gram of water by 1 degree Celsius
Definition
Calorie
Term
Adding a strong acid to water _______ its pH
Definition
Reduces
Term
Number of moles of a solute per liter of solution
Definition
Molarity
Term
The pH of a solution of KOH with a concention of 10-8 hydrogen ions
Definition
Eight
Term
Solid water's _____ is less than liquid water's _____ allowing it to float
Definition
Density
Term
Energy of Motion
Definition
Kinetic
Term
Type of solution created with water as the solvent
Definition
Aqueous
Term
What are buffers?
Definition
Substances that minimize large sudden changes in pH
Term
Is water polar or non-polar?
Definition
Polar
Term
Why is water polar?
Definition
Uneven distribution of electron density. Water has a partial negative charge near the Oxygen atoms and partial positive charges near the Hydrogen atoms.
Term
What is adhesion?
Definition
When water pulls against the glass molecules of a vessel forming a meniscus.
Term
Does cohesion or adhesion contributes to the water transport in plants?
Definition
Cohesion.

As water evaporates from the leaves, cohesion pulls water from the roots.
Term
Why does water have a greater surface tension than alcohol?
Definition
Hydrogen bonds among surface water molecules resist stretching or breaking the surface.
Term
How does temperature relate to kinetic energy?
Definition
it is a measure of heat intensity based on the average amount of KE in a substance
Term
How does heat relate to kinetic energy?
Definition
it is a measure of the total KE due to the molecular motion in a body of matter.
Term
What is the definition of a calorie?
Definition
the amount of heat energy required to raise the temperature of 1g of water by 1˚C.
Term
What is specific heat?
Definition
The amount of heat energy that must be absorbed or lost for 1g of a substance to change its temperature by 1˚C.
Term
Why does water have such a high specific heat?
Definition
Water resists temperature changes when it absorbs or releases heat due to hydrogen bonds.
Term
What does heating do to the kinetic energy of a substance?
Definition
increases the average kinetic energy (temperature) and increases the rate of evaporation.
Term
Define Heat of vaporization
Definition
the quantity of heat that a liquid must absorb for 1g of it to be converted from the liquid to the gaseous state.
Term
Why is solid water less dense?
Definition
Takes up more space
Term
What is a solution?
Definition
A liquid that is a completely homogenous mixture of two or more substances.
Term
What is a solvent?
Definition
The dissolving agent
Term
What is a solute?
Definition
the substance being dissolved
Term
What is an aqueous solution?
Definition
a solution where water is the solvent.
Term
What type of molecules would you expect water to dissolve?
Definition
Polar
Term
What is hydrophilic?
Definition
Having an affinity for water (liking)
Term
What is hydrophobic?
Definition
Not having an affinity for water (not liking)
Term
What is a mole?
Definition
Amount of a substance that has a mass is grams numerically equivilent to its molecular weight in daltons.
Term
What is an Acid?
Definition
Substance that increases the relative concentration of [H+] in a solution
Term
What is a Base?
Definition
Substance that reduces the relative concentration of [H+] in a solution.
Term
What is vaporization?
Definition

Transformation of a molecule from a liquid to a gas.

Also known as: Evaporation

Term
How does evaporative cooling work?
Definition
Term
What is the heat of vaporization of water?
Definition

Quantity of heat that a liquid must absorb for 1g of it to be converted from the liquid to the gaseous state.

 

Relatively high heat of vaporization, requiring about 580 cal of heat to evaporate 1g of water at room temp.

Term
Why is the heat of vaporization of water higher than alcohol?
Definition

The heat of vaporization of water requires double the heat required to vaporize the same quantity of alcohol or ammonia.

 

This is because hydrogen bonds must be broken before a water molecule can evaporate from the liquid.

Term
At what temperature is water the most dense?
Definition

Water is less dense as a solid than as a liquid.

 

At temperatures above 4 degrees C, water expands when it warms and contracting when it cools.

 

Water begins to freeze when its molecules are no longer vigorously enough to break their hydrogen bonds.

Term
How many hydrogen bonds does ice form?
Definition
Term
What is the most H-bonds that water can form?
Definition
Term
Why do lakes freeze from top to bottom?
Definition
It's because ice is less dense than water, therefore it floats.

 

Term
Why is it important to life that lakes freeze from top to bottom?
Definition
The species of the lake survive in winter time because the ice acts as an insulator.
Term
What is molecular weight?
Definition

The sum of the weight of all the parts of atoms in a compound (expressed in daltons)

 

e.g. NaCl

Na = 23 and Cl = 35.5

MW = 23 + 35.5 = 58.5 daltons

Term
What is one mole of NaCl?
Definition
58.5 grams
Term
How would I make a 2 molar (M) solution of NaCl?
Definition

Na=23 and Cl=35.5

NaCl = 58.5 daltons

2x58.5 = 117

 

117 g of NaCl, add water until the total volume was 1 liter

Term
What is Avagadro's number?
Definition

The actual number of molecules in a mole

 

6.02 x 1023

Term
What does Avagadro's number represent?
Definition

Mole of sucrose contains 6.02 x 1023 molecules and weighs 342g; while mole of ethyl alcohol also contains 6.02 x 1023 molecules but weighs only 46g.

 

This is because molecules in Ethanol are smaller than Sucrose.

Term
What is the concentration of a neutral solution?
Definition
[H+] = [OH-]
Term
What is the concentration of an acidic solution?
Definition
[H+] > [OH-]
Term
What is the concentration of a basic solution?
Definition
[H+] < [OH-]
Term

What are acids?

 

Give an example of an acid.

Definition

Substances that INCREASE the relative concentration of [H+] in a solution.

 

Ex: (in water)

HCL ---> H+ + Cl-

 

Thus, hydrochloric acid increases the # of H+ ions making the solution more Acidic.

Term

What are bases?

 

Give an example of an base.

Definition

Substance that REDUCE the relative concentration of [H+] in a solution.

 

Reduce [H+] directly:

NH3 + H+ ---> NH4+

 

Reduce [H+] indirectly:

NaOH ---> Na+ + OH-

OH- + H+ ---> H2O

Term
If a solution’s H+ concentration is 10-9, what is the PH?
Definition
Nine
Term
If a solution’s H+ concentration is 10-1, what is the PH?
Definition
One
Term
If a solution’s H+ concentration is 10-9, is it acidic, basic, or neutral solutions?
Definition
Basic
Term
If a solution’s H+ concentration is 10-1, is it acidic, basic, or neutral solutions?
Definition
Acidic
Term
What is the pH range of most biological fluids?
Definition
Six - Eight
Term
Definition
Each pH unit represents a tenfold difference in H+ and OH- concentrations.
Term
What do buffers do?
Definition
Substances that minimize large sudden changes in the pH of a solution
Term
Why are buffers important to biological systems?
Definition
Buffers are critical for organisms and life for homeostasis.
Term
What is an example of a buffer?
Definition

H2CO3 (Carbonic Acid) + NaHCO3 (Sodium BiCarbonate)

or NH3 (Ammonia) + NH4Cl (Ammonium Chloride)

 

 

If you add a Strong Base to Buffer, it forms a Weak Base + Water

 

If you add a Strong Acid to Buffer, it forms a Weak Acid + Salt

 

Term
[image]
Definition
pH Scale
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