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Carbons/Hydrocarbons
may 12 Class 2
44
Biology
Undergraduate 2
05/12/2015

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Cards

Term
How many valence electrons does carbon have? how many bonds will it form?
Definition
4, 4
Term
Is Carbon polar or nonpolar?
Definition
nonpolar-which makes it regions of molecules with it hydrophobic
Term
Whatz is the shape of carbon?
Definition
tetrahedral
Term
Can carbon form double bonds?
Definition
Yes
Term
Can carbon chains form rings?
Definition
yes
Term
What are hydrophobic molecules attracted to?
Definition
other hydrophobic molecules
Term
What do carbon rings do to the structure?
Definition
constrains the structure
Term
Carbon structures that aren't in rings have this type of flexibility
Definition
rotational
Term
What is an isomer?
Definition
same chemical formula, different moelcules
Term
What is an example of two structural isomers?
Definition
Pentane, 2-methyl butane
Term
Is chemical formula infromative for dertermining biological functions?
Definition
No
Term
What is an Enantiomer?
Definition
mirror image (like hands)
Term
Give an example of enantiomers
Definition

Ibuprofin: Reduces inflammation and pain

S-Ibuprofin is effective

R-Ibuprofin is ineffective

Term
Why would both the effective and ineffective ibuprofin be put in the same pill?
Definition
Difficult to separate them. They have similar effects, but the ineffective enatiomer does not have any negative effects
Term
What does carbons ability to form double bonds convey? ( two effects)
Definition
  • eliminates free rotation around the bond
  • introduces 'sidedness' to the molecules

cis-trans

 

Term
What is a cis isomer?
Definition
the two molecules (that are the same) are on the same side
Term
What is a trans isomer?
Definition
The two molecules (that are the same) are on the same side
Term
How do different shapes effect the molecules?
Definition
different shapes produce different activities
Term
What is the dif between cis-fats and trans-fats?
Definition

cis-fats are necessary in all cells,shorter shelf life

trans-fats are a heart attact waiting to happen,longer shelf life

Term
What is a hydrocarbon made out of?
Definition
only hydrogen and carbon
Term
What is the purpose of a fat molecule?
Definition
for long term energy storage
Term
Why is hydrocarbons important?
Definition

A broad diversity of molecular structures

hydrophobic

Term
What adds to the diversity of carbon molecules?
Definition

adding polar molecules

adding nonpolar molecules

Term
What is are functional groups?
Definition
individual chemical componets of molecules can have specific effects
Term
What are some effects of adding functional groups?
Definition

changes

  •  the shape (binding/marking)
  • charge/polarity(binding/hydrophobicity)
  • electron distribution(stability, pH)
  • energy storage in bonds(ex, ATP)
Term
Is a methyl group (-Ch3) polar or non-polar?
Definition
non-polar
Term
Is Carbon a functional group?
Definition
yes
Term
If you add a methyl group to a compound, what will it do?
Definition

makes molecule more hydrophobic

Can mask charge in a molecule

Change shape of surface

Term
What is a hystone?
Definition
what dna uses to wrap around itself, has positive charges and likes to wrap around DNA. If you add a methyl group, it wont combine with the DNA
Term
What are some functional groups that contain oxygen?
Definition
  • hydroxyl HO- hydrophillic
  • Carbonyl  >C=O
  • Carboxyl -COOH
Term
What are the two classes of carbonyl group? define them
Definition

ketone= if within structure

aldehyde =if at the end of a structure

Term
What is an example of the carboxyl group?
Definition
carboxylic acid or organic acids; frequently ionize
Term
What do carboxylic acids frequently give up to become charged?
Definition

a proton

tendency to become more negative

Term
Molecules have their own tendencies that are effected by
Definition
the environment
Term
What is an amino group?
Definition

-NH2

Amines, frequently ionizes

unbound electrons attract a proton giving it 4 bonds and a positive charge

polar

Term
What does adding an amino group do to a molecule?
Definition

makes it more hydrophillic

changes the shape

change the charge

Term
What is the Sulfhydryl group?
Definition

-SH

Thoils, frequently form disulfides

Term
What does sulfer do in the sulfhydryl group?
Definition
becomes more electronegative
Term
What is a disulfide?
Definition

two sulfers

can link two sulfhydryls containing molecules together

Term
What is important about sulfhydryls?
Definition
polar and can link with other sulfydryls to form disulfides
Term
What is a phosphate group?
Definition

-OPO3^2-

Phosphate with 4 oxygens around it

polar-always going to be charged, making it more hydrophillic

organic phosphates, always charged

can completely change the interactions within a molecule by drawing electron towards it

Term
What is the role of cynases?
Definition
Attaching phosphate groups to proteins
Term
What is ATP?
Definition
Adenesine Tri Phosphate
Term
How can you change the shape,charge and polarity of a molecule?
Definition
Through adding or taking away functional groups
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