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BioChemistry Keywords Ch05
BioChemistry DPPP-368 Keywords Chapter 5
76
Biochemistry
Undergraduate 3
03/30/2011

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Term
ACETOACETATE -
Definition
Ketone body synthesized in the liver for energy via citric acid cycle CH3-C=O-CH2-COO-
Term
ACETONE -
Definition
Ketone body formed by nonenzymatic decarboxylation of acetoacetate O=C-(CH3)2 + CO2
Term
ACID ANHYDRIDE -
Definition
Carbon-Oxygen functional group, acid + acid —R-C=OOO=C-R—
Term
ADENINE (A) -
Definition
Purine base: amino groups only on rings
Term
ALCOHOL -
Definition
Carbon-Oxygen functional group, most reduced form —R-OH
Term
ALDEHYDE -
Definition
Carbon-Oxygen functional group —R-C=OH
Term
ALDOSE -
Definition
If the carboxyl group is an aldehyde, the sugar is an aldose (i.e. glucose, glyceraldehyde)
Term
AMIDE -
Definition
Acid + amine (remove H2O), polypeptide bonds are amides if formed from 2 amino acids —RO=C-NH
Term
AMINO ACIDS -
Definition
Compounds with amino group & carboxylic acid group (always L-alpha in proteins)
Term
AMINO GROUP -
Definition
Carbon-Nitrogen functional group —R-NH2
Term
AMPHIPATHIC -
Definition
Molecule with both polar (hydrophilic) and nonpolar (hydrophobic) portions in its structure.
Term
AMYLOPECTIN -
Definition
Branched polymer of glucosyl residues (form of starch)
Term
ANOMERIC CARBON ATOM -
Definition
Carbon at which anomers rotate (mutarotation between alpha & beta anomers)
Term
ARACHIDONIC ACID -
Definition
Polyunsaturated fatty acid, 20 carbons, 4 double bonds, omega6 fatty acid
Term
CARBOXYLIC ACID -
Definition
Carbon-Oxygen functional group —R-C=OOH
Term
CERAMIDE -
Definition
Amide formed from sphingosine by attaching fatty acid to amino group
Term
CHOLESTEROL -
Definition
Steroid precursor in human cells for every synthesized steriod hormone
Term
CIS-CONFIGURATION -
Definition
Most natural fatty acids in this position (hydrogens on same side of double bond acyl chain)
Term
CYTOSINE (C) -
Definition
Pyrimidine base; amino and keto groups on ring
Term
DEOXYRIBOSE -
Definition
5 carbon monosaccharide formed from reduction of ribose, major component of DNA
Term
DISACCHARIDE -
Definition
2 monosaccharides bound by O-gylcosidic bond
Term
DISULFIDE -
Definition
Carbon-Sulfur functional group, oxidized —C-S-S-C—
Term
EPIMERS -
Definition
Stereoisomers that differ in position of hydroxyl group at only one asymmetric carbon
Term
ESTER -
Definition
Carbon-Oxygen functional group, alcohol + carboxylic acid —R-C=OO-C-R—
Term
ETHER -
Definition
Carbon-Oxygen functional group, not very soluble —R-C-O-C-R—
Term
FATTY ACIDS -
Definition
Straight aliphatic chain with methyl (omega-C) & carboxyl groups at opposite ends
Term
FRUCTOSE -
Definition
6-carbon monosaccharide, ketohexose
Term
GALACTOSE -
Definition
6-carbon monosaccharide, aldohexose; epimer of glucose
Term
GLUCONATE -
Definition
Conj. base form of gluconic acid, which is a product of oxidation of the aldehyde carbon of glucose
Term
GLUCOSE -
Definition
6-carbon monosaccharide, aldohexose—simple sugar body breaks down for energy
Term
GLUCURONATE -
Definition
Conj. base form of glucoronic acid, which is a product of oxidation of the –OH group at the terminal carbon of glucose
Term
GLYCOGEN -
Definition
Polysaccharide—storage form of glucose in human cells
Term
GLYCOSIDIC BONDS -
Definition
Formed between hemiacetal group of saccharide and –OH or –NH group of another compound
Term
GUANINE (G) -
Definition
Purine base: amino and keto groups on rings
Term
HEPTOSE -
Definition
Monosaccharide sugar with 7 carbon atoms
Term
HEXOSE -
Definition
Monosaccharide sugar with 6 carbon atoms
Term
HYDROXIDE RADICAL -
Definition
Dissociation of water (radiation) H2O ? H* + OH*
Term
HYDROGEN PEROXIDE -
Definition
Participant in the enzyme (reducing-sugar) test for glucose in blood; Glucose + O2 =>glucose oxidase => gluconate + H2O2
Term
?-HYDROXYBUTYRATE -
Definition
ketone body (without a ketone group), synthesized in liver for energy CH3-COH-CH2-COO-
Term
KETONE -
Definition
1 carbonyl group (C=O) bonded to two other carbon atoms R-C-CO-C-R
Term
KETOSE -
Definition
If the carbonyl group is a ketone, the sugar is a ketose (i.e. fructose, dihydroxyacetate)
Term
LACTOSE -
Definition
Disaccharide of galactose and glucose bonded by a ?-1?4 glycosidic bond
Term
LINOLENIC ACID -
Definition
Polyunsaturated fatty acid, 18 carbons, 3 double bonds, omega3 fatty acid
Term
LYSOLECITHIN -
Definition
Product of removal of a fatty acid group from lecithin (phosphatidylcholine)
Term
MONOSACCHARIDES -
Definition
Chain of 3 or more carbons, one forms a carboxyl group w/ double bonded oxygen
Term
MONOUNSATURATED -
Definition
Fatty acid chain that contains 1 double-bonded carbon
Term
N-GLYCOSIDIC BONDS -
Definition
Alpha- or beta-glycosidic bonds found in nucleosides & nucleotides
Term
NITRIC OXIDE -
Definition
Highly toxic, reactive free radical
Term
OLEIC ACID -
Definition
Monounsaturated fatty acid, 18 carbons, 1 double bond, omega9 fatty acid
Term
OLIGOSACCHARIDES -
Definition
3 to 12 monosaccharides bound by N- or O-gylcosidic bonds
Term
?-CARBON(OMEGA) -
Definition
Final methyl group on fatty acid chain regardless chain length
Term
PALMITIC ACID -
Definition
Saturated fatty acid chain of 16 carbons
Term
PENTOSE -
Definition
monosaccharide sugar with 5 carbon atoms
Term
PHOSPHATIDIC ACID -
Definition
Precursor for synthesis of phosphoacylglycerols, phospate group attached @ #3 carbon
Term
PHOSPHATIDYLCHOLINE -
Definition
Major phosphoacylglycerols found in membranes, amphipathic (lecithin)
Term
PHOSPHOESTER -
Definition
Carbon-Phosphate functional group, phosphoric acid + alcohol – H2O (HO)2O=P-O-C—
Term
POLYOL -
Definition
Alcohol product of reduction of a carbonyl on a monosaccharide to a hydroxyl. Example: reduction of both glucose and fructose results in sorbitol, a polyol
Term
POLYUNSATURATED FATTY ACID -
Definition
Fatty acid chain that contains 2 or more double bonded carbon
Term
POLYSACCHARIDES -
Definition
10 to thousands of monosaccharides bound by gylcosidic bonds
Term
PURINE BASES -
Definition
Nitrogen containing rings that accept & donate electrons while still part of ring (2 rings)
Term
PYRIMIDINE BASES -
Definition
Nitrogen containing rings that accept & donate electrons while still part of ring (1 ring)
Term
QUATERNARY AMINE -
Definition
Carbon-Nitrogen functional group, soluble, (i.e. choline) —R-N+-(CH3)3
Term
RADICAL -
Definition
Compound with one unpaired electron, toxic & cause cell destruction or death
Term
RIBOSE -
Definition
5-carbon monosaccharide. If one of the hydroxyl groups is reduced, deoxyribose results.
Term
SORBITOL -
Definition
Alcohol formed by reduction of glucose aldehyde group, a polyol
Term
SPHINGOMYELIN -
Definition
Phosphorylcholine group attached to ceramide; component of cell membrane & myelin sheath
Term
STERIOISOMERS -
Definition
Have same chemical formula but differ in hydroxyl position on 1 or more asymetrical carbons
Term
STEARIC ACID -
Definition
Saturated fatty acid chain of 18 carbons
Term
SULFHYDRYL GROUP -
Definition
Carbon-Sulfur functional group, polar, highly electroneg. & reactive. —R-SH
Term
SUPEROXIDE -
Definition
Radical produced by cell that causes much destruction (superoxide anion) O2-
Term
TETROSE -
Definition
Monosaccharide sugar with 4 carbon atoms
Term
THIOESTER -
Definition
Carbon-Sulfur functional group, sufhydryl + acid – H2O —R-C=OS-C-R—
Term
THYMINE (T) -
Definition
Pyrimidine base: amino and keto groups on ring
Term
TRIOSE -
Definition
Monosaccharide sugar with 3 carbon atoms
Term
UNSATURATED FATTY ACID -
Definition
Contain 1 or more double bonded carbon in chain
Term
URACIL (U) -
Definition
Pyrimidine base: amino and keto groups on ring, replaces thymine in RNA
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