Details

Title: Addition Reactions

Description: Review

Total Flash Cards: 19

Created: 06/08/2009 15:58:57

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Additional Chemistry Flashcards

Cards in this set:

Term

H and H

 

regiochem: not relevant

stereochem: syn

 Definition
H2 and Pt (or Pd or Ni)
Term

H and X

 

regiochem: Markovnikov

stereochem: beyond scope of course

 Definition
HX
Term

Br and H

 

regiochem: Anti-Markovnikov

stereochem: beyond scope of course

 Definition
HBr and ROOR (radical pathway)
Term

H and OH

 

regiochem: Markovnikov

stereochem: beyond scope of course

 Definition
H3O+ (concentrated acid)
Term

H and OH

 

regiochem: Anti-Markovnikov

stereochem: Syn

 Definition

1) BH3 : THF

2) H2O2 , NaOH
Term

Br and Br

 

regiochem: not relevant

stereochem: anti

 Definition
Br2
Term

Br and OH

 

regiochem: OH goes on more substituted C

stereochem: anti

 Definition
Br2 with H2O
Term

OH and OH

 

regiochem: not relevant

stereochem: anti

 Definition

1) MCPBA (or CH3CO3H)

2) H3O+
Term

OH and OH

 

regiochem: not relevant

stereochem: syn

 Definition

OsO4

---->

H2O2
Term
Oxidative cleavage of an alkene
 Definition

1) O3

----->

2) DMS
Term
radical bromination
 Definition
NBS, hv
Term
to make OH a good leaving group
 Definition

TsCl

----->

py

 

(OH turns into OTs)
Term
pKa of HF
 Definition
3.2
Term
pKa of acetate
 Definition
4.74
Term
pKa of RSH
 Definition
8.3 or 10.0
Term
pKa of NH4+
 Definition
9
Term
pKa of CH3SH
 Definition
10.0
Term
pKa of HCN
 Definition
9.2
Term
pKa of ROH
 Definition
17