Shared Flashcard Set

Details

Addition Reactions
Review
19
Chemistry
Undergraduate 1
06/08/2009

Additional Chemistry Flashcards

 


 

Cards

Term

H and H

 

regiochem: not relevant

stereochem: syn

Definition
H2 and Pt (or Pd or Ni)
Term

H and X

 

regiochem: Markovnikov

stereochem: beyond scope of course

Definition
HX
Term

Br and H

 

regiochem: Anti-Markovnikov

stereochem: beyond scope of course

Definition
HBr and ROOR (radical pathway)
Term

H and OH

 

regiochem: Markovnikov

stereochem: beyond scope of course

Definition
H3O+ (concentrated acid)
Term

H and OH

 

regiochem: Anti-Markovnikov

stereochem: Syn

Definition

1) BH3 : THF

2) H2O2 , NaOH

Term

Br and Br

 

regiochem: not relevant

stereochem: anti

Definition
Br2
Term

Br and OH

 

regiochem: OH goes on more substituted C

stereochem: anti

Definition
Br2 with H2O
Term

OH and OH

 

regiochem: not relevant

stereochem: anti

Definition

1) MCPBA (or CH3CO3H)

2) H3O+

Term

OH and OH

 

regiochem: not relevant

stereochem: syn

Definition

OsO4

---->

H2O2

Term
Oxidative cleavage of an alkene
Definition

1) O3

----->

2) DMS

Term
radical bromination
Definition
NBS, hv
Term
to make OH a good leaving group
Definition

TsCl

----->

py

 

(OH turns into OTs)

Term
pKa of HF
Definition
3.2
Term
pKa of acetate
Definition
4.74
Term
pKa of RSH
Definition
8.3 or 10.0
Term
pKa of NH4+
Definition
9
Term
pKa of CH3SH
Definition
10.0
Term
pKa of HCN
Definition
9.2
Term
pKa of ROH
Definition
17
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