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04/26/2005

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Term
Define Diffusion
Definition
The phenomenon of material transport by atomic motion.
Term
How is diffusion demonstrated?
Definition
By using a diffusion couple.
Term
Define impurity diffusion/interdiffusion.
Definition
The process whereby atoms of one metal diffuse into another.
Term
Define self diffusion.
Definition
When the atoms exchange positions in a pure metal.
Term
Define Vacancy diffusion.
Definition
The interchange of an atom from a normal lattice positon to an adjacent vacant lattice site or vacancy.
Term
Define interstitial diffusion.
Definition
The type of diffusion that allows atoms to migrate from an interstitial position to a neighboring one that is empty.
Term
Define diffusion flux.
Definition
The rate of mass transfer from one metal to another during diffusion.
Term
What is steady-state diffusion?
Definition
When the diffusion flux is constant w.r.t. time.
Term
What is fick's first law used to find?
Definition
Fick's first law defines the diffusion flux for a steady-state diffusion process.
Term
What is nonsteady-state diffusion?
Definition
The more practical of the two types, where the diffusion flux and concentration gradient are variables that change w/ time.
Term
What is fick's second law used for?
Definition
Finding the concentration diffused for a certain time with a nonsteady-state diffusion process.
Term
Which variable has the most influence on diffusion?
Definition
Temperature
Term
What is the activation energy?
Definition
The energy required to produce the diffusion motion of one mole of atoms. It is the reason temp. is the most influential of all diff. variables.
Term
Where does the interest lie when considering diffusion between polymeric materials?
Definition
The diffusive motion of small foreign molecules (O2,H20,CO2,CH4) between molecular chains. This directly affets how a polymer diffuses.
Term
Describe ionic diffusion.
Definition
Usually occurs in a vacancy mechanism. It also occurs in pairs to maintiain neutrality. The movement of ion's creates electric current, therfore the diffusion flux represents the conductivity of a material.
Term
How are the mechanical properties of materials ascertained?
Definition
They are found by performing carefully designed laboratory experiments that replicate as nearly as possible the service conditions.
Term
What is the difference between structural engineers and materials engineers?
Definition
Structural-determine stresses and stress distributions within members that are subjected to well-defined loads.
Materials-concerned with the production/fabrication of materials to meet certain requirements
Term
What is a tension test?
Definition
One of the most common stress-strain tests where a specimin is deformed to fracture from a gradually increasing tensile load along the axis of rotation. Measurements of elongation are necessary for data collection.
Term
Define engineering stress
Definition
A.K.A. Sigma, engr. stress is defined by the relationship of the instantaneous load divided by the initial cross section.
Term
Define engineering strain.
Definition
It is the change in length divided by the initial length. This gives the percent change in length
Term
What is the difference between a compression and a tensile test?
Definition
Compression applies a compressive force, while tensile pulls apart.
Term
What is a shear/torsional test?
Definition
Test using a pure shear force that provides a rotational force about a fixed axis.
Term
What is the modulus of elasticity?
Definition
A.k.a young's modulus, E is a constant or proportionality that directly relates stress and strain. It also represents the stiffness of the material.
Term
What must be true for elastic deformation?
Definition
The stress-strain relationship must be proportional, following young's modulus. This may be thought of the stiffness. It also is nonpermanent.
Term
What is anelasticity?
Definition
This is the time dependant elastic behavior that is due to the microscopic and atomistic processes that cause deformation. Usually too small to recognize.
Term
What is poisson's ratio?
Definition
v, it is defined as the ratio of lateral to axial strains, and is used when defining the elastic properties of materials.
Term
Define yielding.
Definition
it is the stress level when plastic deformation begins.
Term
What is the yield strength?
Definition
It is the point when the stress-strain curve goes from elastic to plastic
Term
What is the tensile strength?
Definition
TS is the stress at the maximum on the stress-strain curve
Term
What is ductility?
Definition
It is a measure of the degreee of plastic deformation that has been sustained at a fracture. Level of brittleness.
Term
What is resilience?
Definition
the capacity of a material to absorb energy when it is deformed elastically and then upon unloading to have this energy recovered.
Term
Define toughness?
Definition
the measure of the ability of a material to absorb energy up to fracture.
Term
What is true stress, and what is different from true stress and engr. stress?
Definition
True stress represents the force per unit area but uses the instantenous cross section instead of the initial cs.
Term
What is true strain and what is different from true strain and engr. strain?
Definition
True strain represents the percent change in length but uses the instantenous length instead of initial length
Term
Define flexural strength.
Definition
the stress at the fracture during a flexure test, which is what we did in lab.
Term
What are elastomers?
Definition
type of polymers with a rubber-like elasticity
Term
What is hardness, and how is it measured?
Definition
A measure of a material's resistance to localized plastic deformation (scratch or dent). Measured by the depth or size of the resulting indentation.
Term
What is design stress?
Definition
Redefining stress measurements to allow for unanticipated failures.
Term
What is safe stress?
Definition
Aka working stress, it is used instead of design stress because it includes an added factor of safety to further decrease the # of failures.
Term
describe an edge dislocation.
Definition
localized lattice distortion exists along the end of an extra half-plane of atoms along a dislocation line.
Term
describe an screw dislocation.
Definition
the result of a shear distortion, where its dislocation line is actually a spiral atomic ramp.
Term
What is a slip.
Definition
The process by which plastic deformation is produced by dislocation motion. The slip plane is the plane along the dislocation line
Term
what is dislocation density?
Definition
the number of dislocations in a material, expressed as the total dislocation length per unit volume.
Term
Describe slip systems.
Definition
The slip plane defines directions (called slip directions) along which dislocation motion occurs.
Slip systems are a combination of slip directions and slip planes. The slip plane usually has the most dense atomic packing.
Term
What is unique about deformation in plastics?
Definition
The dislocation motion occurs along the slip system that has the most favorable orientation.
Term
How does the grain size in a polycrystalline metal influence its mechanical properties?
Definition
The creation of grain boundaries creates a permenant dislocation of different orientations where the motion of grains must change direction because of an angled grain boundary. Therefore the smaller the grains, the stronger and harder it is.
Term
Describe solid solution strengthening.
Definition
this involves alloying with impurity atoms that go into either substitutional or interstitial solid solutions. By increasing the concentration of impurity results in higher strengths.
Term
What is strain hardening?
Definition
It is the phenomenon whereby a ductile metal becomes harder and stronger as it is plastically deformed. Aka cold working, because the temp. at deformation is relatively "cold" compared to its melting temp.
Term
Describe the process of recovery.
Definition
It is when some of the stored internal strain energy is relieved by virtue of dislocation motion. There is a decrease in the # of dislocations, and physicla properties are recovered to their precold-worked states.
Term
Describe the process of recrystalization.
Definition
this is the formation of a new set of strain-free and equiaxed grains (i.e. having approx. equal dimentions in all directions).
Term
How is recrystallization temperature used?
Definition
It describes recrystallization behavior of a particular metal alloy, and is the temp at which recrystall. just reaches completion.
Term
Describe the phenomenon of grain growth.
Definition
After recry. is complete, the strain free grains will continue to grow if left at elevated temp. This phenomenon is known as grain growth. It can occur in any type of material.
Term
Describe the mechanism of elastic deformation.
Definition
It is the elongation of the chain of molecules from their stable conformations, in the direction of the applied stress.
Term
Describe the deformation of elastomers.
Definition
Since they are so rubbery, it is hard to define any deformation of elastomers. The driving force is entropy, which is a measure of disorder in a system. When returning to its natural state, the entropy will increase as the chains become tangled and less orderly in the system.
Term
Name the causes for failure
Definition
1.)improper material selection/processing
2.)inadequate design/misuse
3.)Understanding the environment
Term
What are the two modes of fracture, and what makes them different?
Definition
Ductile- substantial plastic deformation w/ high energy absorbtion
brittle- very little plastic deformation and low energy absorbtion
Term
What are the two steps of fracture
Definition
Crack formation, and crack propogation
Term
What is a stable crack? Which kind of fracture is it associated with?
Definition
A crack that resists extension unless further stress is applied. It is associated with ductile cracks.
Term
What is a unstable crack? Which kind of fracture is it associated with?
Definition
When crack propogation continues after being initiated. It is assoc. with brittle cracks.
Term
Explain a ductile fracture.
Definition
It is stable, and the cracking grows in the direction parallel to the major axis.
Term
Describe a brittle fracture.
Definition
They are unstable, and they take place w/o any deformation. Cracking occurs in the direction of the crack perpendicular to the axis of tensile stress.
Term
What are transgranular fractures?
Definition
They are fractures that pass through grains, and break atomic bonds.
Term
What are intergranular fractures?
Definition
It is when the fracture takes place along the grain boundaries.
Term
Describe the wonderful world of fracture mechanics.
Definition
The subject that allows one to quantify the relationship between material properties, stress level, pressure of cracking producing flaws, and crack propogation mechanics
Term
What are stress raisers?
Definition
When the flaws that exist in the brittle materials amplify an applied stress in their locale.
Term
What is the stress concentration factor?
Definition
K, it represents the ratio of the maximum stress at the crack tip compared to the magnitude of the nominal applied tensile stress
Term
Define fracture toughness.
Definition
A property that is a measure of a material's resistance to brittle fracture when a crack is present.
Term
When is plane strain used, and what does it mean?
Definition
Plane strain is used when the material the specimen thickness is much greater than the crack dimentions. This gives a new fracture toughness, which accounts for no strain components in the perpendicular faces to the front and back.
Term
Why can you not test the plastic deformation in both crystalline and noncrystalline ceramics?
Definition
Because almost no plastic deformation occurs before fracture.
Term
Do brittle ceramics have higher strengths in the compression tests or the tension tests?
Definition
Compression tests, by a factor of 10.
Term
What is crazing when referring to thermoset polymer failure?
Definition
The inhomogeneous mixing; in low yield stress regions.
Term
What is shear yielding when referring to thermoset polymer failure?
Definition
The homogenius flow of plastic material that also includes covalent bond cessation
Term
List the service environment, specimen geometry factors.
Definition
1.)flaws/scratches
2.)thermal history
3.)temperature
4.)geometry
5.)molecular weight
6.)strain rate
7.)processing orientation
Term
Why were impact fracture testing procedures a bad source of information when gathering data for plastic deformation?
Definition
They tested the material under conditions that were poor for testing purposes. The conditions tended to represent the most severe.
Term
What are the two impact testing technuqies, and what are they used for?
Definition
The two tests are the Charpy and the Izod, and they are used to measure impact energy.
Term
What is ductile-to-brittle transition?
Definition
A process that with decreasing temperature, and is one of the primary functions of the Charpy and Izod tests.
Term
What is fatigue?
Definition
the form of failure that occurs in structures subjected to dynamic and fluctuating stresses (eg bridges, aircrafts, machine coponents.)
Term
What is fatigue limit?
Definition
it represents the largest value of fluctuating stress that will not cause failure for essentially an infinite number of cycles
Term
What is fatigue strength?
Definition
The stress level at which failure will occur for some specified number of cycles.
Term
What is fatigue life?
Definition
The number of cycles to cause failure at a specified stress level
Term
What is the purpose of the s-n curve?
Definition
It is a plot of stress versus the number of cycles.
Term
Describe fatigue in polymers
Definition
fatigue occurs at stress levels that are low relative to the yield strength. Much lower than metals. More sensitive to loading frequency than metals. Failure actually usually do to softening of material rather than typical fatigue process.
Term
What are the three steps for fatigue failure?
Definition
1.)crack initiation
2.)crack propogation
3.)final failure
Term
What are some factors that affect fatigue life?
Definition
1.)Mean stress-the average of the stress applied
2.)Surface effects- its where the maximum stress is for many common loading situations.
3.)Geometric design
Term
What is primary/transient creep?
Definition
continuously decreasing creep rate
Term
What is secondary creep?
Definition
the rate is constant
Term
What is tertiary creep?
Definition
The rate of creep is accelerating
Term
What do all creep behavior lead to?
Definition
A decrease in the cross sectional area, and an increase in the strain rate.
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