Term
| The Williamson Ether Synthesis |
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Definition
| R-OH -NaH/THF-> R-O- Na+ -R'Br-> R-O-R' |
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Term
| Alkoxymercuration of Alkenes |
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Definition
| R=R' -1.(CF3CO2)2Hg/R"OH-2.NaBH4-> R"O-R-R' markov |
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Term
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Definition
R-O-R' -HX/H2O-> R-OH X-R'
Does not work with HCL |
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Term
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Definition
| O2/Ag2O 300 C or m-Chloroperoxy benzoic acid/CH2Cl2 |
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Term
| Acid-Catalyzed Epoxide Opening |
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Definition
| HX/Ether If there is a tert C on epoxide, OH goes to less substituted C |
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Term
| Base-Catalyzed Epoxide Opening |
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Definition
| ROH/H2O ROH deprotonates and attacks LEAST substituted C or H3O+ new OH takes MOST substituted C |
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Term
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Definition
thiol= (S) version of alcohol
SH= Mercapto
sulfide= (S) version of ether |
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Term
| Oxidation of thiol to Disulfide |
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Definition
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Term
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Definition
| RS- + R'CH2Br -> RSCH2R' + Br- |
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Term
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Definition
| RCH2Br -1.(H2N)2C=S/2.H2O, NaOH-> RCH2SH |
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Term
| oxidation of sulfides to sufoxides and sulfones |
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Definition
| R-S-R' -H2O2-> R-S=O-R' -RCO3H-> R-S=O=O-R' |
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