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Unit 6 vocabulary : Acid/Base Equilibria
Unit 6 vocabulary : Acid/Base Equilibria
26
Chemistry
12th Grade
02/05/2013

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Term
Hydronium ion
Definition
The ion H3O, consisting of a protonated water molecule and present in all aqueous acids.
Term
Bronsted-Lowry Acid
Definition
Any substance that donates hydrogen ion (proton).
Term
Bronsted-Lowry Base
Definition
Any substance that accepts a proton.
Term
Amphiprotic
Definition
Brønsted-Lowry acids and Lewis acids. It means a substance capable of donating and accepting protons, such as water and bicarbonate. Amphiprotic species must have acidic protons.
All amphiprotic substances are amphoteric; not all amphoteric species are amphiprotic.
Term
Amphoteric
Definition
Lewis acids. It means a substance capable of acting both as a lone pair acceptor and a lone pair donor, such as aluminium hydroxide and tin dioxide. Amphoteric species don't necessarily need acidic protons.
All amphiprotic substances are amphoteric; not all amphoteric species are amphiprotic.
Term
Conjugate Base
Definition
Acids form a conjugate base.
Term
Conjugate Acid
Definition
Bases form a conjugate acid.
Term
Conjugate Acid-Base Pair
Definition
Ex) HNO3 + H2O -> H3O + NO3
A B CA CB
Term
Autoionization
Definition
when H2O breaks down into H+ and OH-. the reaction is at equilibrium, because the H2O is always breaking down into H+ and OH-, which is constantly forming H2O.
It is at a pH 7 because the [H+] concentration is going back and forth at equilibrium, causing it to be neutral.
Term
Ion Product Constant, Kw
Definition
KW = [H3O+][OH-]
Term
pH
Definition
A measure of how acidic or basic (alkaline) an aqueous solution is.
Term
Acid Dissociation Constant, Ka
Definition
The acid dissociation constant is the equilibrium constant of the dissociation reaction of an acid and is denoted by Ka.
Term
Percent Ionization
Definition
The percentage of the weak electrolyte that ionizes in a solution of given concentration.
Term
Polyprotic Acids
Definition
An Acid that can form two or more hydronium ions per molecule; often a least one step of ionization is weak.
Term
Base Dissociation Constant, Kb
Definition
Equilibrium constant that measures the extent of dissociation for a base.
Term
Hydrolysis
Definition
When water reacts with another substance and as a result the oxygen in water makes a bond with the substance.
Term
Oxyacids
Definition
An oxyacid is an acid that contains an oxygen atom bonded to a hydrogen atom and at least one other element.
Ex) Sulfuric acid (H2SO4), phosphoric acid (H3PO4), and nitric acid (HNO3) are all oxyacids.
Term
Carboxylic Acids
Definition
Carboxylic acid is an organic compound containing the COOH functional group.
Ex) acetic acid, CH3COOH
Term
Lewis Acid
Definition
A substance that can accept an electron pair from a base; thus, AlCl3, BF3, and SO3 are acids.
Term
Lewis Base
Definition
A substance that can donate an electron pair; examples are the hydroxide ion, OH-, and ammonia, NH3.
Term
Common-Ion Effect
Definition
The lowering of the degree of ionization of a compound when another ionizable compound is added to a solution; the compound added has a common ion with the other compound.
Term
Buffered Solutions (Buffers)
Definition
Buffer systems contain both an acid and a base(either an acid and its conjugate base or a base and its conjugate acid).
Term
Buffer capacity
Definition
The relative ability of a buffer solution to resist pH change upon addition of an acid or a base.
Term
Henderson-Hasselbalch equation
Definition
An equation expressing the pH of a buffer solution as a function of the concentration of the weak acid or base and the salt components of the buffer.
Term
pH Titration Curve
Definition
A curve relating pH to the equivalents of strong base added per equivalent of acid in the solution.
Term
Indicators
Definition
Indicators are dyes which change colors to show acidity or alkalinity. These are qualitative because they show acidity or alkalinity by changing color.
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