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Chemistry Unit 2
Chapters 4 & 5
72
Chemistry
Undergraduate 1
10/02/2015

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Term

Strong Acids

 

HCl

Definition
Hydrochloric Acid
Term

Strong Acids

 

HBr

Definition
Hydrobronic Acid
Term

Strong Acids

 

HI

Definition
Hydroiodic Acid
Term

Strong Acid

 

HNO³

Definition
Nitric Acid
Term

Strong Acid

 

HclO³

Definition
Chloric Acid
Term

Strong Acid 

 

HClO4

Definition
Perchloric Acid
Term

Strong Acid

 

H2SO4

Definition
Sulfuric Acid
Term
Percipitate
Definition
An insoluable solid product that seperates from a solution
Term
Soluability
Definition
The maximum amount of solute that will dissolve in a given quantity of a solvent @ a specific temperature
Term

Soluability Rules 

CASHIN N 1's

Definition

+1 charge = soluable 

Chlorates

Acetates 

Sulfates

Halogens 

N²: Nirates & Ammonium (NH4)

1's: goup 1 elements

Term

Insoluablity Rules 

SCOOP-Choclate

Definition

Sulfide

Carbonates 

O²: salts

OH: salts

Phosphates

Chromates

*larger the charge less soluable*

Term

Dissolving Properties 

Solids vs. Gases

Definition

Solids: some dissolve eaiser @ higher temps

 

Gases: Dissolve easier @ lower temps

Term
Ionic Equations
Definition
  • Keeps precipitant together 
  • gets rid of ions that don't contribute to the equation 
Term
Spectator Reactions
Definition
ions that don't contribute anything to the reaction
Term
Aqeous Solution
Definition
a homogeneous mixture of 2+ substances
Term
Electrolyte
Definition

a substance that dissolves into water to yield a solution that conducts electricity


* presence of ions allows it to conduct electricity*

Term
Nonelectrolye
Definition
A substance that dissolves in water to yield a soltion that dosen't conduct electricity
Term
Dissociation
Definition
When an ionic compound breaks into its ions
Term
Ionization
Definition
When a covalent molecular compound forms into it's ions
Term
Dissolving
Definition
When a molecular compound stays intact
Term
Strong Electrolyte
Definition
An electrolyte that dissociates comletely
Term
Strong Bases
Definition

Metals in groups 1&2

LiOH, NaOH, KOH, RbOH, CaOH,

Ca(OH)2, Sr(OH)2, Ba(OH)2

Term
Acids
Definition
a proton (H+) donor
Term
Bases
Definition
a proton (H+) acceptor
Term
Monoprotic Acids
Definition
strong acids wher each mlecule has 1 proton to donate
Term
Diprotic Acids
Definition

Each acid milecule has 2 protons that it can donate 

*only strong during first ionization*

Term
Polyprotic Acids
Definition
  • Those w/ many protons 
  • each ionization is incomplete
Term
Neutralization Reaction
Definition

A reaction between an acid and a base that produces water and salt 

*anion from the acid & cation from the base*

Term
Oxidation-Reduction Reaction/Redox Reactions
Definition
chemical rection in which high energy electons are transferred from 1 reactant to a lower energy reactant
Term
OIL RIG
Definition

OIL: Oxidation is the loss of electrons 

 

RIG: Reduction is the gain of electrons

*when you gain an electron the oxidation # decreases*

Term
Assigning Oxidation #s
Definition

Free elements are 0 (neutral)

Ions: thier charge from PT

Oxygen is -2

Hydrogen is +1

Sum of the molecule is 0 or change indicted on the molecule 

Outside first Inside Last

Term

Type of Redox Reaction

 

Displacement Reaction

Definition

metals are switched out

Zn + CuCl2 --> ZnCl + Cu 

Term

Type of Redox Reaction

 

Combination Reaction

Definition

two ions come together 

N2 + 3H2 --> 2NH3 

Term

Type of Redox Reaction 

 

Decomposition 

Definition

Start with a compound and break down into ions

2NaH --> Na = H2

Term

Type of Redox Reaction

 

Disproportion Reaction 

Definition

when a substance is reduced and oxidized at the same time 

2H2O2 --> 2H2O2 + O2

Term

Type of Redox Reaction

 

Combustion Reaction 

Definition

when something burns in the presence of oxygen and creates carbon dioxide and water

CH4 + 2O2 --> CO2 + 2H2O

(C1)(V1) = (C2)(V2)

Term
Molarity
Definition

the # of moles of solute per liter of solution

Symbol: M

Equation: M = Moles of solute/liters solution

g=MW (g/mol) x M (mol/L) x V(L)

Term
Titration of an acid w/ a base
Definition
base of the known concentration is added to an acid of unknown concentration
Term
Dilution
Definition
the process of preparing a less concentrated solution from a more concentrated one
Term
Energy
Definition
The capacity to do work or transfer heat
Term
Kinetic Energy
Definition
energy that results from motion
Term
Potential Energy
Definition
energy possessed by an object by virtue of its position
Term
Thermal Energy
Definition
a form of kinetic energy when energy associated w/ the random motion of atoms & molecules
Term
How does thermal energy measured?
Definition
measures changes by monitoring temp changes
Term
Chemical Energy
Definition
energy stored w/in the structure units (molecules/polyatomic ions) of chemical substances
Term
Electrostatic Energy
Definition
potential energy that results from the interaction of charged particles
Term
law of conservation of energy
Definition
when energy of one form disappears, the same amount of energy must appear in another form(s)
Term
System
Definition
the specific part of the universe that is of interest
Where the chemical reaction takes place
Term
Surroundings
Definition
rest of the universe outside of the systems
Term
Exothermic Process
Definition
process that gives off energy
ex) handwarmers, burning a log
Term
Endothermic Process
Definition
process that absobrs thermal energy as heat
ex) cold packs
Term
What is the SI unit of energy and what does it measure?
Definition
Joules & amount of kinetic energy
Term
Thermodynamics
Definition
study of the effects of work, heat, and energy (E) of a system
Term
Open System
Definition
chain exchange mass & energy w/ its surroundings
Term
Closed System
Definition
allows the transfer of energy nut not mass
Term
isolated system
Definition
does not exchange either mass or energy w/ its surroundings
Term
First Law of Thermodynamics
Definition
mass & energy can't be created or destroyed
Term
Internal Energy
Definition
the system = delta U
Delta U = Uf - Ui
total must be 0
one +, one -
Term
Heat
Definition
when a system releases of absorbs heat it's internal energy (delta U) changes
Term
q = ?
Definition
q = heat
Term
w = ?
Definition
w = work
Term
U decreases when...
Definition
releasing heat = q<0
doing work ON the surrounding
work ON the surrounding = w<0
Term
U increases when...
Definition
heat is absorbed by the system q>0
work done on the system w>0
Term
Enthalpy
Definition
H = U+PV
internal E of system + (pressure x vol of system)
Term
Change in Enthalpy
Definition
delta H = delta U + delta(PV)
Term
Enthalpy (delta H)
Definition
the different between the enthapies of the products & the enthapies of the reactants
Term
Thermochemical Equations
Definition
chemical equations that show the enthalpy changes & the mass relationships
Term
Guidelines of thermochemical equations
Definition
1. always specify the physical states of all reactant & products becasue they help determine actual enthropy stages
2. multiply both sides of a thermochemical equation by a factor n
3. when we reverse a chemical equation we have to reverse the rules of delta H
Term
Calorimetry
Specific Heat (s) of a substance
Definition
the amount of heat required to change 1g of the substance by 1 degree C
Term
Calorimetry
Heat Capacity
Definition
heat required to raise the temp of an object by 1 degree C
Term
Exothermic reactions what do they do to the specific heat equation?
Definition
Make it negative
Term
Hess's Law
Definition
Change in enthalpy that occurs when reactants are converted to products in a reaction is the same where they reaction takes place in one step or 3
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