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Test 4
Chapter 7, 8, 9, 10, 11 ISBN: 0321741536
60
Chemistry
Undergraduate 2
06/29/2012

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Term
Solution
Definition
a homogeneous mixture in which one substance called the solute is uniformly dispersed in another substance called the solvent
Term
Hydration
Definition

when water molecules surround each ion.


hydration of the ions diminishes their attraction to othe rions and keeps them in solution


Ex:

             H2O

NaCl(s)------->Na+ (aq) + Cl- (aq)

Term
Nonpolar solutes
Definition
requier nonpolar solvents for a solution to form
Term
"like dissolves like"
Definition

way of saying that the polarities of a solute and a solvent must be similar in order to form a solution

 

Solute (polar/ionic) --> Solvent (polar)

Term
Electrolytes
Definition
dissolve in water and when they separate into ions forming solutions that are able to conduct electricity
Term
nonelectrolytes
Definition
dissolve in water at molecules and can't conduct electricity
Term
Dissociation
Definition

some or all of the solute that dissolves produces ions


in an equation for dissociation of a compound in water , the charges must balance


ex:


Mg(NO3)2(s)  H2> Mg2+(aq) +2NO3-(aq)

Term
strong electrolyte
Definition
100 % dissociation of the solute into ions
Term
Weak Electrolyte
Definition
compound that dissolves in water mostly as molecules
Term
Equivalent (Eq)
Definition
the amount of that ion equal to 1 mole of positive or negative electrical charge
Term
solubility
Definition
the amount of a solute tha tcan dissolve ina given amount of solvent
Term
unsaturated solution
Definition
when a solute readily dissolves when added to the solven, the solution does not continan the maximum amount of solute
Term
saturated solution
Definition
a solution that contains all the solute that can dissolve
Term
supersaturated solution
Definition
when a saturated solution is carefully cooled it contains more solute than the solubility allows
Term
Henry's Law
Definition

the solubility of gas in a liquid is directly related to the pressure of that gas above the liquid

 

at higher pressures, there are more gas molecules available to enter and dissolve in the liquid

Term
soluable salts
Definition
ionic compounds that dissolve in water
Term
insoluble salts
Definition
ionic compounds that remain as solids even in contact with water
Term
Concentration of solution
Definition

C = amount of solute

        amount of solution

Term
Mass Percent
Definition

describes the mass of the solute in grames for exactly 100g of solution

 

m/m = mass of solute(g)

               mass of solution (g)

Term
Volume percent (v/v)
Definition

v/v =  volume of solute  X 100

volume of solution

Term
Mass/volume Percent (m/v)
Definition

    grams of solute      X 100%

milliliters of solution                 

Term
Molarity (M)
Definition

moles of solute

liters of solution

Term
dilution
Definition

a solvent (usually water) is added to a solution which increases the volume.

 

As a result the concentration of the solution decreases

Term
Colliods
Definition

the solute particles are large molecules, they are homogeneous mixtures that do not separate or settle out

 

  • have medium-size particles
  • cannot be filtered
  • can be separated by semipermeable membranes
  • fog, whipped cream, milk, cheese, blood plasma, pearls
Term
Suspensions
Definition
heterogeneous, nonuniform mixtures that are very different from solutions or colliods the particles of a suspension can often be seen with the naked eye
Term
colligative properties
Definition
depend only on the number of solute particles in the solution
Term
osmosis
Definition
water molecules move through a semipermeable membrane from teh solution with the lower concentration fo solute into a solution with the higher solute concentration
Term
osmotic pressure
Definition
prevents the flow of additional water into the more concntrated solution
Term
reverse osmosis
Definition
a pressure greater than the osmotic pressure is applied to a solution
Term
isotonic solutions
Definition
exert the same osmotic pressure as body fluids such as blood
Term
hypotonic solution
Definition
has a lower solute concentration water flows into the cell by osmosis
Term
hypertonic solution
Definition
has a higher solute concentration water goes out of the cell into the hypertonic solution by osmosis
Term
Dialysis
Definition

similar to osmosis

a semipermeable membrane (called dialyzing membrane) permits small solute molecules and ions as well as solbent water molecules to pass through, but retains large particles such as colloids

Term
Chapter 8
Definition
Term
Acids
Definition

substances that produce hydrogen ions(H+) when they dissolve in water

 

are electrolytes

sour taste

turn litmus red

neutralize bases

Term
Naming Acids
Definition

Acids with H and a nonmetal are named with the prefix hydro and end with ic acid

Ex: hydrochloric acid

 

acids with H and  a polyatomic ion are named by changing the end of the name of the polyatomic ion afrom ate to ic acid or ite to ous acid

Term
Bases
Definition
are ionic compounds that dissociate into a metal ion adn hydroxide ions (OH-) when they dissolve in water
Term
Arrhenius bases
Definition

produce OH- ions in water

taste bitter or chalky

are electrolytes

feel soapy or slippery

neutralize acids

Term
Bronsted-Lowry Acids and Bases
Definition
  • acids donate a proton (H+)
  • bases accept a proton (H+)

Ex: in teh reaction of ammonia and water

  • NH3 is the base that accpets H+
  • H2O is the acid that donates H+
Term
Conjugate Acid-base pairs
Definition

in any acid-base reaction, there are two conjugate acid-base pairs

  • Each pair is related by the loss and gain of H+
  • One pair occurs in the forward direction
  • one pair occurs in the reverse direction
Term
Buffers
Definition
  • resist changes in pH from the addition of acid or base
  • in the body, absorb H3O+ or OH- from foods and cellular processes to maintain pH
  • are important in the proper functioning of cells and blood
  • in blood maintain a pH close to 7.4. A change in the pH of the blood affects the uptake of oxygen and cellular processes
Term
Buffer Solution
Definition
  • contains a combination of weak acid-base conjugate pairs
  • may contain a weak acid and a salt of its conjugate base
  • typically has equal concentrations of a weak acid and its salt
  • may also contain a weak base and a salt of the conjugate acid
Term

function of the weak acid in a buffer

Definition

neutralize a base

 

Ex: the acetate ion produced adds to the available acetate

 

HC2H3O2 +OH- →C2H3O2- + H2O

acetic acid             base        acetate ion        water

Term

Function of the Conjugate Base

 

Definition
  • function of the acetate ion  C2H3O2- is to neutralize H3O+ from acids
  • the acetic acid produced contributes to the available weak acid

Ex:

C2H3O2-  + H3O+ → HC2H3O2 + H2O

 

 

Term
Buffer Action
Definition

Buffer action occurs as

  • the weak acid in a buffer neutralizes base
  • the conjugate base in teh buffer neutralizes acid
  • the pH of the solution is maintained

 

Term

Chapter 9

Definition

 

 

Term
nuclear radiation
Definition

  • is the radiation emitted by an unstable atom
  • takes the form of alpha particles, neutrons, beta particles, positrons, or gamma rays

 

Term
radioactive isotope
Definition

 

  • an unstable nucleus
  • emits radiation to become more stable
  • can be one or more of the isotopes of an element

 

Term

Stable Isotopes

 

 

Definition

 Magnesium- 2412Mg (Magnesium-12)

Iodine- 12753I (Iodine-127)

Uranium- None

Term

Types of Radiation:

  1. Alpha particle (α)
  2. Beta particle (β)
  3. Positron (β+)
  4. Gamma ray (γ)
Definition
  1. (α)- two protons and two neutrons
  2. (β)- is a igh-energy electron
  3. (β+)-a positive electron
  4. (γ)- high-energy radiation released from a nucleus
Term
Alpha Particle
Definition
  • Symbol:  α,  42He
  • Change in Nucleus: 2 protons and 2 neutrons are emitted as alpha particles
  • Mass Number: 4
  • Charge: +2

 

Term
Beta Particle
Definition

Symbol:                 β, 0-1e

Change:                a neutron changes to proton and

                                  electron is emitted

Mass Number:      0

Charge:                 -1

Term
Positron
Definition

Symbol:              β+,  0+1e

Change:             a proton changes to a neutron and

                                emits a positron

 

Mass number:   0

Charge:             +1

Term
Gamma Ray
Definition

Symbol:                  γ,   00γ

Change:                  energy is lost to stabilize the nucleus

Mass Number:        0

Charge:                   0

Term

Radiation protection

 

 

Definition
  • alpha particles→paper and clothing
  • beta particles→lab coat or gloves
  • gamma particles→a lead shield or thick concrete wall
  • limiting the amount of time spent near a radioactive source
  • increasing the distance from the source

 

Term
Alpha Decay
Definition
  • when a radioactive nucleus emits an alpha particle, a new nucleus forms that has
    • a mass number that is decreased by 4
    • an atomic number that is decreased by 2
Term
balancing nuclear equations
Definition
the sum of the mass numbers and the sum of the atomic numbers are equal for the nuclei of the reactants and the products
Term
changes in nuclear particles due to radiation
Definition

when radiation occurs

  • particles are emitted from the nucleus
  • mass number may change
  • atomic number may change
Term
guide to completing a nuclear equation
Definition
  1. write the incomplete nuclear equation
  2. determine the missing mass number
  3. determine the missing atomic number
  4. determine the symbol of the new nucleus
  5. complete the nuclear equation
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