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Definition
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Term
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Definition
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Definition
| highest priority groups on opposite sides of pi bond |
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Term
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Definition
| highest priority groups on same side of the pi bond |
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Definition
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Definition
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Term
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Definition
| chiral molecule that polarizes light clockwise |
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Term
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Definition
| chiral molecule that polarizes light c-clockwise |
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Definition
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Definition
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Term
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Definition
| sterioisomers that are not enantiomers |
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Term
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Definition
| equal mix of S and R enantiomers |
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Term
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Definition
| % of one type of enantiomer greater than another (ie - 10%/90% == 80% enatiomeric excess) |
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Term
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Definition
| molecules with 2 apparent steriogenic centers, but w/ a plane of symmetry |
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Term
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Definition
| molecules that differ by rotation around a single bond |
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Term
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Definition
| bond w/ 0degree conformation angle |
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Term
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Definition
| bond w/ conformational angle of 60 degrees |
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Term
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Definition
| electric repulsion of electrons when bonds overlap |
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Term
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Definition
| physical interation of overlapping groups on a conformal bond |
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Term
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Definition
| conformation where two groups overlap (0 degrees) |
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Term
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Definition
| staggered conformation with two groups 180 degrees from each other |
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Term
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Definition
| conforman w/two groups seperated by 60 degrees |
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Term
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Definition
| bonds bent b/c of a cyclic compound |
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