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reducing sugars
info about reducing monosaccharides, disaccharides, reactions and reagents
5
Biochemistry
Undergraduate 3
05/27/2013

Additional Biochemistry Flashcards

 


 

Cards

Term
A) Which monosaccharides are reducing?
B) Which disaccharides are reducing?
C) The 3 common oxidizing agents
Definition

A) all monosaccharides are reducing.  Aldoses oxidize into carboxylic acids and ketoses tautomerize then oxidize

 

B) Maltose and Lactose are reducing.

Sucrose and trehalose are NOT reducing

(The cyclic hemiacetal forms of aldoses can open to reveal an aldehyde--able to become oxidized and reduce a reagent)

(Sugars having acetal or ketal linkages are not reducing sugars)


C) Benedict's, Fehling's, and Tollen's discern between reducing and non-reducing.

 

Molisch's test will just tell if you have a carbohydrate

Term
Benedict's Solution
A) Composition
B) Color initial, final
C) Redox Reactions
Definition

A)copper sulfate in alkaline citrate

B) blue to red, ppt = Cu2O(s)

C) Cu2+ + e ---> Cu

& reducing sugar

oxidised to carboxylate

Term
Fehling's Solution
A) Composition
B) Color initial, final
C) Redox Reactions
Definition

A)copper sulfate in alkaline tartarate

B) blue to red, ppt = Cu2O(s)

C) Cu2+ + e ---> Cu

& reducing sugar

oxidised to carboxylate

Term
Tollen's Reagent
A) Composition
B) Color initial, final
C) Redox Reactions
Definition

A) silver nitrate in aqueous ammonia

B) colorless to silver mirror, ppt = Ag(s)

C) Ag+ + e ---> Ag(s)

& reducing sugar

oxidised to carboxylate

Term
Acetal and hemi acetal structures
Definition
[image]
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