Term
Cyclohexanol + (TsCl & Pyridine)
Step 2 : NaCN DMSO |
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Definition
| Overall, CN replaces the OH |
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Term
| Cyclohexanol + (SO2Cl2 & Pyridine) |
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Definition
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Term
| Cyclohexanol + H2SO4 and heat |
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Definition
| a double bond in the ring |
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Term
| Cyclohexanol + POCl3 & Pyridine (cold) |
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Definition
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Term
| Cyclohexanol + PBr3 & Pyridine |
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Definition
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Term
| Cyclohexanol + Na2Cr2O7 or PCC |
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Definition
| the OH becomes a double-bonded oxygen |
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Term
| 1-methyl-1-Cyclohexanol + HBR |
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Definition
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Term
| 1-methyl-1-Cyclohexanol + POCl3 & Pyridine (cold) |
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Definition
| OH and methyl join together into a C=C off the ring. |
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Term
| Cyclohexanol with a methene + BH3 THF H2O2 OH- |
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Definition
| Methene becomes a methanol |
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Term
| Cyclohexanol with a methanol + PCC |
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Definition
| the O becomes double-bonded to the methane. |
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Term
| Cyclohexanol with a methanol + Na2Cr2O7 |
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Definition
| another O is added, double-bonded to the methane. OH remains. |
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Term
acetylene + H2/Lindlars
step 2 : HBr |
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Definition
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Term
Cyclohexanol with a methanol + NaNH2
Step 2: EtBr + DMSO |
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Definition
| OH becomes O-, which then has an ethane added to it. |
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Term
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Definition
| removes a Hydrogen, leaving it open to bond with anything. |
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Term
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Definition
| takes the triple bond to a double bond |
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Term
1-methyl-Cyclohexane + Br/hv
Step 2: NaOtBu / HOtBu |
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Definition
| First, a Br sticks off where the methyl is, then the Br and methyl are replaced by a methene. |
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Term
| 1-bromo-methyl-Cyclohexane + DMSO and a deprotenated acetylene |
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Definition
| The alkyne bond replaces the Bromine |
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Term
| Cyclohexane with a methyl and alkyne sticking off + HgH2SO4 |
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Definition
| Becomes an alkane structure with an oxygen double-bonded to the 2nd carbon. |
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Term
alkene bond + HgOAc + H20
Step 2: NaBH4 |
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Definition
| OH added to most subbed side |
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Term
| Epoxide ring opening in basic conditions, where does the Nu go? |
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Definition
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Term
| Epoxide ring opening in acidic conditions, Nu goes to.... |
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Definition
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Term
Epoxide + NaCN & DMSO
Step 2: H3O+ |
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Definition
| OH on most subbed, CN on least subbed |
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Term
| to make an epoxide from a double bond use the reagent |
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Definition
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