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Quiz 4
Inorganic Chemistry - Dr.Z
11
Chemistry
Undergraduate 4
10/09/2011

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Term
Aufbau Principle
Definition
puts electrons in their lowest energy configuration.
Term
Molecules form?
Definition
When total energy in electrons of molecules is lower than in separate atoms.
Term
MO theory
Definition
are treated as moving under the influence of the nuclei in the whole molecule
Term
Valence Bond theory
Definition
electrons are localized between atoms and half-filled atomic orbitals overlap to form bonds
Term
bonding orbital
Definition
increased electron density between the two nuclei, and is of lower energy than the two separate atomic orbitals.
Term
antibonding orbital
Definition
results in a node between the two nuclei, and is of greater energy than the two separate atomic orbitals.
Term
gerade
Definition
symmetric with respect to a center of
inversion
Term
Photoelectron spectroscopy
Definition
a technique in which a beam of ultraviolet light with an energy of 21 eV is used to irradiate molecules. Used to determine the energy level of the electron.
Term
Heteronuclear Diatomic Molecules
Definition
more electronegative atom will have
orbitals of lower energy, and therefore
contribute more to the bonding orbitals
Term
LUMO
Definition
electron pair acceptor
Term
Π-orbitals for benzene
Definition
B2g + E1g + A2u + E2u
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