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patterns in periodic table
defs and concepts for lecture test
37
Chemistry
Undergraduate 1
01/13/2013

Additional Chemistry Flashcards

 


 

Cards

Term
how are elements in the same period arranged?
Definition

Each sequential element has one more proton and one electron

 

(as you go from left to right)

Term
how are elements in the same group related ?
Definition
they have a same valence config & have similar chemical properties
Term
grp 1A is called
Definition
alkali metals
Term
grp 2a is called
Definition
alkali earth metals
Term
B,Si,Ge, As,Sb,Te,Po are called
Definition
metalloids
Term
C,N,O,P,S,Se are called
Definition
non metals
Term
Grp 7A are called?
Definition
halogens
Term
Grp 8A is called
Definition
inert(noble) gases
Term
effective nuclear charge def
Definition

as the nucleus becomes ↑ positive,

all electrons experience a stronger pull toward the center.

 

"how strong a particular element pulls electrons"

Term
Why do cations vs (anions /neutral) have a higher effective nuclear charge?
Definition

cations: have more protons than electrons, therefore they are strongly attracted to electrons

(aka they really want to get rid of their positive charge).

 

anions: have more elecs will have a slightly lower effective nuclear charge.

 

neutral: have an equal # of protons and elecs

(have the lowest eff. nuc charge)

Term

Who has a larger effective nuclear charge(Zeff):

Na or Mg?

Definition

Mg

effective nuclear charge increaes as you go across elements in the same period.

Term

Who will have a bigger prinicipal quantum number H or Fr?

whos electrtons will be held less tightly?

Definition

Fr ;

as you go  DOWN a grp prinicipal quantum number increases


its  valence e- will be held less tightly to nucleus

 

Term
Tell who has a bigger atomic radius K or Mn?
Definition

K ;

atomic radii decreases as you go across a period

(recall zeff increases)

Term
Ionization energy/potential (IE) def
Definition

energy required to remove an electron from a gaseous atom or ion

 

(this requires energy (endothermic))

Term

If the effective nuclear charge is high :

describe the location of the valence e-

the ionization energy

the electron affinity

 

Definition

high zeff=

valence e- tightly bound to nucleus

HIGH ionization energy

HIGH electron affinity

 

(aka it takes it alot energy to remove these electrons)

Term
Why is the second ionization energy always higher than the 1st ionization energy?
Definition

Recall an element doesn't want to have a postive charge it wants to gain e- in order to have a full octet,

so it takes alot more energy to remove the 2nd e-  b/c the element is becoming increasingly positive.

Term

Why do grps 1 & 2 have low electron affinties?

Why do grp 7 have high?

Definition

grps 1 & 2 (alkali metals &alkali earth metals) need to lose 1 or 2 e- to achieve their octet.

grp 7 (halogens): only need to gain 1 more e- to achieve their octet so they are the greediest.

Term

electron affinity def

electronegativity def

Definition

1.energy released when atom recieves an electron

*(remember if an element is closer to its octet its energy will be lower hence released , that is a very good thing)

 

2. is a measure of the attractive force that an atom will excert in an electron in a chemical bond, aka its attraction for bonding electrons

Term
what is another name for electronegativity?
Definition
nuclear positivity
Term
True or False: metals have a low density & high melting points
Definition

metals have a high density

high melting point

Term

For metals in general give high/low for the following:

zeff (effective nuclear charge)

electronegativity

atomic radius

ionization energy

Definition

zeff (effective nuclear charge)

electronegativity

atomic radius

ionization energy

Term
 What do the previous characterisitcs allow metals to do?
Definition
donate one or more electrons
Term
Why are metals good conductors of heat and electricity?
Definition
their valence electrons are not bound tightly, they can move freely.
Term
  1. For non metals in general give high/low for the following:

    zeff (effective nuclear charge)

    electronegativity

    electron affinity

    atomic radius

    ionization energy

Definition

zeff (effective nuclear charge)

electronegativity,electron affinity

atomic radius

ionization energy

Term

True or False:

Non metals are good conductors of electricity and heat

Definition
false
Term
Which metals are the most reactive?
Definition
alkali and alkali earth
Term
alkali metals typically have an oxidation state of?
Definition

+1

(they often lose 1 e- to complete their octet)

Term
what is the oxidation state of alkaline earth metals
Definition

+2

(they like to lose 2 electrons in order to complete their 'octet')

"full outer shell"

Term
halogen oxidation state
Definition

-1

(prefer to gain 1 e- to complete their octet)

*remember they have 7 electrons

Term
true or false: halogens have the highest electronegativities
Definition
yes, remember they only need one more e- to complete their octet
Term

Noble gases:

Why are they stable?

tell high/low:

ionization energy

electronegativites

Definition

their valence shell is complete (8e-)

 

ionization energy

almost zero  electronegativites

Term

describe the oxidation states of transition metals

give 2 ex

Definition

transition metals have many positive oxidation states

Fe: +1 ,+2

Mn: +2,+3,+6,+7

Term
transition metals have many positive oxidation states, what does this allow them to do?
Definition

form many differnt ionic compounds

ex hydration complexes (water)

highly colored solutes and compounds(enchances the low solubility of some compounds) 

Term
hemogloblin has what significance regarding this chapter?
Definition
hemogloblin features Fe which changes it state in order to carry out its fcn.
Term

Why does P have a lower electron affinity than Si?

(this goes agaist the periodic table trend )

Definition

P's electronegativity gives a very stable half filled p oribital

vs

Si only needs 1 more electron to fill its p orbital and therefore is very greedy.

Term
the grp next to the halogens is called
Definition
chalogen
Term

which will have a bigger atomic radius?

anion or cation vs a neutral atom

Definition

K- (bigger)

than K

b/c its has gained more e-

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