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Oxidation and Reduction
N/A
13
Chemistry
11th Grade
12/06/2008

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Term
oxidation
Definition
LEO
loss of one or more electrons

For example:

Mg(s)+1/2O2(g) goes to MgO(s)

The magnesium ions was oxidized because it went from the atom for to the ion form of plus 2.
Term
reduction
Definition
GER

gain of one of more electrons

for example

Mg(s) + 1/2O2 goes to MgO(s)

The oxygen was reduced because it went from the oxygen gas atom to the oxide ion of -2
Term
oxidation numbers
Definition
1. for simple compounds between two elements, each oxidation number is the same as the ion for the element in the compound

2. for covalent compounds, assume the compound is ionic

3. the sum of all the oxidation numbers is zero or equal to the charge of the ion

4. elements in their pure form have an oxidation of zero

5. oxygen= -2
hydrogen= +1
Term
disproportionation
Definition
the same element can be both oxidized and reduced in the same reaction

For example: Cl2(g)+H2O(l) goes to HCl(aq)+ HClO (aq)
Term
oxidizing agents
Definition
substances that are reduced and can readily gain electrons
Term
reducing agents
Definition
these are oxidized and readily give up electrons
Term
reactivity series
Definition
if an element is above another element in the reactivity series, then that element is more reactive

it can also determine how spontaneous a reaction is
Term
voltaic cells
Definition
spontaneous reaction

simplest form is with a metal in a solution of its ions

salt bridge is used to prevent a charge build up

1.01x10^5 Pa pressure, 298K, 1M aqueous solution


flow of electrons is always from the negative to the positive
Term
anode
Definition
AN OX

oxidation occurs at the negative electrode
Term
cathode
Definition
RED CAT

reduction occurs at the positive electrode
Term
electrochemical series
Definition
the standard hydrogen cell is used as the reference half- cell
Term
electrolytic cell
Definition
makes a non-spontaneous reaction occur with an external source of power(electrolyte)

signified by molten of aqueous solution
Term
electrolysis in an aqueous solution
Definition
in any aqueous solution, there will also be hydrogen ions and hydroxide ions present as well as the ions of the electrolyte

in some cases the electrodes that do not normally react, will react in this case
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