Term
| cis addition of OH to an alkene |
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Definition
| OsO4 + catalytic peroxide |
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Term
| nonselective addition of OH to an alkene |
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Definition
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Term
| problem of addition with KMnO4 |
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Definition
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Term
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Definition
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Term
| R-(triple bond)-R' -> R-carboxylic acid + R'-carboxylic acid |
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Definition
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Term
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Definition
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Term
| increasing hindrance of alcohol |
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Definition
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Term
| addition to carbonyls (always adds H) |
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Definition
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Term
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Definition
| electrons to most electronegative atom in bond, then subtract the number it has from the number it should have |
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Term
| oxidation (reduction of alcohol) |
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Definition
| H2CrO4 + Jones (acetone, H2O, H2SO4) |
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Term
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Definition
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Term
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Definition
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Term
| non-Jones oxidation of 2' alcohol |
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Definition
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Term
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Definition
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Term
| nonselective halide formation |
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Definition
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Term
| halide formation with inversion |
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Definition
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Term
| halide formation with retention |
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Definition
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Term
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Definition
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Term
| ethers accept/donate H bonds |
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Definition
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Term
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Definition
| ONLY cations and Lewis acids |
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Term
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Definition
| acid cleavage (HBr, AlCl3) |
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Term
| oxidation of thioether (O double bond S) |
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Definition
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Term
| alkylation of thioether (S(+)-I(-)) |
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Definition
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Term
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Definition
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Term
| end: more substituted ether |
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Definition
| acid-catalyzed opening of epoxide |
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Term
| end: less substituted ether |
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Definition
| base-catalyzed opening of epoxide (or organometallic opening) |
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