Term
| Reduction of aldehydes produce this. |
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Definition
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| Ketones are reduces to give this |
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Definition
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| Esters are reduced to give |
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Definition
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| Carboxylic acids are reduced to give |
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Definition
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| To reduce aldehydes and ketones but not carboxylic acids or esters I would use what reagent? |
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Definition
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Term
| To reduce aldehydes, and ketones, as well as esters and carboxylic acids I would use what reagent? |
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Definition
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Term
| LiAlH4 will add how many H's to esters and carboxylic acids? |
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Definition
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Term
| Grignard Reactions are especially reactive with what? |
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Definition
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Term
| Grignard reactions with formaldehyde(CH20) yields what? |
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Definition
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Term
| Grignard reactions with aldehydes yield what? |
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Definition
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Term
| Grignard reactions with ketones yield what? |
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Definition
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Term
Esters react with Grignard reagents to yield what?
(Be specific about where the substituents came from) |
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Definition
| Tertiary alcohols in which two of the substituents bonded to the hydroxyl bearing carbon have come from the Grignard reagent. |
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Term
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Definition
| That water is eliminated. |
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Term
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Definition
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Term
| To dehydrate secondary and tertiary alcohols use? |
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Definition
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Term
| Oxidation of alcohols yields what? |
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Definition
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Term
| An oxidation reaction that ends in an aldehyde or a carboxylic acid had to come from what kind of alcohol? |
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Definition
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Term
| Oxidation of secondary alcohols yields what? |
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Definition
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Term
| Oxidation of a tertiary alcohol yields what? |
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Definition
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Term
| What reagent would we use to prepare an ONLY an aldehyde fron and alcohol, and what type of alcohol would we be using? |
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Definition
| Aldehydes come from primary alcohols and if we wanted to isolate the aldehyde we would use PCC. |
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Term
| What reagent would we use for preparing a carboxylic acid from an alcohol and what type of alcohol would we be using? |
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Definition
| Primary alcohol and the reagent would be CrO3 or Na2Cr2O7 |
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Term
| What reagents would we use to prepare a ketone from an alcohol using oxidation and what type of alcohol would we have started with? |
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Definition
| Secondary alcohols are oxidized to yield ketones and we would use CrO3 or Na2Cr2O7 |
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Term
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Definition
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Term
| These are ALWAYS unreactive in Sn1 and Sn2 |
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Definition
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Term
| If there are 9H singlets what does that tell me about the structure of the molecule? |
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Definition
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Term
| Williamson did what reaction? |
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Definition
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Term
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Definition
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Term
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Definition
| Ether in a 3 membered ring |
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Term
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Definition
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Definition
| position next to the double bond |
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Term
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Definition
| Yield the more highly substituted alkene as major. |
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Definition
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Term
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Definition
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Term
| What is unique about identical neighboring atoms in NMR. |
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Definition
| They don't split. Twins don't date. |
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Term
| If something is more conjugated what does that mean about the UV? |
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Definition
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Term
| 6H doublet and 1 multiplet |
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Definition
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Term
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Definition
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Term
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Definition
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Term
| What does addition of H-X do to an alkene? |
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Definition
| It breaks the double bond and adds the X |
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Term
| What does addition of X2 do to an alkene? |
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Definition
| It breaks the double bond and adds anti X's |
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Term
| What type of alcohols work best with HX reactions? |
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Definition
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