Term
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Definition
| When forming a carbocation, must be the most stable position. |
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Term
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Definition
| Dienes where the double bonds are right next to each other |
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Term
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Definition
| Diene in cis form. Must be in this form for reaction to occur. |
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Term
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Definition
| Double bonds are separated by a single bond |
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Term
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Definition
| X and Y are added to the same side of the double bond |
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Term
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Definition
| Addition of -OH or -O and heat to a structure with a halogen to form a double bond. (Removes halogen) |
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Term
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Definition
| When an -OH is removed from an alkane to form a double bond (alkene) |
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Term
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Definition
| Benzoic C > Allylic C > 3 > 2 > 1 > CH3 |
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Term
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Definition
| Benzoic C > Allylic C > 3 > 2 > 1 > CH3 |
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Term
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Definition
| One of the most stable carbocations |
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Term
| Cyclopropanation Reaction |
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Definition
| A reaction (using CH2I2) where a cyclopropyl group forms where a double bond was present |
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Term
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Definition
| Reaction using MCPBA where an epoxide group forms where a double bond was present. |
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Term
| Anti-Markovnikov Addition |
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Definition
| Addition of a halide, OH, or other group to an alkene on the least substituted position of the double bond. |
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Term
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Definition
| Addition of OH and Br or Cl across a C=C bond in an anti conformation |
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Term
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Definition
| A diene that has groups attached that donate electrons toward the double bonds making it more positive near the DB |
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Term
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Definition
| a dienophile in which electrons are drawn away from the double bond by attached groups |
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Term
| Oxymercuration-demercuration reaction |
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Definition
| A reaction in which an alcohol is prepared from an alkene using Hg(OAC)2, H20, NaBH4, and KOH. It follows Markovnikov addition but rearragement can't occur. |
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Term
| Hydroboration-oxidation reaction |
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Definition
| A reaction in which an alcohol is prepared from an alkene but is anti-Markovnikov (B2H6 in THF and H202, KOH) |
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Term
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Definition
| Reaction in which two pi bonds are lost and 2 sigma bonds are gained. |
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Term
| Kinetic controlled vs. Thermodynamic controlled |
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Definition
Kinetic-faster (1,2 major) <25 degrees C -------
Thermodynamic-more stable (1,4 major) > 25 degrees C |
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