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Organic Enol/Amine/Carbohydrate
n/a
23
Chemistry
Undergraduate 3
04/16/2012

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Cards

Term
[image]
Definition
Allose
Term
[image]
Definition
Altrose
Term
[image]
Definition
Glucose
Term
[image]
Definition
Mannose
Term
[image]
Definition
Gulose
Term
[image]
Definition
Idose
Term
[image]
Definition
Galactose
Term
[image]
Definition
Talose
Term
Carbohydrates w/ 4 chiral centers mnemonic
Definition
All altruists gladly make gum in gallon tanks
Term
Carbohydrates w/ 3 chiral centers mnemonic
Definition
Ribs are xtra lean
Term
Alpha halogenation
(what -> what, reagents)
Definition
carbonyl -> halocarbonyl
acetic acid, H2O
Term
Aldol condensation
(what -> what, reagents)
Definition
2 carbonyls -> aldol
1. -OH
2. H+
Term
Aldol dehydration
(what -> what, reagents)
Definition
aldol -> alkene carbonyl
H2SO4, H2O
Term
Aldol reduction
(what -> what, reagents)
Definition
aldol -> diol
H2, Ni
Term
Claisen condensation
(what -> what, reagents)
Definition
Ester -> ester with carbonyl on it
1. -OR
2. H+
Term
Azide alkylation
(what -> what, reagents)
Definition
Azide -> primary amide
1. RX
2. LAH
3. H+
Term
Secondary aliphatic amine substitution
(what -> what, reagents)
Definition
Secondary amine -> R2NN=O
NaNO2, HCl
Term
Tertiary aromatic amine substitution
(what -> what, reagents)
Definition
Tertiary aromatic amine -> ortho and para nitro tertiary aromatic amine
NaNO2, HCl
Term
Primary aromatic amine substitution
(what -> what, reagents)
Definition
Primary aromatic amine -> Diazonium salt
NaNO2, HCl
Term
Hoffman elimination
(what -> what, reagents)
Definition
Primary amine -> Alkene
(least substituted double bond selectivity)
1. Excess CH3I
2. Ag2O, H2O
3. heat
Term
Michael Reaction
(what + what, reagents)
Definition
Dicarbonyl + alpha, beta unsaturated carbonyl
1. NaOEt
2. alpha, beta unsaturated carbonyl
3. EtOH
Term
Acetal formation of carbohydrates
(what -> what, reagents)
Definition
carbohydrate -> glycoside
CH3OH, H+
Term
Reduction of carbohydrates
(what -> what, reagents)
Definition
carbohydrate -> alditol
1. NaBH4
2. HCl, H2O
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